硅氧化焼注入后水树老化交联聚乙烯电缆电气特性和微观结构（英文）

To evaluate the effect of using siloxane liquid to rejuvenate water tree defects in cross-linked polyethylene(XLPE)cables,we investigated the electrical properties and micro-structures of water-tree aged XLPE cables after siloxane liquid injection treatment.The water-tree aged samples were prepared by performing accelerated aging experiment using water-needle electrodes,and the siloxane liquid is injected into the aged cable through a pressurized injection system.Dielectric loss factors of the samples before and after the rejuvenation were compared.The water trees and the internal filler were observed using scanning electron microscope(SEM).Electrical properties of the reactants are measured.Electric field simulation is conducted to verify the rejuvenation effect by finite element method.The results show that the siloxane liquid diffused into the insulation layer in a short time and reacted with water in the water trees.The electrical properties of the formed organic filler are in accord with that of XLPE.Therefore,the action between siloxane and water can inhibit the growth of water trees and reduce electric field distortion of the water tree areas.As a result,insulation performance of the cable is enhanced.A 70 m long cable was aged and rejuvenated in laboratory and an on-site rejuvenation experiment was conducted,and in both cases the dielectric loss factor and leakage current halved after rejuvenation.     

压力注入电压稳定剂对热氧老化电缆绝缘性能的增强机理

为了研究压力注入电压稳定剂对热氧老化电缆的修复效果,通过配置修复液对电缆样本进行注入修复,研究修复液对电缆绝缘性能的增强效果及作用机理。选取抗氧剂300和二茂铁配置不同添加浓度的7种硅氧烷修复液,对热氧老化电缆样本进行注入式修复,测试修复前后XLPE绝缘的电树引发电压、直流电导率和介质损耗因数,对部分样本进行二次老化,并测试不同老化时间的氧化诱导期和电树引发电压。结果表明,注入2种类型的电压稳定剂均能够大幅提高热氧老化电缆的电树引发电压,但也会在一定程度上增大电导率和介质损耗因数;注入抗氧剂300能够提高热氧老化电缆的氧化诱导时间,并在较长时间内提升其抗热氧老化和抗电树能力。由扩散公式与实验结果可知,通过增大注入压力,升高扩散温度,选择有效浓度区间更大的电压稳定剂,选取较为保守的添加含量等措施,使电压稳定剂在绝缘层中的浓度分布处于有效浓度区域,是保证修复效果的有效措施。     

在线注入有机硅修复液对交联聚乙烯电缆中水树生长的影响

提出了水树老化电缆的在线修复方法,讨论了在交变电场下修复液对水树的抑制作用及其绝缘修复机理。采用高频高压水针电极法对新样本、预修复样本和在线修复样本进行加速水树老化。老化一个月后,使用显微镜观察样本中水树形态并测量其水树长度。通过差示扫描量热法分析样本绝缘层的劣化程度,同时利用扫描电镜和能谱分析仪对比水树区域的微观形貌及化学结构变化。研究表明,在线注入有机硅修复液能有效地抑制水树的生长。在电场的作用下,修复液分子和水分子同时向强电场区域(如微孔、水树区域等)进行扩散并发生反应,消耗水分并且生成凝胶颗粒填充微孔,一定程度上缓解了绝缘的劣化。     

冷却介质对低密度聚乙烯电树枝老化特性的影响

低密度聚乙烯是电力电缆的主要绝缘材料,电树枝生长特性分析是评估电缆绝缘性能的基础。为此选用冰水、空气和硅油3种不同介质对聚乙烯进行淬火处理,采用针板电极设计出试样的电树枝生长实验系统,通过实时数字显微摄像系统对试样中电树枝生长过程进行了观测,采用差示扫描量热法分析了试样的结晶度和晶粒尺寸均匀性,采集了试样的局部放电数据并对数据进行了统计分析。试验与分析结果表明:硅油冷却聚乙烯电树枝增长速度与扩散系数均小于冰水、空气冷却试样;3种试样中,硅油冷却聚乙烯结晶度最高,晶粒尺寸分布最均匀,放电量与放电重复率较低;冰水冷却聚乙烯结晶度最低,放电量与放电重复率较高。     

水树老化XLPE电缆绝缘修复技术应用及展望

电力电缆的水树修复技术为电网企业解决老旧电缆问题提供了一条新思路.为此,对水树老化交联聚乙烯（XLPE）电缆绝缘修复技术的国内外现状、在我国的应用及发展前景进行了介绍.重点对修复液成分、注入技术及相关监测手段的发展和现状做了归纳总结,提出了当前需要解决的问题,并结合实际运行电缆的修复实例,对修复效果进行了分析.实例分析显示,修复后电缆的绝缘水平在短时间内有了明显提高,因此,也说明该修复方法对老化电缆绝缘有很好的修复作用.     

NaCl溶液对XLPE电力电缆工频击穿特性和水树的影响

采用同一根抗水树XLPE电力电缆,分别在自来水和NaCl溶液中进行60 d、120 d和180 d的加速老化试验,然后对老化前和老化后的电缆试样,分别进行工频逐级击穿,对老化后击穿的电缆试样进行水树检查。试验结果表明,NaCl溶液对抗水XLPE电力电缆的老化有明显的作用。     

Long-term characteristics of XLPE cables

To study the long-term characteristics of XLPE cables installed in free air and in water, aging tests were conducted under various testing conditions using XLPE cables with both 3.5 mm and 6 mm insulation. From the Weibull plots of lifetime distribution under the voltage stress E_L as the minimum breakdown strength, the minimum value of time to breakdown t_L under the constant voltage was estimated. The results of accelerated aging tests of XLPE cables installed in free air demonstrated that the V-t characteristics of XLPE cables could not be described by the conventional inverse power law (t ∝ V⁻ⁿ) with a single constant life exponent n. Based on the microscopic observation of a sliced insulation removed from XLPE cables, it was concluded that bow-tie trees with longer tree length observed in cables tested in water were caused by the moisture from outside, whereas the trees in cables tested in free air were caused by the residual moisture originally existing in the insulation. The breakdown strength of the aged cables tested in water increases through cable drying. However, it does not recover to the original values.     

Effect of water on aging of XLPE cable insulation

Cables as elements of power distribution system have great influence on its reliable service and overall planning requirements. During last years, crosslinked polyethylene (XLPE) cables have been more and more used in power systems. This paper presents the results of an investigation of changing of (XLPE) cables insulation breakdown stress (AC BDS) due to water absorption. The paper deals with AC BDS of the following kinds of XLPE cable insulations: steam and dry cured with water tree retardant crosslinked polyethylene (TR-XLPE) and non-tree retardant crosslinked polyethylene (XLPE). During tests, the tap water was injected into, (1) conductor with cable ends closed; (2) into cable conductor with ends opened; and (3) into metallic screen with cable ends opened. The presence of water in XLPE cables was subjected to electrical stress and heating. AC BDS tests were performed as a function of aging time and water content in the cable insulation at different aging temperatures. Also, in this investigation, tests with the changing of AC BDS in the radial direction of unaged and aged XLPE cable insulations were carried out.     

A study of treeing phenomena in the development of insulation for500 kV XLPE cables

This review summarizes research on treeing phenomena, i.e. the formation of electrical trees and water trees, that has been undertaken in Japan for the development of 500 kV XLPE cable. Section 1 presents the results of factors affecting XLPE cable insulation breakdown under commercial ac and lightning impulse voltages. Section 2 verifies the phenomena of electrical tree formation in XLPE cable insulation using block samples and model cables, and gives the results of studies to determine the level electrical field stress initiation for such trees. Section 3 summarizes the results of studies on long-term aging characteristics, which is a particular problem under commercial ac voltages, while Section 4 explains how this research influenced the design of 500 kV XLPE cable insulation. All authors were members of `The investigation committee of fundamental process of treeing degradation' under IEEJ     

Accelerated cable life testing of EPR-insulated medium voltagedistribution cables

This paper presents results aimed at developing a reliable accelerated aging tank test for EPR-insulated cables. Aging was performed at 2 to 4 times rated voltage on load cycling to temperatures of 45°C, 60°C, 75°C, and 90°C at the conductor with water in the conductor strands and outside the cable. Results show that cable failure is more rapid at the highest electrical stress and lowest conductor load cycle temperature. Cables aged at higher temperatures and various levels of electrical stress rarely failed and retained in excess of 40% of their original breakdown strength after 1500+ days of aging. Aging performed at 90°C load cycle temperature and 4 times rated voltage with air on the outside and water at the conductor of the cable showed more rapid loss of life than with water outside. Results indicate the optimum aging conditions for EPR-insulated cables in the accelerated cable life test (ACLT) differ significantly from those previously observed for XLPE-insulated cables, and that the appropriate test methodology for EPR-insulated cables requires additional study     

去极化电流法对10kV电缆绝缘老化诊断的研究

为了对10k V运行电缆绝缘状态进行简单、快速评估,提出一种基于去极化电流的诊断方法,对水树老化交联聚乙烯电缆绝缘状态进行评估,并对其诊断参数进行了研究。首先通过水树加速老化装置在电缆样本中生成明显的水树。然后采用虚拟仪器(Labview)配合Keithely皮安表与高压真空开关系统完成去极化电流控制采集平台的搭建。利用搭建的测试平台对不同长度和不同老化时间的电缆样本进行去极化电流测试,通过对去极化电流曲线的积分,提出了基于去极化电流放电量的电缆绝缘老化判别方法。结果表明:长电缆的去极化放电量远大于短电缆,老化电缆的放电量大于新电缆,且老化程度越严重,稳定后去极化电流值越大。说明该去极化电流法能准确有效判别电缆绝缘老化问题。     

Dielectric and viscoelastic properties of cross-linked polyethylene aged under multistressing conditions

Different measurements were performed in cross-linked polyethylene (XLPE) employed as insulating material in coaxial cables that were field-aged and laboratory-aged under multistressing conditions at room temperature. Samples were peeled from the XLPE cable insulation in three different positions: just below the external semiconductor layer (outer layer), in the middle (middle layer) and just above the internal semiconductor layer of the cable (inner layer). The imaginary part of the electric susceptibility showed three peaks that obey the Dissado-Hill model. For laboratory-aged XLPE samples peeled from the inner and from the middle positions the peak at very low frequency region increased while in samples from the outer position a quasi-DC conduction process was observed. In medium frequency range a broadening of the peak was observed for all samples. Viscoelastic properties determined through dynamic mechanical analysis suggested that the aging generates processes that promoted changes of the crystallinity and the cross-linking degrees of the polymer. Fourier transform infrared spectroscopy (FTIR) measurements revealed an increase of oxidation products (esters), evidence of polar residues of the bow-tie tree and the presence of cross-linking by-products (acetophenone). Optical and scanning electronic microscope (SEM) measurements in aged samples revealed the existence of voids and bow-tie trees that were formed during aging in the middle region of the cable.     

交联聚乙烯电缆水树缺陷的修复方法研究

采用硅氧烷修复液修复交联聚乙烯电缆老化试样中的水树,进而分析修复效果及机理。将介质损耗因数为4%～6%,绝缘电阻7 500～10 000 MΩ的短电缆在7.5 kV 450 Hz交流电压下老化至介质损耗因数达到20%左右,绝缘电阻3 500～5 000 MΩ。然后用压力注入式修复装置把修复液注入缆芯对水树缺陷进行修复。以介质损耗因数、绝缘电阻和击穿电压为指标对修复效果进行评判;通过显微镜切片观察修复前后水树微观形态;通过仿真修复前后水树附近电场分布来分析和验证水树的修复机理。实验结果证明,修复液可以充分与电缆水树中的水发生反应生成胶状聚合物填充水树通道;修复后电缆介质损耗因数、绝缘电阻和击穿电压恢复到新电缆水平;改善了绝缘层电场分布;有效地抑制了水树生长。实验表明,该修复液可有效修复电缆中的水树缺陷,提高电缆绝缘水平。     

The influence of defects on the short-term breakdowncharacteristics and long-term dc performance of LDPE insulation

Extruded polyethylene is used as the bulk insulation for ac HV cables because of its high electric resistivity and breakdown strength. Although the material at present has limited use in dc power cables, it is used extensively in submarine optical communication cable systems. This paper reports on the study of the short-term characteristics and long-term performance of low-density polyethylene (LDPE) insulation under dc electric stress. The results are presented in which controlled defects as found in practical systems (voids, metallic and non-metallic particles) were introduced into well-characterized polymer material so that their influence on electrical strength and breakdown mechanisms could be determined. Samples were compression-molded under laboratory conditions and subjected to ramp-to-failure and electrical aging tests at various stresses. Weibull statistics are used to analyze the results. Examination of electrically aged samples indicates an oxidation degradation around the defects due to stress enhancement. From the failed samples a value of n in the inverse power model was estimated. The residual life of aged samples was also examined     

The fractal analysis of water trees: an estimate of the fractaldimension

Water trees result from ac electrical aging of the polymeric insulation of medium and HV power cables in a humid or wet environment. As suggested by their name, they arise from penetration of water in the polymer. Visual observation with the help of an optical microscope shows tree (bush) type structures. This suggests that water trees might be fractal objects. Calculation of the fractal dimension from experimental samples may confirm the fractal characteristics and also give information on the damage caused to the polymer. In this work images of water trees taken under the optical microscope, dyed by methylene blue and etched for scanning electron microscopy (SEM), were studied in order to estimate the fractal dimension using a box-counting algorithm. The photographs, made using an optical microscope (scale of 100 μm), of the dyed samples were obtained from laboratory-aged low-density polyethylene (LDPE) specimens using accelerated techniques. Different field amplitude and frequency and also time of aging were used and the dimension values were compared. SEM images resulting from aged cross-linked polyethylene (XLPE) cables revealed a structure at a different scale (~3 μm). Each photograph was analyzed to compare regions with and without water trees     

Dielectric spectroscopy for diagnosis of water tree deteriorationin XLPE cables

An HV dielectric spectroscopy system has been developed for diagnostics of water tree deteriorated extruded medium voltage cables. The technique is based on the measurement of nonlinear dielectric response in the frequency domain. Today's commercially available systems are capable of resolving low loss and small variations of permittivity as a function of frequency and voltage. Experience from more than 200 field measurements was combined with laboratory investigations. Small samples were used in an accelerated aging test to elucidate the correlation between water tree growth and dielectric response. Furthermore, field aged cables were investigated in the laboratory. It has been shown that the dielectric response of water tree deteriorated crosslinked polyethylene (XLPE) cables can be recognized and classified into different types of responses related to the aging status and breakdown strength. The influence of termination and artifacts such as surface currents was investigated. The measurement method enables us to separate the response of the cable from the influence of accessories. Finally, two different field studies of the implementation of the diagnostic method are presented. The field studies show that the fault rate decreased significantly when replacement strategy was based on the diagnostic criteria formulated     

交联聚乙烯电缆热老化与电树枝化相关性研究

热老化过程不但会影响交联聚乙烯（XLPE）电缆绝缘的物理化学性能,还对绝缘内电树的产生与生长有着一定的影响。研究了热老化后XLPE电缆绝缘中的电树行为．探讨XLPE电缆绝缘中电树枝过程与材料热老化的关系。采用带循环通风的热老化箱对XLPE电缆绝缘进行3个温度等级的热老化实验：采用针板结构电极进行电树枝实验,并利用数码显微镜观察电树枝的产生和发展情况;利用差示扫描量热法（DSC）、傅里叶红外光谱分析（FTIR）测试了不同温度热老化下XLPE电缆绝缘的物理化学性能;最后探讨了几种不同结构电树枝的生长机理．认为热老化并没有加速电树枝的生长．反而有一定的抑制作用．     

Comparative laboratory evaluation of TR-XLPE and XLPE cables with Super-smooth conductor shields

This paper provides data on four commercial tree retardant crosslinked polyethylene (TR-XLPE) and one cross-linked polyethylene (XLPE) insulated 15 kV cables supplied by three manufacturers. The cables have "super-smooth" conductor shields and "extra-clean" insulation and insulation shields. AC and impulse voltage breakdown and selected other characterization data are presented for cables that were aged immersed in room temperature water (15-30/spl deg/C) up to 24 months of a planned 48 months aging program. The five cables have high ac voltage breakdown strength, three of the TR-XLPE cables, actually increased in breakdown strength during aging. The one TR-XLPE cable that had the lowest ac voltage breakdown had vented trees at the insulation shield and high dissipation factor, which the other cables did not have. The impulse voltage breakdown strength of all cables decreased during aging; the cable with the lowest ac voltage breakdown also has the lowest impulse voltage breakdown. The dissimilar performance of the TR-XLPE cables and the excellent performance of the XLPE cable indicates evaluations at longer times are required to differentiate between modern TR-XLPE and XLPE insulated cables.     

Investigation of water effects on degradation of crosslinkedpolyethylene (XLPE) insulation

This paper presents the results of the study of the influence of moisture on the electrical characteristics of XLPE power cable insulation under various service conditions. Tap water was put into the cable conductors and the ends were properly closed by terminal boxes in the first case, and opened in the second case. The samples of cables were subjected to electric stress and heating. Results from the accelerated aging tests of XLPE cables in these conditions are reported with reference to the changing of the XLPE's electrical characteristics. On the basis of the compared performances of XLPE cables given by this investigation, the lifetime of XLPE cables was estimated in the case of service under these conditions. Results of testing indicate that the combined effects of pressure of water or water vapour, electric field and temperature will greatly accelerate the deterioration of XLPE insulation     

交联聚乙烯热老化与绝缘性能的关联关系

为研究交联聚乙烯（cross-linked polyethylene,XLPE）绝缘材料的热分解活化能、电气特性和力学特性随热老化程度变化的规律,对交流电力电缆绝缘用XLPE材料在110 ℃下开展加速热老化实验。采用热失重（thermogravimtric analyzer, TGA）测试手段,对XLPE在20~600 ℃的热分解行为进行研究;采用交流击穿测试、宽频介电谱测试及体积电阻率测试,研究老化后XLPE试样的电气特性;采用拉伸实验测试,研究老化后XLPE试样的力学特性。结果表明：热老化使得XLPE的交联结构和结晶状态被破坏,XLPE活化能呈减小趋势。由于氧化反应快速进行,使得XLPE分子链发生断裂,交联结构变弱,导致XLPE绝缘材料严重劣化,其活化能、击穿强度、体积电阻率、弹性模量和断裂伸长率随老化时间增长呈下降趋势,而介电常数、介电损耗和电导率呈增加趋势。