共查询到19条相似文献,搜索用时 843 毫秒
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目前,大多数聚合物固态电解质在室温下离子电导率较低,约为10–8 ~10-6 S /cm,且对温度存在着较大的依赖性,仍无法满足高性能室温固态锂电池的实际应用需要。基于此,本文先介绍了室温聚合物电解质在锂离子电池中应用的主要研究进展及其优缺点。然后,从物理调控、化学调控等多角度重点阐述了室温聚合物电解质(包括全固态聚合物电解质、准固态聚合物电解质)的制备工艺、优化与改性方法、作用机理等在电池中应用的主要研究进展和现状。最后,对锂离子电池用室温聚合物电解质存在的挑战和未来可能发展趋势进行了展望。 相似文献
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聚合物电解质由于本身的优点,已成为锂离子电池研究的一个热点.聚合物电解质由聚合物、锂盐及添加剂组成,本文综述了聚合物电解质研究的新体系,论述了聚合物电解质中各组分对其性能的影响. 相似文献
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凝胶型聚合物锂离子电池现场聚合工艺研究进展 总被引:1,自引:0,他引:1
凝胶型聚合物锂离子电池的现场聚合工艺已经成为聚合物锂离子电池领域的一个研究热点。主要介绍了室温现场聚合、热引发现场聚合、辐射引发现场聚合及电化学引发现场聚合等几种聚合物锂离子电池的现场聚合工艺,并对这几种现场聚合工艺的工艺过程、聚合物体系、聚合反应原理、所制聚合物电解质及电池性能方面进行了总结和评述,比较了各种工艺的优缺点,并对聚合物锂离子电池现场聚合工艺的发展前景进行了预测。 相似文献
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纳米复合在光聚合高分子固体电解质中的应用研究 总被引:5,自引:0,他引:5
将纳米级陶瓷粉末分散到含有高分子基体预聚物、高氯酸锂及光引发剂的光敏物质中 ,并通过紫外光辐射使其交联固化为导电薄膜锂聚合物电池用电解质材料 ,并对其成膜性、感光性能以及导电性能进行了研究 ;本文还介绍了近年来纳米复合材料在锂聚合物电池中的应用进展情况 相似文献
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R. Koksbang I. I. Olsen P. E. Tonder N. Knudsen D. Fauteux 《Journal of Applied Electrochemistry》1991,21(4):301-307
AC impedance measurements of polymer electrolyte-based, symmetrical composite cathode cells were used to probe the effects of the composite cathode composition and fabrication process upon its performance when used in polymer electrolyte-based thin film rechargeable lithium batteries. The relationship between cycling performance and AC impedance measurements were used to elucidate some of the reported failure mechanisms of rechargeable lithium polymer electrolyte batteries. The rapid initial capacity decay observed within the first few cycles of the polymer electrolyte/V6O13 based composite cathode is shown to be related to the properties of the composite cathode active material, while the slower capacity decay observed during subsequent cycles, under continuous cycling regimes, appears to be related to a loss of ionic and electronic contact in the composite cathode. 相似文献
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Solid polymer electrolyte supported by a microporous membrane was prepared and characterized. The polymer electrolyte was prepared by penetrating the highly conductive solvent-free polymer electrolyte based on poly(oligo [oxyethylene] oxyterephthaloyl) into the pores of the highly porous membrane. The electrochemical characteristics of the solid polymer electrolytes are presented, and we discuss the possibility of them as an electrolyte material for lithium polymer batteries. 相似文献
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目前商业化的锂离子电池多使用有机液态电解质,存在易燃易爆、易泄露等安全风险,而采用固态电解质替代有机液态电解质可以有效提高电池安全性。锂离子电池用固态电解质又可分为无机固态电解质和有机——即聚合物固态电解质。无机固态电解质对高温或其他腐蚀性环境适应性好,适用于在极端工作环境中刚性电池等领域;聚合物固态电解质在柔韧性和可加工性上则优势明显,适用于柔性电池等领域,但这些材料均尚有问题待解决。无机-有机复合的方式,有望综合两种材料的优势,取长补短,提高固态电解质的综合性能和实用价值。 相似文献
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Mingtao Li Bolun Yang Zhan Zhang Lu Wang Ying Zhang 《Journal of Applied Electrochemistry》2013,43(5):515-521
Polymer gel electrolytes comprising a sulfur-based ionic liquid (IL), a lithium salt, and butyrolactone (GBL) as an additive hosted in PVdF-HFP matrix were prepared and characterized. The result shows that adding small amount of GBL to the polymer electrolytes can improve the cathodic stability of the electrolytes, which ensures the lithium plating/stripping in the redox process. Furthermore, cyclic voltammograms studies indicate that the polymer electrolytes have well reversible redox process. When the IL component reaches 75 wt%, the polymer electrolyte has higher ionic conductivity than the other samples and it is 6.32 × 10?4 S cm?1. The assembled batteries with the polymer electrolyte have better discharge capacity, and after 100 cycles, the discharge capacity of the battery still retains 148 mAh g?1. 相似文献
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《Ceramics International》2023,49(3):4473-4481
All solid-state lithium batteries (ASS-LBs) with polymer-based solid electrolytes are a prospective contender for the next-generation batteries because of their high energy density, flexibility, and safety. Among all-polymer electrolytes, PEO-based solid polymer electrolytes received huge consideration as they can dissolve various Li salts. However, the development of an ideal PEO-based solid polymer electrolyte is hindered by its insufficient tensile strength and lower ionic conductivity due to its semi-crystalline and soft chain structure. In order to lower the crystallization and improve the performance of PEO-based solid polymer electrolyte, tungsten trioxide (WO3) nanofillers were introduced into PEO matrix. Herein, a PEO20/LiTFSI/x-WO3 (PELI-xW) (x = 0%, 2.5%, 5%, 10%) solid composite polymer electrolyte was prepared by the tape casting method. The solid composite polymer electrolyte containing 5 wt% WO3 nanofillers achieved the highest ionic conductivity of 7.4 × 10-4 S cm-1 at 60 °C. It also confirms a higher Li-ion transference number of 0.42, good electrochemical stability of 4.3V, and higher tensile strength than a PEO/LiTFSI (PELI-0W) fillers-free electrolyte. Meanwhile, the LiFePO4│PELI-xW│Li ASS-LBs demonstrated high performance and cyclability. Based on these findings, it can be considered a feasible strategy for the construction of efficient and flexible PEO-based solid polymer electrolytes for next-generation solid-state batteries. 相似文献
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Solid‐state lithium metal batteries (SSLMBs) are believed to be important pathway to overcome the limitations that state‐of‐the‐art lithium‐ion batteries face in terms of safety and energy density. In addition to transporting ionic species in solid‐state configuration, solid polymer electrolytes (SPEs) are structurally designable and processable, and have been deemed as an auspicious kind of solid electrolyte to access highly‐performant SSLMBs. In this essay, we provide a historical overview on the development of SPE‐based SSLMBs, aiming to highlight the main achievements being made at both material and cell levels. It is hoped that the personal reflection and retrospect presented in this essay give an impetus to inspire the discovery of tantalizing battery materials and improve the overall performance of SPE‐based SSLMBs and other emerging battery technologies. 相似文献