粘结MoS2固体润滑涂层的转动微动磨损特性

采用粘结法在LZ50钢表面制备MoS2固体润滑涂层,研究MoS2涂层及LZ50钢基体在干态不同角位移幅值下的转动微动磨损行为。在分析转动微动动力学特性的同时,结合光学显微镜、扫描电子显微镜、电子能谱仪以及轮廓仪对磨痕形貌进行微观分析。结果表明:涂层和基体的转动微动运行区域仅呈现部分滑移区(Partial slip regime,PSR)和滑移区(Slip regime,SR),未观察到混合区。涂层改变基体的微动运行区域,使得PSR缩小,SR运行区域向小角位移幅值方向移动。由于MoS2涂层的固体润滑作用,涂层的摩擦因数在整个试验过程都明显低于基体。在PSR,涂层损伤轻微;在SR,涂层的转动微动磨损机制主要表现为剥层和摩擦氧化。研究表明粘结MoS2固体润滑涂层具有明显的防护作用,显著降低LZ50钢的转动微动磨损。     

Study on rotational fretting wear of bonded MoS2 solid lubricant coating prepared on medium carbon steel

The rotational fretting wear behaviors of the bonded MoS₂ solid lubricant coating and its substrate steel were comparatively studied under varied angular displacement amplitudes, constant normal load, and rotational speed. Dynamic analysis in combination with microscopic examinations was performed through SEM, EDX, XPS, optical microscope, and surface profilometer. The experimental results showed MoS₂ changed the fretting running regimes of substrate. The friction coefficients of MoS₂ were lower than those of the substrate. For MoS₂, the damage in partial slip regime was very slight. The damage mechanism of the coating in slip regime was main abrasive wear, delamination, and tribo-oxidation.     

Torsional Fretting Wear Behavior of Bonded MoS2 Solid Lubricant Coatings

The effects of applying a bonded MoS₂ solid lubricant to a 1050 steel substrate were investigated using a torsional fretting wear apparatus. Tests were conducted under a normal load of 50 N with angular displacement amplitudes ranging from 0.1 to 5°. Wear scars were examined using scanning electron microscopy, energy-dispersive X-ray spectrometry, optical microscopy, and surface profilometry. The MoS₂ coating exhibited different torsional fretting regimes than those of the substrate. Fretting regimes of the coating were primarily in the partial slip regime (PSR) and the slip regime (SR) with no mixed fretting regime. The width of the PSR narrowed. Due to the lubricating effects of the coating, the friction torque was consistently lower than that of the substrate. The damage to the coating in the PSR was very slight, and its granular structure remained even after 1,000 cycles. The damage mechanism to the SR coating was a combination of abrasive wear, oxidative wear, and delamination. The MoS₂ coating had potential to alleviate torsional fretting wear.     

Fretting Wear Behavior of Medium Carbon Steel Modified by Low Temperature Gas Multi-component Thermo-chemical Treatment

The introduction of surface engineering is expected to be an effective strategy against fretting damage. A large number of studies show that the low gas multi-component (such as carbon, nitrogen, sulphur and oxygen, etc) thermo-chemical treatment(LTGMTT) can overcome the brittleness of nitriding process, and upgrade the surface hardness and improve the wear resistance and fatigue properties of the work-pieces significantly. However, there are few reports on the anti-fretting properties of the LTGMTT modified layer up to now, which limits the applications of fretting. So this paper discusses the fretting wear behavior of modified layer on the surface of LZ50 (0.48%C) steel prepared by low temperature gas multi-component thermo-chemical treatment (LTGMTT) technology. The fretting wear tests of the modified layer flat specimens and its substrate (LZ50 steel) against 52100 steel balls with diameter of 40 mm are carried out under normal load of 150 N and displacement amplitudes varied from 2 μm to 40 μm. Characterization of the modified layer and dynamic analyses in combination with microscopic examinations were performed through the means of scanning electron microscope(SEM), optical microscope(OM), X-ray diffraction(XRD) and surface profilometer. The experimental results showed that the modified layer with a total thickness of 60 μm was consisted of three parts, i.e., loose layer, compound layer and diffusion layer. Compared with the substrate, the range of the mixed fretting regime(MFR) of the LTGMTT modified layer diminished, and the slip regime(SR) of the modified layer shifted to the direction of smaller displacement amplitude. The coefficient of friction(COF) of the modified layer was lower than that of the substrate in the initial stage. For the modified layer, the damage in partial slip regime(PSR) was very slight. The fretting wear mechanism of the modified layer both in MFR and SR was abrasive wear and delamination. The modified layer presented better wear resistance than the substrate in PSR and MFR; however, in SR, the wear resistance of the modified layer decreased with the increase of the displacement amplitudes. The experimental results can provide some experimental bases for promoting industrial application of LTGMTT modified layer in anti-fretting wear.     

基于双重扩展自适应卡尔曼滤波的汽车状态和参数估计

准确实时地获取行驶过程中的状态信息是汽车动态控制系统研究的关键,为此提出了一种新的汽车状态估计器。建立了包含不准确模型参数和未知时变统计特性噪声的非线性汽车动力学模型,针对该非线性系统提出一种双重扩展自适应卡尔曼滤波算法（DEAKF）。该算法采用两个卡尔曼滤波器并行运算,状态估计和参数估计互相更新,同时将带遗忘因子的噪声统计估值器嵌入到状态校正过程和参数校正过程之间,以解决系统的噪声时变问题。基于ADAMS的虚拟试验和实车试验结果表明,该算法的状态估计精度高于EKF方法和DEKF方法的状态估计精度,同时具有良好的模型参数校正能力,对汽车动态控制系统中估计器的设计具有理论指导意义。
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High temperature fretting wear behavior of WC-25Co coatings prepared by D-gun spraying on Ti-Al-Zr titanium alloy

Detonation gun (D-gun) spraying is one of the most promising spraying techniques for producing wear-resistance coatings. A thick layer (about 0.3 mm thickness) of WC-25Co with high hardness was covered on Ti-Al-Zr titanium alloy by D-gun spraying and the fretting wear behavior of WC-25Co coatings was studied experimentally on a high precision hydraulic fretting wear test rig. An experimental layout was designed to perform fretting wear tests at elevated temperatures from room temperature (25 °C) to 400 °C in ambient air. In the tests, a sphere (Si₃N₄ ceramic ball) was designed to rub against a plane (Ti-Al-Zr titanium alloy with or without WC-25Co coatings). It was found that the fretting running regimes of WC-25Co coatings were obviously different from those of Ti-Al-Zr titanium alloy. The mixed fretting regime disappeared in WC-25Co coatings, and the boundaries in the running condition fretting map (RCFM) showed hardly any change as temperature increased. The worn scars were examined using a laser confocal scanning microscope (LCSM), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). The results showed that the coefficients of friction (COF) of WC-25Co coatings at elevated temperatures were nearly constant in the partial slip regime and very low in the steady state. The fretting damage of the coatings was very slight. In the slip regime, the WC-25Co coatings exhibited a good wear resistance, and the wear volume of the coatings obviously decreased with increasing tested temperature. The fretting wear mechanisms of WC-25Co coatings were delamination, abrasive wear and oxidation wear at elevated temperature. The oxide debris layer formed at higher temperature was denser and thicker on top of WC-25Co coatings, thus providing more surface protection against fretting wear, which played an important role in the low fretting wear of the coatings.     

聚四氟乙烯基粘结固体润滑涂层微动磨损性能研究

在不同位移幅值与载荷条件下研究了酚醛环氧粘结聚四氟乙烯(PTFE)基固体润滑涂层的微动磨损特性，并利用扫描电子显微镜、表面轮廓仪和傅里叶表面红外仪等对涂层磨斑进行分析。结果表明，粘结PTFE基涂层具有良好的抗微动损伤性能，随循环次数的变化只存在部分滑移区和滑移区，部分滑移区的损伤轻微，滑移区的损伤强烈依赖于栽荷，其损伤与PTFE分子链在往复交变载荷作用下的疲劳断裂相关。     

Oil-Lubricated Fretting Behaviors of 304 Stainless Steels under Different Fretting Strokes and Normal Loads

The influence of oil lubrication on the fretting wear behaviors of 304 stainless steel flat specimens under different fretting strokes and normal loads has been investigated. The results proved that fretting regimes and fretting wear behaviors of 304 stainless steels were closely related to the fretting conditions. In general, the increase in normal load could increase wear damage during sliding wear. However, according to the results, a significant reduction in wear volume and increase in friction coefficient was observed when the normal load was increased to critical values of 40 and 50 N at a fretting stroke of 50 μm due to the transformation of the fretting regime from a gross slip regime to partial slip regime. Only when the fretting stroke further increased to a higher value of 70 μm at 50 N, fretting could enter the gross slip regime. There was low wear volume and a high friction coefficient when fretting was in the partial slip regime, because oil penetration was poor. The wear mechanisms were fatigue damage and plastic deformation. There was high wear volume and low friction coefficient when fretting was in the gross slip regime, because the oil could penetrate into the contact surfaces. Unlike the wear mechanisms in the partial slip regime, fretting damage of 304 stainless steels was mainly caused by abrasive wear in the gross slip regime.     

TiAlZr合金微动磨损性能研究

采用高精度液压式微动磨损试验机研究了TiA lZr合金在不同微动运行区域的微动磨损行为,建立了其运行工况微动图。试验结果表明:滑移区、混合区和部分滑移区的摩擦因数随循环次数变化呈现不同的规律,其中部分滑移区摩擦因数较低,磨损体积随着位移幅值的增大而增大;滑移区、混合区磨损体积随着法向载荷的增加而增大,而部分滑移区磨损体积随着法向载荷的增加而减小;滑移区磨屑堆积于中心区域,磨损以磨粒磨损和剥层机制为主;混合区磨损机制主要表现为粘着磨损与磨粒磨损并存;部分滑移区磨损轻微。     

粘结石墨固体润滑涂层微动磨损性能研究

在不同位移幅值与载荷下研究了粘结石墨固体润滑涂层的微动磨损特性，并利用扫描电镜和X射线衍射仪分析了涂层微动磨斑。结果表明：粘结石墨涂层具有良好的抗微动损伤性能，随循环次数的变化只存在部分滑移区和滑移区，部分滑移区涂层损伤轻微；滑移区损伤严重，主要表现为裂纹萌生和扩展，最终按剥层机制呈层状剥落。     

桨-毂轴承材料扭动微动磨损行为研究

采用面接触扭动微动形式,以动力定位系统可调距螺旋桨桨-毂轴承摩擦副材料(CuNiAl-42CrMo4)为对象,以不同的角位移幅值模拟海水波动影响下的微动磨损行为,并结合扫描电子显微镜和超景深三维显微镜对磨痕形貌进行分析,探究桨-毂轴承摩擦副材料扭动微动磨损规律。结果表明,随着角位移幅值的增加,扭动微动依次运行于部分滑移区、混合区、滑移区,摩擦因数减小,同时磨损量增加,微动损伤中剥层机制所占的比例逐渐增加,且由于疲劳裂纹扩展的不利影响,实际运行过程中要尽量避开混合区。     

On the mechanisms of various fretting wear modes

According to relative motion directions for a ball-on-flat contact, there are four fundamental fretting wear modes, e.g., tangential, radial, torsional and rotational modes. In this paper, the mechanisms of these four fundamental fretting wear modes, particularly for the later three modes, have been reviewed from results obtained by the authors in combination with results from literature. Some general features have been reported. Differences both in running and degradation behavior have been discussed in detail. Results showed that some similar laws for three fretting regimes (partial slip regime, mixed regime and slip regime), fretting maps (running condition fretting map and material response fretting map), wear and cracking mechanisms obtained from the classic mode (i.e. tangential fretting) were also identified and useful to characterize the other modes. Nevertheless, the occurrence of relative slip for the radial fretting, the formation of mixed regime for the torsional fretting, the evolution of surface morphology for the rotational fretting were quite different compared to that of the classical fretting mode.     

690合金材料的微动磨损特性研究

利用微动磨损试验机,在载荷50N以及位移幅值为60μm、100μm、150μm的工况下,研究了690合金材料在常温下的微动磨损行为及其动力学特性,采用激光共焦扫描显微镜(LCSM)和扫描电子显微镜(SEM)观察磨痕微观形貌。结果表明,载荷和位移幅值对微动特征有很大的影响,微动运行完全处于滑移状态。在滑移区,滑移磨损严重、磨痕面积大。690合金材料的磨损机制主要表现为磨粒磨损与剥层的共同作用。     

Effect of Cold Rolling on the Fretting Wear Behavior and Mechanism in Inconel 690 Alloy

The influence of cold rolling on the fretting wear behavior and mechanism of Inconel 690 alloy at 320?°C in air was studied. The wear volume and worn surface were obtained and analyzed using laser scanning confocal microscopy, electron back-scattering diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The grinding surface and strain distribution were also studied by electron back-scattering diffraction to analyze the mechanism of fretting damage. The results indicated that with an increase in cold rolling reduction, the microhardness was increased. However, the friction coefficient and wear volume first increased and then decreased. The characteristics of fretting areas changed from a gross slip regime to a partial slip regime. Accordingly, the damage mechanism in the gross slip regime was a combination of oxidative wear, abrasive wear, and delamination, whereas the damage mechanism in the partial slip regime was mainly adhesive wear.     

Fretting wear behavior of superelastic nickel titanium shape memory alloy

The fretting behavior of superelastic nickel titanium (NiTi) shape memory alloy was studied at various displacement amplitudes on a serve-hydraulic dynamic test machine. The results showed that the superelastic properties of the material played a key role in the observed excellent fretting behavior of NiTi alloy. Due to the low phase transition stress (only 1/4 the value of its plastic yield stress) and the large recoverable phase transition strain (5%) of NiTi, the friction force of NiTi/GCr15 stainless steel pair is smaller than the value of GCr15/GCr15 pair and at the same time the Rabinowicz wear coefficient of NiTi plate is about 1/9 the value of GCr15 plate under the same fretting conditions. For NiTi/GCr15 pair, even NiTi has a much lower hardness than GCr15, the superelastic NiTi alloy exhibits superior fretting wear property than GCr15 steel. It was found that the weak ploughing was the main wear mechanism of NiTi alloy in the partial slip regime. While in the mixed regime and gross slip regime, the wear of NiTi was mainly caused by the abrasive wear of the GCr15 debris in the three-body wear mode.     

Development of a test device for the evaluation of fretting in point contact

Fretting wear and fatigue may occur between any two contacting surfaces, wherever short‐amplitude reciprocating sliding is present for a large number of cycles. A test device has been developed for the evaluation of fretting fatigue and wear in partial and gross slip conditions. Three similar sphere‐on‐plane contacts run at the same time. Normal force, tangential force or displacement amplitude and constant bulk stress can be controlled and measured separately. Reciprocating tangential displacement is produced with rotational motion, the amplitude and frequency of which can be adjusted and controlled accurately by an electric shaker. The number of load cycles for crack initiation and growth is determined with strain‐gauge measurements near the fretting point of contact. The contact surfaces are measured with 3D optical profilometer before fretting measurements to determine actual contact geometry. The measurements were done with quenched and tempered steel. The initial results indicate that cracks are mostly formed in partial slip conditions, whereas fretting wear is more heavily involved in gross slip conditions. The initiation of a crack occurs near the edge of the contact in the slip direction, where the calculated cracking risk has its maximum value in partial slip conditions. The number of cracks increases as the displacement amplitude, i.e. friction force, increases in partial slip conditions. Copyright © 2008 John Wiley & Sons, Ltd.     

Study on rotational fretting wear of 7075 aluminum alloy

Rotational fretting wear tests in a ball-on-flat configuration have been successfully realized on a special rotational fretting rig developed from an ultra-low-speed reciprocating rotational driver. The rotational fretting behavior of 7075 aluminum alloy against 52 100 steel was studied under different angular displacement amplitudes and normal loads. The results showed that both F_t?θ and F_t/F_n curves can be used to characterize the rotational fretting running behavior, which exhibited different curve shapes and variation trends in different fretting running regimes. The rotational fretting behavior of 7075 aluminum alloy was strongly dependent on the angular displacement amplitude, normal load and number of cycles. The wear of 7075 aluminum alloy was characterized by slight attrition in the partial slip regime, while a combination of delamination, abrasive and oxidative wear was found in the slip and mixed fretting regimes. The formation of a central bulge probably due to plastic flow was observed under gross slip condition of the rotational fretting mode.     

AZ91D镁合金微动磨损特性研究

采用液压高精度材料试验机考察了平面一球面接触的AZ91D镁合金摩擦副的微动磨损行为，分析了位移幅值、法向载荷和频率等参数对摩擦因数和磨损体积的影响，考察了不同实验条件下的磨斑形貌，并探讨了其磨损机理。结果表明：AZ91D镁合金的微动区域可分为部分滑移区、混合区和滑移区3个区域，粘着磨损、疲劳磨损和磨粒磨损分别是3个区域的主要磨损机制；磨损体积随着位移幅值和法向载荷的增加而增大，但却随着频率的增大而减小。在微动部分滑移区和混合区，摩擦因数随着位移增大迅速增加；在微动滑移区，摩擦因数随法向载荷的增大而减小，而位移幅值和频率对摩擦因数的影响较小。     

不同水介质下GCr15/45#钢微动腐蚀行为研究

在洁净水、酸性水和海水3种不同水介质条件下，对GCr15／45^#钢进行了不同位移幅值的微动磨损试验。结果表明：洁净水和酸性水改变了微动区域，降低了摩擦系数和磨损量，具有润滑效果，磨损受水润滑和介质腐蚀双重作用影响,且润滑作用随位移幅值的增加而减弱；对海水，摩擦系数与干态相近,电化学腐蚀作用强烈，磨痕中可观察到大量点蚀坑。     

四种核电用包壳材料的微动磨损性能研究

在切向微动磨损试验机上对4种核电用包壳材料(Zr合金、Zr/Cr涂层、FeCrAl和ODS-FeCrAl)进行切向微动磨损试验,考察不同包壳材料的微动磨损特性.研究结果表明:不同包壳材料的摩擦因数、耗散能曲线和形变有显著差异;4种包壳材料在切向微动过程中均处于部分滑移区.通过分析磨痕微观形貌和磨痕轮廓,发现ODS-Fe...