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Membrane-supported liquid-liquid extraction uses artificial membranes for the generation of a phase interface between the two liquid phases involved in extraction. Additional equipment for the generation of droplets as well as phase separation afterwards is no longer necessary. Since the membranes used for this special type of extraction are quite well described concerning thickness, porosity, tortuosity and material it is possible to generate information about the diffusion coefficient of the component to be extracted within the preferred solvent from extraction trails easily. This article describes an experimental set-up for both the proof of principle of membrane-supported liquid-liquid extraction and, using a dedicated computer-aided data treatment, how to calculate the overall mass transfer coefficient as well as the diffusion coefficient for a given system within moderate testing duration. 相似文献
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Päivi Mäki‐Arvela Imane Hachemi Dmitry Yu. Murzin 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2014,89(11):1607-1626
Carotenoid extraction from algae is currently under intensive research due to the increased demand for naturally occurring compounds, which are especially rich in biologically active isomers. Furthermore, natural carotenoids exhibit greater stability than synthetic ones. Conventional liquid extraction suffers from several drawbacks, such as use of high amounts of solvent, and several extraction steps. In this work carotenoid extraction from algae using different methods, such as microwave and ultrasound assisted extraction as well as pressurized liquid extraction and extraction with supercritical CO2 and ethane, is summarized together with modelling of extraction kinetics. In addition carotenoid availability, algae pretreatment, stability of extracts, their antioxidative and antimicrobial activities as well as downstream processing and storage of algae extracts have been reviewed. As a conclusion it can be stated that carotenoid extraction is complex, demanding optimization of the carotenoid yield and antioxidative stability, which are often inversely proportional. © 2014 Society of Chemical Industry 相似文献
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协同萃取作为溶剂萃取法的分支被广泛研究。对于协同萃取的机理探索,必须阐明协同效应产生的微观原因,并给出微观与宏观性质的联系,因此从分子的微观结构和内部运动认识协同萃取以及影响因素尤为重要。本工作重点综述了萃取剂之间、萃取剂与金属离子之间的协同作用机理以及影响其作用因素的研究进展,指出协同萃取的本质是氢键的形成导致萃取剂的结构与能量发生变化,进而提高了萃取效果。协同萃取主要包括两个方面,一是更容易生成稳定的萃合物从而提高萃取效率,二是利用萃取剂之间的差异提高分离性能。萃取系统的pH、不同萃取剂的组合及比例、萃取剂的浓度、中性磷类萃取剂的添加等诸多因素显著影响协同萃取过程,且各种因素之间存在交互。运用模拟计算进行理论性预测,通过实验进行验证,并且辅以现代分析化学方法进行表征,是今后化工研究领域行之有效的方法之一,理论推广实际,从而更好地指导生产。 相似文献
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D. K. Bredeson 《Journal of the American Oil Chemists' Society》1978,55(11):762-764
The mechanical screw press was the principal means of extracting vegetable oilseeds in the United States from the 1930s through
the 1940s and 1950s. Then the utilization of solvent extraction cut drastically into their use for full extraction, but created
a great demand for screw presses for prepressing of high oil content seeds for solvent extraction. However, use of the screw
press for full extraction has been increasing over the years in the less developed countries, and is the main modern machine
utilized for some products such as palm fruit. Today ever larger and more efficient machines are being developed for full
extraction and pre-pressing of vegetable oilseeds and fruits. 相似文献
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朱宝伟 《化学工业与工程技术》2014,(3):4-8
微波条件下,研究了在乙醇抽提神府煤中加入氯化锌对其结果的影响。采用气相色谱/质谱联用的方法分析了乙醇和乙醇-氯化锌抽提物的组成;利用傅里叶红外光谱技术分析了神府脱矿物质煤、乙醇抽余煤和乙醇-氯化锌抽余煤的结构。分析结果显示:在乙醇溶剂中添加少量的氯化锌,其抽提物的组成发生了改变;乙醇-氯化锌抽余煤与原脱矿物质煤和乙醇抽余煤相比,芳环吸收强度降低,表明在抽提过程中可能伴随着烷基化反应的发生。 相似文献
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微波萃取技术研究进展 总被引:8,自引:0,他引:8
综述了微波萃取的机理、特点、参数和设备、影响微波萃取效果的因素,介绍了微波萃取技术在有效成分提取、临床和物质检测方面的国内外研究和应用情况。微波萃取作为一种新技术,其前景广阔,有望在萃取抽提领域开拓出新的天地。 相似文献
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L. L. Diosady L. J. Rubin N. Ting O. Trass 《Journal of the American Oil Chemists' Society》1983,60(9):1658-1661
The simultaneous size reduction and solvent extraction of canola seeds were studied using a laboratory blender and a small,
pilot-scale Szego mill. The laboratory tests established that over 95% of the oil may be removed from the seed in a single
contact stage. The effects of contact time and solvent-to-seed ratio were investigated. The extraction equilibrium favored
the extraction of the oil at higher solvent-to-seed ratios. In all cases the extraction reached some 90% of the equilibrium
value after 3 min. Runs in the Szego mill, which is a unique orbitalmill developed by one of us (O. Trass), confirmed that
solvent grinding is an efficient extraction technique. In this equipment, contact times as short as 30 sec give significant
extraction, with the system approaching equilibrium in one minute. The Szego mill appears to be suitable for the rapid extraction
of edible oil seeds such as rapeseed. 相似文献
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W. Becker 《Journal of the American Oil Chemists' Society》1978,55(11):754-761
The removal of edible oils from oilseeds was practiced by the Egyptians many centuries ago. Some of the developments leading
to today’s worldwide extraction industry are discussed, and a brief history of the industry in the United States from 1940
to the present is included. The theory of solvent extraction is outlined in practical terms. Several types of solvent extraction
and desolventizing systems are explained. Also, typical preparation and extraction processes for presscake, soybeans, and
some high oil content seeds are illustrated. Some reasons for taking extra precautions in the preparation process and the
desolventizing process when producing human edible soy protein products are explained. Energy conservation suggestions are
included. 相似文献
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针对十溴联苯醚(BDE-209)难溶性和萃取方法的复杂性,通过从萃取剂和萃取条件上对BDE-209进行萃取优化。结果表明:(1)上清-沉淀复合法的萃取效率仅为21.8%。(2)烘干温度对样品的萃取效率影响不显著,在80、 100和120℃条件下的萃取效率均达到95%以上,但高温条件有可能使BDE-209发生降解。(3)不同萃取剂和分步萃取对样品萃取效率影响显著,2次萃取比一次性萃取的萃取效率提高了13.6%~29.6%,正己烷萃取效率(100%)>乙酸乙酯萃取效率(84.87%)>异辛烷萃取效率(23.33%)。(4)采用正己烷少量多次萃取,可短时间内最大程度回收水相样品中的BDE-209(97.82%)。少量多次萃取法萃取效率高,操作简便,节省时间,适于大部分水相样品快速定量分析。 相似文献
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以大黄为实验材料 ,利用半连续提取设备 ,分别采用简单提取和循环提取的方式 ,研究了溶剂流速对提取率和提取液浓度的影响。结果表明简单提取的速度快 ,极限提取率高 ,提取液浓度在初期很高 ,并随提取率增加而下降 ;循环提取溶剂用量和提取液浓度易控制 ,收率受级平衡限制而较低 ;适当增大溶剂流速可缩短提取时间 ,但会增加前者的溶剂消耗 ;在简单提取中引入回流对后期的提取有一定促进作用 ,回流的时间和回流强度值得研究。将简单提取和循环提取适当组合能够在保证效率的基础上使收率和提取液浓度有较大提高。 相似文献
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酶法提取无患子皂苷的工艺研究 总被引:3,自引:0,他引:3
采用酶法提取无患子皂苷,研究了酶的类型对无患子皂苷提取的影响,并通过正交实验优化酶法提取工艺。结果表明,纤维素酶有助于无患子皂苷的提取,酶提法的较优工艺条件为:纤维素酶用量为无患子粉末质量的0.1%,酶提时间2.5 h,酶提温度50℃,pH值4.7。此时,无患子皂苷的提取率达到86.59%,比未加酶处理时提高了19.63%。 相似文献
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Measurements of rates of oil extraction from either fine flour or soybean flakes in a column showed that oil extraction from
flour was dependent on the volume of solvent, but oil extraction from flakes depended on time of contact rather than volume
of solvent. We interpreted the data to mean that oil was being washed out of the fine flour with little diffusion involved,
whereas in flakes, the limit on rate was diffusion of the solvent into and out of the tissue.
Fine full fat flour worked well in a batchwise countercurrent extraction system with mixing and centrifugal separation. Because
the oil dissolved immediately and reached equilibrium rapidly, the actual material balance was close to calculated values.
However, due to the large hold-up volume, the separation of miscella from the meal required several mixing and separation
stages. The oil resulting from this countercurrent extraction system had a superior quality with 37 ppm phosphorus, 0.08%
free fatty acids, and a light color. 相似文献
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D. K. Bredeson 《Journal of the American Oil Chemists' Society》1983,60(2):211-213
Competitive pieces of equipment for full-pressing and prepressing oilseeds are described. “Enhanser” machines to treat seeds before solvent extraction considerably increase the capacity of the solvent extraction system. 相似文献
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In the experimental countercurrent extraction of flaked cottonseed meats by trichloroethylene the residual oil content of the extracted flakes decreased with: first, a decrease in the final oil content of the final miscella; second, decrease in the flake moisture down to 8.64%; third, decrease in flake thickness; fourth, increase in temperature; and fifth, increase in extraction time. For the batch of cottonseed meats used the following equation was developed: whereR is percent residual extractables,b is flake thickness in feet,D is meat diameter in feet,ϑ is extraction time in hours,μ in viscosity, lb. per ft. hr.,ρ is density, lb. per cu. ft., andt is extraction temperature in degrees F. Not enough data were secured by extraction with hexane to check the equation developed for trichloroethylene extraction. Hexane is a poorer solvent for cottonseed oil than trichloroethylene. The amount of oil remaining in the meal is affected to a greater extent by the miscella concentration in hexane extraction than in trichloroethylene extraction. 相似文献