生物电阻抗铜片电极的化学刻蚀工艺(英文)

为获得具有强稳定性能的生物电阻抗电极,采用化学刻蚀加工方法,制造出表面具有一系列微结构的金属铜片电极。通过改变加工工艺参数的方法,着重分析刻蚀时间、刻蚀温度、刻蚀液体浓度、样品尺寸等刻蚀工艺参数对铜片电极的蚀刻速率和表面微结构的影响。结果表明:刻蚀速率将随着刻蚀时间的延长而逐渐降低,随着刻蚀温度的升高而逐渐升高,而刻蚀样本尺寸对刻蚀速率的影响不大。选用合适的刻蚀液体浓度(组分3),在室温条件下刻蚀20min,可以获得具有丰富表面微结构的铜片电极。另外,进行24h电极对接的连续性交流阻抗测试,与心电电极相比,利用化学刻蚀加工的铜片电极,由于表面具有丰富的表面微结构,可以形成可靠的表面接触,从而具有稳定的交流阻抗值。     

Low Temperature Growth of GaAs on Si byIon Beam Cluster Technique

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Ar+离子束对U薄膜表面粗糙度的影响

采用Ar+离子束对U薄膜表面进行反应溅射,通过白光干涉仪和台阶仪的测量与分析,着重研究Ar+离子束溅射能量、入射角度对其表面粗糙度Ra的影响,并与Ar+离子束刻蚀试验进行比对.结果表明,以30°角入射,随溅射时间的增加,能量为0.5 keV的Ar+离子束较1.0 keV对U薄膜表面粗糙度趋于减小,表面愈光滑,溅射深度仅限于纳米级,而与金属Mo的刻蚀效果相比与之相反.Ar+离子束溅射对材料表面具有超精细抛光的效果,辅之于离子束微米级刻蚀减薄,将有助于U薄膜表面精细加工.     

表面形貌对TB8钛合金/环氧树脂粘结性能的影响

目的 通过在基体表面构建出不同的微观结构,提升环氧树脂与钛合金的粘结强度。方法 采用等离子刻蚀设备,调节气体流量、处理时间、RF功率对TB8钛合金样品进行处理,并对处理过的样品进行单搭接接头制备。利用扫描电子显微镜对等离子刻蚀前后的样品表面形貌进行研究,利用XPS分析刻蚀前后样品表面化学成分变化,利用水接触角表征样品表面润湿性,利用电子万能试验机对等离子刻蚀处理后的样品与环氧树脂的粘结强度进行研究。结果 采用CF4对样品进行等离子化学刻蚀,不同的刻蚀时间形成了不同类型的表面微观结构,其中圆粒状结构比蜂窝坑结构表面的粘结性能优越。采用Ar对样品进行等离子溅射刻蚀,样品表面形成纳米级片状微坑结构。等离子刻蚀后,基体表面更加洁净,活性增强,水接触角基本降为0°,润湿性显著提升。等离子刻蚀处理前,样品与环氧树脂的粘结强度为5.32MPa;等离子刻蚀处理后,样品与环氧树脂的粘结强度可达23.25 MPa,而经喷砂后,等离子刻蚀处理的样品与环氧树脂的粘结强度高达30.29 MPa。最佳等离子刻蚀处理工艺参数为RF功率540 W,气体流量120 mL/min,处理时间50 min,喷砂后最佳等离子刻...     

Application of surface charge lithography to nanostructuring of GaN epilayers

It is shown that treatment of GaN epilayers by a low energy low dose focused ion beam with subsequent photoelectrochemical etching represent an efficient tool for GaN nanostructuring. Direct “writing” of a surface negative charge trapped by radiation defects allows one to fabricate thin GaN walls with a thickness as low as 100 nm using focused ion beam treatment. The obtained results show that the undercut etching inherent to GaN etching through windows defined by surface charge lithography depends on the depletion length in the doped GaN material and does not occur in the structures below a critical size of 200 nm in our case. The text was submitted by the authors in English.     

Microstructure, Morphology, and Nanomechanical Properties Near Fine Holes Produced by Electro-Discharge Machining

Fine holes in metal alloys are employed for many important technological purposes, including cooling and the precise atomization of liquids. For example, they play an important role in the metering and delivery of fuel to the combustion chambers in energy-efficient, low-emission diesel engines. Electro-discharge machining (EDM) is one process employed to produce such holes. Since the hole shape and bore morphology can affect fluid flow, and holes also represent structural discontinuities in the tips of the spray nozzles, it is important to understand the microstructures adjacent to these holes, the features of the hole walls, and the nanomechanical properties of the material that was in some manner altered by the EDM hole-making process. Several techniques were used to characterize the structure and properties of spray-holes in a commercial injector nozzle. These include scanning electron microscopy, cross sectioning and metallographic etching, bore surface roughness measurements by optical interferometry, scanning electron microscopy, and transmission electron microscopy of recast EDM layers extracted with the help of a focused ion beam.     

不同工艺制备的铁电薄膜底电极Pt／Ti

采用高真空电子束蒸与直流溅射在ＳｉＯ２／Ｓｉ基底上制备Ｐｔ／Ｔｉ底电极,对Ｐｔ／Ｔｉ在不同热处理温度下的结构与形貌进行对比研究。结果表明;由于采用不同的制备工艺,Ｐｔ晶粒在成核与生长方式上有所不同,导致了Ｐｔ薄膜在结构与形貌的差异。     

Effects of Ag nanoshape and AgGa phase in Ag-Si nanostructure using 2-step etching process

The etching scale was controled by the layball process and a focus ion beam (FIB) was used to investige the dry-wet etching (DWE) mechanism. Increasing the beam current of dry-etching raised the height of nano prominent structures, but deteriorated the interface of Ag/Si film, and even damaged the Ag film because of Ga⁺ bombardment. Regardless of the Ag nanoshape deposition, the residual Ag films were doped with Ga⁺ and were sensitive to DWE. After wet-etching, the nano hollow formed and the Ag films sunk. However, AgGa sidewall films formed by the concentration gradient and the oxidative potential and this increased the volume of microporous phases, resulting in a reduction in the depth. Also, 15-30 nm Ag nano-particles were able to enhance the DWE mechanism in the Ag/Si nanostructures.     

铜-不锈钢复合材料在HSO3-和/或Cl-介质中的腐蚀行为

采用选择腐蚀技术，提取了铜一不锈钢复合材料中的纤维相，并测定了纤维相电极电位。通过循环加速腐蚀试验和电化学测试方法，研究了3种铜一不锈钢复合材料和纯铜在HSO^3-和／或Cl^-介质中的腐蚀行为。同时研究了腐蚀对材料的力学性能、导电性能和显微组织的影响。结果表明，Cu-10wt％SS原位(微观)复合材料在HSO3^-和／或Cl-介质中具有一定的耐蚀性。HSO3^-对铜-不锈钢复合材料腐蚀的影响显著。     

Laser beam welding of dissimilar stainless steels in a fillet joint configuration

This paper investigates laser beam welding of dissimilar AISI 304L and AISI 430 stainless steels. Experimental studies were focused on effects of laser power, welding speed, defocus distance, beam incident angle, and line energy on weld bead geometry and shearing force. Metallurgical analysis was conducted on a selected weld only to show various microstructures typically formed at different zones and consequent change in microhardness. Laser power and welding speed were the most significant factors affecting weld geometry and shearing force. All the bead characteristics but radial penetration depth decreased with increased beam incident angle. The focused beam allowed selecting lower laser power and faster welding speed to obtain the same weld geometry. Weld shape factor increased rapidly due to keyhole formation for line energy input ranging from 15 kJ/m to 17 kJ/m. Fusion zone microstructures contained a variety of complex austenite-ferrite structures. Local microhardness of fusion zone was greater than that of both base metals.     

Preparation of pyramid-SiNWs binary structure with Ag nanoparticles-assisted chemical etching

It is an important way to improve the efficiency of solar cells by using the special microstructures of surface. In this work, a pyramid-silicon nanowires(pyramidSiNWs) binary structure was prepared on the silicon surfaces with the metal-assisted chemical etching(MACE)method. Scanning electron microscope(SEM) was used to observe the micromorphology of the pyramid-SiNWs binary structure. The formation mechanism of the binary structure was discussed. The role of Ag nanoparticles in MACE is considered to be the template and the catalyzer.The optical reflectivity of the silicon surfaces was studied with ultraviolet-visible(UV-Vis) spectrophotometer.Compared with the flat silicon surface and the simple pyramidal structure, the silicon surfaces with the pyramidSiNWs binary structure achieve a much lower reflectance in a wide range of wavelength. The effect of etching time as a parameter on the reflectivity was also discussed.     

3D打印两相钛合金组织性能研究现状

3D打印成型技术由于快速性、低成本、高集成化、适用于加工复杂零件等显著优点,近几年来得到快速发展,但是目前还存在许多不足,如精度不高、材料性能不稳定等。随着3D打印两相钛合金的应用越来越广泛,国内外针对3D打印两相钛合金的研究也逐渐深入和成熟,通过指导工艺的改进方向来提高其综合性能。本研究针对3D打印中激光快速成型和电子束熔化成型两种技术的工艺进行分析,阐释不同成型工艺条件下两相钛合金宏微观组织特征、力学性能特点,得出打印成型工艺参数、热处理工艺等因素对其影响,为3D打印两相钛合金工程化应用提供借鉴。     

激光熔覆TiC金属基陶瓷涂层的研究

采用自动送粉模式在碳钢表面原位激光熔覆TiC金属基陶瓷涂层。测试了涂层的温度场并模拟计算了光斑能量分布。用XRD表征了粉末和涂层的物相,用SEM分析了涂层表面和横截面的显微组织。研究表明光斑直径大小对熔覆涂层温度分布和涂层微观结构、性能的影响显著。当光斑直径为2.8mm时,能量分布为“尖顶帽状”模式,涂层为均匀的枝晶组织且致密,其显微硬度最高可以达到1280HV。     

工艺参数对TiAl合金激光表面合金化改性层组织与耐磨性的 …

利用元素氮和元素碳对γ－ＴｉＡｌ合金（简称ＴｉＡｌ合金）进行激光表面合金化处理,分别制得了以ＴｉＮ及ＴｉＣ硬质耐磨相为增强相的快速凝固原位耐磨复合材料表面改性层,改性层与基体间为完全的冶金结合,其显微组织从熔池底部到自由表面具有梯度渐变特征,越接近自由表面,增强相越密集,较系统地研究了激光表面合金化工艺参数对改性层显微组织以及在磨料磨损及滑动磨损条件,增强相越密集。较系统地了激光表面合金化工艺参数     

Microstructure and mechanical properties of laser beam welding 6061 aluminum alloy with different states

With the diversification of manufacture methods,joining the same materials with different states becomes indispensable in practical application.In present work,6061 aluminum alloys with different states were welded by laser beam welding (LBW).The microstructures of welded joint,before and after heat treating,were investigated.The mechanical properties,such as the tensile properties and microhardness,were tested.And the fracture characteristic was observed by means of scanning electron microscope (SEM).The results show that the 6061 aluminum alloys have superior weldability and the microstructures are different significantly in different states.Besides,the grain boundaries of the joint microstructures become unclear after the heat treating.The strength and the elongations of welded joints could reach to those of the base metal.The tensile fracture occurs in the fusion zone and near 6061-0 alloy.And the fracture presents ductile rupture.Therefore,the LBW is an effective method for 6061 aluminum alloy.     

Microstructures of electron beam welding joint of CNTs/ Al composites

Carbon nanotube(CNT) reinforced aluminum metal matrix composites were welded by electron beam welding and the microstructures of welded joints were investigated.The result showed that the interfacial reaction happened between the CNTs and Al matrix,which resulted in producing brittle Al4C3 compounds in electron beam welds.The extent of interfacial reaction varies gradually in the depth and width direction.The length of the reactants Al4C3 became short duo to the temperature gradient in the molten pool.The quantity and size of Al4C3 compounds increased with the increase of beam current and the decrease of welding speed in the middle zone of weld.However,no needle-like phase Al4C3was observed in HAZ.     

带极电渣堆焊奥氏体不锈钢耐晶间腐蚀性能

用带极电渣堆焊和带极埋弧堆焊2种方法堆焊了Cr-Ni不锈钢,研究了这两种方法和焊接速度对堆焊层金属显微组织及耐晶间腐蚀性能的影响。显微组织观察表明,带极电渣堆焊和带极埋弧堆焊层的显微组织都为奥氏体+δ铁素体。带极电渣堆焊层金属中δ铁素体随着焊速的提高而增多,含量由6。8%增加到20.4%,带极埋弧堆焊金属中的δ铁素体含量比带极电渣堆焊的高,达到了23.6%;电化学动电位再活化试验结果表明,焊接速度8m/h的带极电渣堆焊层金属的再活化率仅为3.22%,耐晶间腐蚀的性能最佳,焊速快慢或焊接方法改变都将使带极电渣堆焊层金属的再活化率升高,耐晶间腐蚀性能下降。10%草酸溶液电解浸蚀试验的结果与EPR曲线结果一致。     

42CrMo钢宽带激光熔覆NiCrBSi组织和性能

采用宽带扫描吕磁针 圆形光斑展宽成矩形,在42CrMo基材表面激光熔覆NiCrBSi合金,得到致密无裂纹结合层,研究了熔覆层组织、物相及其对熔覆层硬度、耐磨性的影响,并综合阐述了不同工艺对硬度、耐磨性及熔覆层的影响。     

TC4-DT钛合金疲劳裂纹扩展及裂纹尖端塑性区

研究了TC4-DT钛合金不同组织的疲劳裂纹扩展行为,观察了疲劳裂纹在不同显微组织中的裂纹扩展路径,分析了不同显微组织的裂纹尖端塑性区变形情况,并与理论计算结果进行了对比。结果表明,疲劳裂纹在片层组织中扩展路径曲折,且片层组织的裂纹尖端塑性区较双态组织的大,理论计算的裂纹尖端塑性区的范围较实际测量的范围小得多。     

Effects of Ti addition on microstructures of melt-spun CuCr ribbons

The microstructure and resistivity of melt-spun CuCrTi ribbon were studied.The results reveal that the maximal size of theprimary Cr particles in the microstructures is below 100 nm by 0.65%-3.8%Ti(mole fraction)addition and the resistivity of annealedribbons of 0.65%-1.3%Ti addition can meet the need of the contact materials used by the medium-voltage vacuum interrupters.Bycontrasting the melt-spun microstructures to the annealed microstructures,the primary Cr particles do not grow up quickly in theannealing process.The X-ray diffraction studies reveal that alloying increases the amount of the solute in Cu and Cr phases andresults in the increase of resistivity.By the thermodynamic analysis,adding Ti to CuCr29 alloys increases the critical supercooling ofthe liquid/solid transformation,which makes the critical radius of nucleation decrease and the rate of nucleation increase.As a result,the microstructure of CuCr ribbon can be further refined.