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合成了不同TMPAC和AlCl3摩尔比的TMPAC-AlCl3离子液体,并测定了其在不同温度下的电导率。在摩尔比为1:2的TMPAC-AlCl3离子液体中进行了恒电流电沉积实验,研究了温度、电流密度、搅拌速度和添加剂甲苯等对沉积层的影响。结果表明:在相同条件下摩尔比为1:2的TMPAC-AlCl3离子液体电导率最大,当温度为80℃,电流密度为20 mA·cm-2,搅拌速度为500 r·min-1时,沉积层质量较好且电流效率较高;甲苯的加入,增大了TMPAC-2AlCl3离子液体的电导率,降低了槽电压,当添加甲苯的体积分数为50%,电流密度为23 mA·cm-2时,可以得到较为致密、色泽良好、平整而均匀的沉积层。 相似文献
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针对高性能聚合物尼龙6材料的选择性激光烧结(SLS)工艺,研究了不同激光功率与扫描速度对成型件致密度的影响并进行了工艺优化。实验中激光功率10~50 W,扫描速度1 000~5 000 mm/s,其他工艺参数保持恒定。引入能量密度对激光功率与扫描速度的综合作用进行研究。结果表明:随着激光功率的增加或扫描速度的增大,制件的致密度呈现先增大后减小的趋势;随着能量密度的增加,制件的致密度呈现先增大后减小的趋势。在不同工艺参数下,获得制件的最大致密度为86.74%,此时激光功率为30 W,扫描速度为2 000mm/s,能量密度为0.043 J/mm^2。选定致密度为衡量指标,通过响应面回归分析模型建立了激光功率、扫描速度与致密度的优选工艺图谱,得到最优的工艺参数为激光功率45 W,扫描速度3 465 mm/s,此时预测的制件致密度为88.971%。 相似文献
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为研究七喷嘴气化炉的流场分布,建立了顶置七喷嘴气化冷模试验装置,采用激光粒子成像测速系统(PIV)在气化炉的上部、中部及下部视窗进行了流场测试,比较分析了颗粒流量、分散风流量对气化炉流场的影响。结果表明,在颗粒流量20~150 kg/h,分散风流量740~880 m3/h的工艺条件下,气化炉上部流场呈现自由射流特点,射流长度为40 cm,平均射流速度为25 m/s,中下部流场则以返混区为主,流速在8 m/s以下;颗粒流量增大会使得最大射流速度由40 m/s降低至15 m/s,且气化炉上部射流粒子束的径向脉动增强,造成射流弥散;分散风流量增大使得最大射流速度由25 m/s增至35 m/s,射流长度无明显变化。颗粒流量和分散风流量对流场的影响主要体现在气化炉上部,对中下部流场的影响逐渐减弱。 相似文献
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采用玻碳/铂为惰性阳极,以1-丁基-3-甲基咪唑氯盐([BMIM]Cl/AlCl3)离子液体体系为电解液,研究了离子液体电解铝工艺,优化了电解工艺条件,探讨了电解影响因素。结果表明,当电解液[BMIM]Cl∶AlCl3摩尔比为1∶2.00时,随着温度的升高,铝的沉积槽电压逐渐减小,电流密度增加,但电解液的稳定性减弱,当温度达到90℃时,电解液分解明显。当电解温度一定时,随着[BMIM]Cl∶AlCl3摩尔比的增加[(1∶1.25)~(1∶2.00)],电流密度增加。通过赫尔槽实验,SEM、XRD分析了电解铝的沉积形貌和晶相结构。随电流密度的逐渐减小,沉积层变薄,晶相结构变化不大;相同电流密度区随温度的升高,沉积层逐渐变得粗糙。计算了不同槽间距下的槽压与电流密度的关系。 相似文献
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The electrodeposition of Zn-Co alloy deposits was studied by means of pulse-plating technique. The surface morphologies of Zn-Co alloy deposits were examined using scanning electron microscopy (SEM), and an attendant energy dispersive X-ray analyser (EDA) was used to analyse the composition of Zn-Co alloy deposits. Results obtained showed that the average current density and reverse current density amongst all the variables investigated had very strong effects on the cobalt content in the Zn-Co alloy deposits. It is possible to electrodeposit Zn-Co alloy coatings with a very wide cobalt content range of 10-90 wt.% by modulating pulse parameters. Grain size, surface appearance and internal stress in the deposits were also improved significantly by introducing reverse current. 相似文献
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添加剂对喷射电沉积纳米晶Co-Ni合金的影响 总被引:1,自引:0,他引:1
在氯化镍-硫酸钴体系电解液中采用添加剂喷射电沉积纳米晶Co-Ni合金,测定了其阴极极化曲线.研究了添加剂对阴极过电位、电流效率、镀层中Co含量、镀层的相结构、晶粒尺寸、表面形貌及显微硬度、软磁性能等影响.结果表明:添加剂增加了极化作用,影响了Co、Ni电沉积的动力学过程.当添加剂为2.5g/L时,与未加添加剂相比较,阴极过电位从3.594V增大到4.755 V,电流效率和沉积层中Co含量变化不大,但沉积层晶粒尺寸从12.8 nm明显降低到5.5 nm,维氏硬度从423升高到511,同时Co-Ni合金的软磁性能得以提高. 相似文献
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The jet electrodeposition from watts baths with a device of electrolyte jet was carried out to prepare nano-crystalline cobalt-nickel alloys. The influence of the concentration of Co2+ ions in the electrolyte and electrolysis parameters, such as the cathodic current density, the temperature as well as the electrolyte jet speed, on the chemistry and microstructure of Ni-Co-deposit alloys were investigated. Experimental results indicated that increasing the Co2+ ions concentration in the bath, the electrolyte jet speed and decreasing of the cathodic current density and decrease of the electrolyte temperature all results in an increase of cobalt content in the alloy. Detailed microstructure changes upon the changes of alloy composition and experimental conditions were characterized using X-ray diffraction (XRD) and transmission electron microscopy (TEM). XRD results show the Ni-Co solid solution was formed through the jet electrodeposition. Phase constitution of solid solution changes progressively under different electrolyte concentration. Alloys with low Co concentration exhibit single phase of face-centered cubic (fcc) structure; The Co concentration over 60.39 wt.%, the alloys are composed of face-centered cubic (fcc) phase and hexagonal close-packed (hcp) phase. Furthermore, the formation of the nanostructured Ni-Co alloy deposit is investigated. Increasing the Co2+ ions concentration in the bath, the cathodic current density, the electrolyte temperature and the electrolyte jet speed all result in the finer grains in the deposits. Additives such as saccharin in the electrolyte also favor the formation of the finer grains in the alloy deposits. 相似文献
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利用高速摄像仪对二维喷嘴内稠密气固射流稳定性进行了实验研究,考察了颗粒粒径、料仓压力以及喷嘴收缩角等因素对射流流动模式及稳定性的影响。结果表明:对于颗粒粒径为78μm的气固射流,随着料仓压力的增大,射流出口速度增大,射流固含率降低,在料仓压力≥0.03MPa、射流速度≥4.82m/s、射流固含率≤0.168时,喷嘴内稠密气固射流出现气泡型的不稳定流动模式;随着颗粒粒径的增大,气固射流固含率降低,喷嘴内稠密气固射流从气泡模式转变为颗粒团不稳定流动模式;改变喷嘴收缩角对射流不稳定模式影响不大。利用微型压力传感器对喷嘴直管不同位置压力进行测量,结果表明压力脉动主要是由于气固射流中气泡及颗粒团的产生及演变导致的。研究表明,随着料仓压力增大,颗粒在喷嘴内向下运动过程中压降增加,渗透进颗粒流的气体分率增加,将导致喷嘴内气固相互作用增强,进而引起气固射流不稳定。 相似文献
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Reinhard Böck Gloria Lanzinger Renate Freudenberger Thomas Mehner Daniela Nickel Ingolf Scharf Thomas Lampke 《Journal of Applied Electrochemistry》2013,43(12):1207-1216
Electrodeposition of palladium from a non-aqueous electrolyte solution [choline chloride/urea/palladium(II)chloride] has been carried out by direct and pulse current electroplating. In this study, the influence of an organic additive (nicotinic acid amide), current mode (direct current or pulse current deposition) and hydrodynamic on the surface morphology of electroplated palladium films was investigated. In order to determine the surface morphology and thickness of the electrodeposited palladium layers, a scanning electron microscope and an energy dispersive X-ray fluorescence spectroscope were used. In addition, the cell voltage during the different electrodeposition experiments was recorded and analysed. The experimental results showed that the surface morphology of the palladium deposits could be remarkably affected either by addition of the additive or by applying pulse current. Pulse plating and the selected inhibitor mutually interfere with each other, causing changes in the microstructure of the palladium deposits (e.g. smoothening or forming of micro-cracks). It was possible to optimise the palladium deposit quality by applying pulse current or by addition of the appropriate inhibitor. 相似文献
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利用FLUENT软件对1300 mm′230 mm的板坯结晶器建立了三维稳态数学模型,以流体表面流速和射流冲击深度作为主要参考指标,研究了水口的特性及拉速、水口浸入深度对该水口作用下结晶器内流场的影响. 结果表明,A水口作用下具有表面流速大,射流冲击深度小,液面波动大,卷渣的可能性大等特点,且随拉速的增加而逐渐增大;随拉速的增加,结晶器内最大表面流速以0.06 m/s的幅度逐渐增大,射流冲击深度呈减小趋势,在150, 170和190 mm浸入深度下,结晶器液面表面流速最大值分别为0.599, 0.518和0.465 m/s,射流冲击深度分别为385, 410和420 mm,随水口浸入深度的增加,结晶器内表面流速逐渐减小,射流冲击深度逐渐增加;在实际生产过程中,使用A水口时应适当降低拉速、增大水口浸入深度;在高拉速的情况下,需用平行水口替换A水口. 相似文献
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The influence of pulse electrodeposition parameters (current on-time Ton, current off-time Toff, and pulse current density Jp) was investigated on the surface morphology and grain size of zinc electrodeposited from a sulfate bath containing polyacrylamide and thiourea additives. The grain size and surface morphology of zinc deposits were studied by field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM), and the preferred orientation of the deposits was studied by X-ray diffraction. At constant current off-time and pulse current density, the grain size decreased asymptotically with increasing current on-time. In contrast, increase in the current off-time at constant current on-time and pulse current density resulted in grain growth. A progressive decrease of the grain size was observed with increasing pulse current density at constant current on-time and off-time. Nanocrystalline zinc with an average grain size of 38 nm was obtained at a pulse current density of 1200 mA/cm2. The crystallographic orientations developed were correlated with the change in the cathodic overpotential, the angle between the preferred oriented plane and the lowest energy of formation plane (0 0 0 2), and the pulse electrodeposition parameters. 相似文献
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This paper deals with jet electrodeposition for the production of maskless deposits and patterns of a well-defined shape,
and the potential improvements allowed by a pulsed laser beam. On the basis of the example of zinc deposition in a sulphate
medium, several aspects of this type of deposition (mass transfer rate, i-E curves, morphology of the deposit, and the effect of a pulsed YAG laser beam at 532 nm) are presented. Laser assistance has
no significant effect on the deposition current. Pulsed irradiation improves zinc morphology by an appreciable grain coalescence
and a reduction in grain size; this results in increased precision of the maskless deposits, the central zones of which are
as wide as the nozzle. 相似文献
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S.O. Moussa M.A.M. Ibrahim S.S. Abd El Rehim 《Journal of Applied Electrochemistry》2006,36(3):333-338
Induced electrodeposition of Ni–W alloys was carried out onto steel substrates from acidic citrate baths (pH 4.5) under different
conditions of concentration of electrolyte, current density and temperature. Bright and highly adherent Ni–W deposits were
successfully obtained with a relatively high cathodic current efficiency CCE (80–85%). The CCE increases greatly with increasing
pH and Ni2+ ion content in the bath. The W% in the alloy deposits is in the range of 4–20 wt% depending on the operating condition. The
W content in the deposit was found to increase with an increase in Ni2+ ion content, pH and temperature. The surface morphology was examined by scanning electron microscopy while the structure
of the alloy was examined by X-ray diffraction analysis. 相似文献