氧化铝体积分数对Al2O3f+Cf/ZL109混杂复合材料干滑动摩擦磨损行为的影响

利用挤压铸造法制备了Al₂O_3f+C_f/ZL109短纤维混杂金属基复合材料,并探讨了Al₂O₃纤维对该混杂复合材料干滑动摩擦磨损行为的影响。结果表明:混杂复合材料的摩擦系数以及从轻微磨损到急剧磨损转变的临界载荷均随着Al₂O₃体积分数的增加不断增大。在轻微磨损阶段,复合材料的主要磨损机制为犁沟磨损和层离,且Al₂O₃体积分数为12%时混杂复合材料的磨损率最低。发生严重磨损时,基体和复合材料的磨损机制均为严重的粘着磨损。     

三维编织超高分子量聚乙烯纤维-碳纤维混杂增强环氧树脂复合材料摩擦磨损性能

以超高分子量聚乙烯纤维(UHMWPE)-碳纤维(CF)三维混杂编织体为增强体,环氧树脂(ER)为基体,通过树脂传递模塑(RTM)工艺制备了三维编织混杂复合材料,研究了其摩擦磨损性能了,并采用混合正压力模型对摩擦系数进行了预测。结果表明,在纤维总体积含量一定的情况下,随着CF体积含量的增加,复合材料的摩擦系数增大,而其比磨损率降低。UH_3D/ER复合材料的磨损机制以粘着磨损为主,CF_3D/ER复合材料则以磨粒磨损为主,混杂复合材料的磨损机制主要取决于CF与UHMWPE纤维的相对含量 ,通过调节UHMWPE纤维和CF的体积比例可实现对复合材料摩擦磨损性能的有效调控。采用的计算模型可较好地预测UH_3D/ER的摩擦系数。     

石墨/CNTs增强铝基混杂复合材料的微观组织与摩擦磨损性能

采用粉末冶金法制备了石墨/碳纳米管(CNTs)增强铝基复合材料,研究了石墨和碳纳米管对复合材料摩擦磨损性能及硬度的影响,并利用扫描电子显微镜观察了复合材料的显微组织、磨损表面形貌。结果表明:仅添加石墨的复合材料摩擦系数明显降低,而磨损率、硬度有少量降低;但是将石墨和碳纳米管混杂加入到复合材料中后,材料的摩擦系数明显降低,磨损率急剧升高,且材料的硬度随碳纳米管含量增加而逐渐下降。仅添加石墨的复合材料磨损形式主要是磨粒磨损和犁沟磨损,而添加石墨和碳纳米管的复合材料主要是剥层磨损。     

铸造GrP?SiCP/ZA27混杂复合材料磨损行为的研究

本文研究了5vo l%G_rP 和10vo l%SiC_P 混合增强ZA 27复合材料滑动磨损行为。分折了在不同载荷(3～ 8kg)、不同滑动速度(0. 1～ 1m/s) 下的磨损机制, 并与SiC_P/ ZA 27复合材料和ZA 27基体合金作对比。试验结果表明: 混杂复合材料的耐磨性优于其它两种材料。这是因为G_rP 的加入提高了材料抗粘着和层离能力; 随着载荷或滑动速度的增大, 材质的磨面形貌和磨层结构发生变化, 由此得出其磨损机制也随之变化。     

纤维几何尺寸效应对聚合物基复合材料的摩擦磨损性能研究

采用碳纤维、芳纶浆粕和硫酸钙晶须为增强体,通过模压成型工艺制备了5种不同几何尺寸纤维体系的聚合物基复合材料。利用定速摩擦试验机和扫描电子显微镜研究了不同几何尺寸的纤维体系对聚合物基复合材料在无润滑条件下摩擦磨损性能和表面形貌的影响,以求探究聚合物基复合材料的摩擦磨损机理。结果表明:随着增强体系由单一纤维到混杂纤维,材料的摩擦系数和耐磨性先增大后减小;磨擦后表面逐渐疏松多孔,磨损率增大;适宜混杂比的纤维增强聚合物基复合材料的摩擦磨损性能较优。     

SiC 和Gr 颗粒混杂增强Al 基复合材料的摩擦磨损特性的研究

比较了SiC 和Gr 颗粒混杂增强Al 基复合材料的干摩擦磨损行为, 并与单一SiC_P 和单一G_rP 增强Al 基复合材料的相应行为进行了比较。结果表明, 在低载荷(< 30 N ) 时, SiC_P 和G_rP 能协调作用, 使混杂复合材料的摩擦系数和磨损率均比单一SiC_P 和G_rP 增强复合材料低。在较高载荷(30～ 120 N ) 时, 混杂复合材料磨损以剥层磨损机制为主, 摩擦系数比单一SiC_P 增强复合材料低, 磨损率比单一G_rP 增强复合材料低得多, 比单一SiC_P 增强复合材料高。混杂复合材料对偶件的磨损比单一SiC_P 增强复合材料低得多。      

硼酸铝晶须/双马来酰亚胺树脂摩擦磨损性能

研究了不同偶联剂及硼酸铝晶须添加量对硼酸铝晶须/双马来酰亚胺复合材料的摩擦磨损性能的影响。结果发现,硼酸铝晶须能有效地提高复合材料的耐磨性,晶须的加入使材料的磨损率明显降低;偶联剂对材料摩擦磨损性能的影响不明显;体系中添加硼酸铝晶须后随摩擦时间的延长复合材料的摩擦系数呈增大趋势。当晶须含量较小时摩擦机制主要是轻微的粘着磨损和疲劳磨损,当晶须含量大于8%时,疲劳磨损占主导地位,同时伴有粘着磨损和磨粒磨损。      

石墨/聚四氟乙烯/玻璃纤维改性PA6的力学和摩擦磨损性能

采用石墨(Gr)、聚四氟乙烯(PTFE)和玻璃纤维(GF)改性聚酰胺6(PA6),以提高PA6的摩擦磨损性能和力学性能。重点研究了填料组合、配比、载荷和转速对复合材料摩擦磨损性能的影响,通过磨损表面形貌分析探讨了摩擦磨损机理。结果表明:Gr/PTFE/GF混杂改性PA6能明显降低摩擦系数并提高耐磨性,PA6/Gr/PTFE/GF质量比为70/5/10/15时摩擦系数和磨损率最低,且在高转速(40N,1500r/min)下摩擦磨损性能更好,摩擦系数为0.08,比PA6降低了27%,磨损率为5.5×10~(-6) mm~3/(N·m),比PA6降低了1个数量级,且该复合材料的拉伸强度、冲击强度、储能模量和损耗模量都高于PA6。     

无压熔渗制备TiC/Ti3SiC2复合材料高速载流摩擦磨损性能

采用无压熔渗反应烧结技术制备了TiC/Ti₃SiC₂复合材料,通过HST-100型载流摩擦磨损试验机,在60~90 m/s滑动速度范围内,对TiC/Ti₃SiC₂复合材料的高速载流摩擦磨损性能进行了研究。结果表明：当与HSLA80配副时,TiC/Ti₃SiC₂的摩擦磨损性能与摩擦速度和TiC含量呈现出一定的相关性。当摩擦速度小于80 m/s时,摩擦表面出现具有减磨作用的熔融状态的均匀分布氧化膜（FeTiO₃和Fe_2.35Ti_0.65O₄）,呈现山脊及犁沟状形貌,磨损机制以磨粒切削磨损、氧化磨损及粘着磨损为主;当摩擦速度超过80 m/s时,摩擦表面出现不均匀分布的氧化膜,呈现孤峰状形貌,磨损机制以氧化磨损及电弧烧蚀磨损为主。相同实验条件下,摩擦系数随着TiC含量的增加而增大,磨损率随之降低。     

三维网络Al2O3增强球墨铸铁基复合材料摩擦磨损性能

采用SRV摩擦磨损试验机研究了球墨铸铁及三维网络Al₂O₃增强球墨铸铁基复合材料的干摩擦磨损性能, 测量了球墨铸铁和复合材料在不同摩擦频率及载荷下的摩擦系数和磨损率; 用扫描电镜观察磨损表面形貌, 并分析了三维网络Al₂O₃对复合材料磨损机制的影响。结果表明: 陶瓷与金属基体之间具有良好界面结合的三维网络Al₂O₃/球墨鋳铁复合材料, 其摩擦系数随载荷和摩擦频率的变化保持稳定; 复合材料的耐磨性能远优于球墨铸铁, 而且随着摩擦频率和载荷的增加, 复合材料的抗磨损性能明显提高。这是由于复合材料中陶瓷与金属相之间三维空间结构和良好的界面结合有利于摩擦载荷的传递; 金属基体中的石墨减摩作用保持摩擦系数的稳定; 三维陶瓷骨架在磨损表面形成硬的微突体并起承载作用, 制约了基体的塑性变形和高温软化, 有利于磨损表面氧化膜的留存。     

Effect of sliding distance on the wear and friction behavior of as cast and heat-treated Al–SiCp composites

The present investigation aims to evaluate the effect of sliding distance on the wear and friction behavior of as cast and heat-treated Al–SiCp composites using pin-on-disc wear testing machine, giving emphasis on the parameters such as wear rate and coefficient of friction as a function of sliding distance (0–5000 m) at different applied pressures of 0.2, 0.6, 1.0 and 1.4 MPa, and at a fixed sliding speed of 3.35 m/s. Characterizing the alloy and composites in terms of microstructure, X-ray diffraction analysis, microhardness and wear surface analysis. The results revealed that the heat-treated composite exhibited superior wear properties than the base alloy, while the coefficient of friction followed an opposite trend. Moreover, the wear rate of the composite is noted to be invariant to the sliding distance and increased with applied pressures. Microstructure of composite shows fairly uniform distribution of SiC particles in the metallic matrix. The hardness value of heat-treated composite increased 20–30% by addition of SiC particles to the alloy, intermetallic phases like Al₂Mg₃ and Al₂CuMg, etc., were obtained from X-ray analysis. The wear mechanism of the investigated materials was studied through worn surfaces examination of the developed wear tracks.     

碳纤维和二硫化钼混杂增强尼龙复合材料的摩擦学性能研究

以注塑成型法制备MoS₂和碳纤维混杂增强尼龙1010复合材料,采用MM-200型磨损试验机考察复合材料摩擦磨损性能。研究结果表明:在干摩擦条件下,MoS₂和碳纤维混杂可显著改善尼龙复合材料摩擦学性能,较小载荷下复合材料磨损以轻微磨粒磨损和疲劳磨损为主,较高载荷下复合材料则以热疲劳断裂剥落磨损为主。摩擦过程中MoS₂和对偶铁发生摩擦化学反应,生成和对偶底材具有较强结合能力的硫化亚铁和硫酸铁等,同时部分被氧化生成MoO₃。     

SiCp/A356铝基复合材料的磨损性能研究

在干摩擦条件下,对SiC颗粒含量20％的铝基复合材料在2～20 MPa载荷和200 r/min、400 r/min的滑动摩擦速度下进行摩擦系数及磨损率变化分析,并结合对磨损表面的SEM和EDS分析,探讨了SiC颗粒增强铝基复合材料的性能,并建立了在不同载荷和速度下的摩擦磨损机理图.研究表明,当载荷和摩擦速度都相对较低时,磨损表面主要为轻微的磨粒磨损,并伴随氧化磨损.当载荷达到10 MPa时,会发生轻微磨损向严重磨损转变,逐渐出现剥层磨损.最后在载荷为20 MPa、摩擦速度为400 r/min时,材料表面产生严重的粘着磨损.     

Effect of the SiC particle size on the dry sliding wear behavior of SiC and SiC–Gr-reinforced Al6061 composites

The effect of size of silicon carbide particles on the dry sliding wear properties of composites with three different sized SiC particles (19, 93, and 146 μm) has been studied. Wear behavior of Al6061/10 vol% SiC and Al6061/10 vol% SiC/5 vol% graphite composites processed by in situ powder metallurgy technique has been investigated using a pin-on-disk wear tester. The debris and wear surfaces of samples were identified using SEM. It was found that the porosity content and hardness of Al/10SiC composites decreased by 5 vol% graphite addition. The increased SiC particle size reduced the porosity, hardness, volume loss, and coefficient of friction of both types of composites. Moreover, the hybrid composites exhibited lower coefficient of friction and wear rates. The wear mechanism changed from mostly adhesive and micro-cutting in the Al/10SiC composite containing fine SiC particles to the prominently abrasive and delamination wear by increasing of SiC particle size. While the main wear mechanism for the unreinforced alloy was adhesive wear, all the hybrid composites were worn mainly by abrasion and delamination mechanisms.     

镍基复合材料在水环境中的摩擦学性能及磨损机理研究

本文考察了Ni-SiC-石墨系复合材料在水环境中的摩擦学性能,并研究其磨损机理.结果表明:复合材料在水环境中的摩擦系数比干摩擦降低了一半左右,磨损率仅为干摩擦下的1/15,水环境中,负荷和速度的变化对摩擦系数的影响不大,摩擦系数基本保持在0.28～0.32之间,磨损率随负荷和滑动速度的增加而不断增加.磨损表现为机械微切削;摩擦副表面吸附水的边界润滑作用以及水的冷却作用使材料容易耗散摩擦热,塑性变形减小,严重粘着磨损明显减轻.水的存在使不锈钢偶件更容易发生氧化,同时暴露于磨损表面的SiC以及由于水的渗透而导致与基体脱粘的SiC,易被氧化生成SiO2,进而SiO2发生水合反应在磨擦对偶表面生成不均匀的SiO2·nH2O水合反应膜,起到了一定的减磨润滑作用,显著降低摩擦系数和磨损率.     

Dry sliding wear behavior of spray deposited AlCuMn alloy and AlCuMn/SiCp composite

The dry sliding wear behavior of spray-deposited Al-Cu-Mn alloy and its composite reinforced with 13 vol.% SiC particles have been studied in the applied load of 5–400 N (corresponding normal stress is 0.1–8 MPa). It showed that SiC particle-reinforced AlCuMn composite produced by spray deposition process exhibited an improved wear resistance at the entire applied load range in comparison to the monolithic alloy. However, this improvement was not significant in the overall load range. With increasing the applied load, the wear rate of the composite and the monolithic alloy exhibited four different regions, therefore the wear was dominated by different wear mechanism. The former three regions all belonged to mild wear. The transition from mild to severe wear occurred at the similar critical load for both the composite and the monolithic alloy. For both the composite and the monolithic alloy, with increasing applied load, the dominant wear mechanism exhibited successively: oxidative mechanism, delamination mechanism, subsurface-cracking-assisted adhesive mechanism and adhesive mechanism.     

(Mg2B2O5w+ND)/ZK60镁基复合材料的摩擦磨损性能研究

在湿球磨条件下以600 r/min高能球磨混粉,并将球磨后的粉末经过热压烧结-热挤压成型制备(Mg2B2O5w+ND)/ZK60镁基复合材料。研究了(Mg2B2O5w+ND)/ZK60镁基复合材料在不同载荷和转速下的干摩擦磨损性能。结果表明:干摩擦条件下,材料的摩擦系数随着滑动距离的增加会经历跑和阶段和稳定阶段;材料的质量磨损率随着转速的增大而降低,随着载荷的增大而增大,且基体镁合金的质量磨损率始终低于复合材料。随着摩擦载荷和转速的增加,材料的摩擦系数减小,然后逐渐趋于平稳。混杂增强的镁基复合材料相比基体合金具有更低的摩擦系数。     

Dry sliding wear behaviour of zinc oxide reinforced magnesium matrix nano-composites

The main objective of the present work is to investigate the dry sliding wear behaviour of a magnesium matrix composite reinforced with zinc oxide nano-particles. Magnesium matrix composites have many applications, especially in the automotive and aerospace industries, due to their superior specific properties. A magnesium matrix composite with 0.5 vol.% ZnO nano-reinforcement was prepared using powder metallurgy and was hot extruded to eliminate pores. The wear behaviour of the Mg/ZnO nano-composite was investigated by conducting dry sliding tests as a function of wear with an oil-hardened non-shrinking (OHNS) steel disc as the counterpart on a pin-on-disc apparatus. Wear tests were conducted for normal loads of 5, 7.5 and 10 N at sliding velocities of 0.6, 0.9 and 1.2 m/s at room temperature. The variations of the friction coefficient and wear rate with the sliding distances (500 m, 1000 m and 1600 m) for different normal loads and sliding velocities were plotted and analysed. To study the dominant sliding wear mechanism for various test conditions, the worn surfaces were analysed using scanning electron microscopy. The wear rate was found to increase with the load and sliding velocity.