冷喷涂Zn工艺参数对涂层质量的影响

简要介绍了冷喷涂技术的特点及工艺原理。利用粒子测速仪进行了粒子速度测试,借助扫描电镜观察了涂层以及涂层与界面的形貌,具体讨论并分析了气体压力、温度、粉末性质以及喷涂距离等因素对颗粒速度和涂层质量的影响。     

用于非取向硅钢的新型涂层设备

非取向硅钢广泛应用于电机和变压器制造。其对钢板表面电绝缘涂层的厚度要求精准,这使涂层工艺成为该产品市场竞争的关键因素之一。     

刀具涂层材料的最新研究进展

随着难加工材料和绿色干切削等先进加工技术的开发与广泛应用,刀具切削环境日益严苛,刀具涂层材料不断更新换代。涂层材料已由最初的二元涂层逐渐发展成三元及多元涂层,结构由单层逐渐向多层、梯度、复合结构转变。首先总结了几种常用二元涂层的性能和特点。再以Ti基和Cr基三元及多元涂层为例,阐述了掺杂元素对涂层微观结构和性能的影响及强化机制,分析了多元涂层的研究现状和面临的难题,以及多种掺杂元素的协同作用机制。还讨论了纳米晶/非晶复合结构涂层、纳米多层涂层以及梯度涂层的结构优势及研究现状,介绍了金刚石、类金刚石和立方氮化硼三种超硬涂层以及具有低摩擦因数软涂层的特点和研究进展。最后介绍了近几年研究的热点涂层(如高熵合金涂层、含氧涂层和多元多层复合涂层)的研究现状,并对刀具涂层的未来发展方向进行了展望。     

深海交变压力对水在环氧涂层中传输行为的影响

目的深入了解有机涂层在深海交变压力环境下的失效机制,为涂层服役寿命的预测提供指导。方法利用增重法和电化学阻抗测量技术,研究常压和深海交变压力条件下水在环氧涂层中的传输行为,计算不同环境下水的扩散系数,并分析交变压力对水在涂层中吸水动力学的影响。结果交变压力加速了水在涂层中的传输过程,使其扩散机制由常压下的理想Fick扩散行为变为非Fick扩散,延长了饱和时间,增大了涂层饱和吸水率。微观形貌观测发现,涂层内部填料/基料界面产生了大量裂痕,是导致水在涂层中扩散机制发生改变的主要原因。结论交变压力通过压力对水的推动作用及对涂层结构的破坏,加速了水在涂层中的传输。     

IPcote9183金属陶瓷涂层制备及其性能

用一种进口水基含铝高温防腐蚀涂料制备了金属陶瓷涂层,介绍了制备的工艺,对该涂层的性能进行了研究.结果表明,按照一定的喷涂压力和喷涂距离进行喷涂,可获得表面均匀、结合良好的涂层.喷涂一层IPcote9183可以获得厚度为0.01 mm～0.02 mm的涂层;可进行多层喷涂.厚度为0.02～0.03mm的涂层,中性盐雾试验...     

刀具涂层技术及其发展

随着切削技术向着高速、高效、干式的方向发展,刀具涂层技术得到了广泛的应用,并成为了左右切削技术发展的主要因素。本文介绍了各种刀具涂层材料、刀具涂层结构和刀具生长工艺的研究现状。对刀具涂层的发展方向提出了个人见解。     

等离子喷涂生物材料涂层的研究进展及应用

等离子喷涂是一种较为成熟的热喷涂技术,其制备的生物材料涂层具备优良的生物活性、良好的生物稳定性、与基体结合强度较高等突出的优点.根据国内外针对该领域的研究热点,综合介绍了多种采用等离子喷涂技术制备的生物陶瓷涂层和高聚合物涂层,分析了涂层的物理及化学特性,以及涂层的主要应用研究现状,并从涂层的生物相容性、稳定性、界面结合强度等研究方向出发分别对所制得涂层的厚度、梯度、均匀度等重要参数进行了研究.最后,对等离子喷涂制备生物材料涂层领域的后续研究进行了展望.     

回转体零件热喷涂涂层的结合强度

回转体失效零件利用热喷涂技术修复之后需要对其涂层抗拉结合强度进行测量。参考平面热喷涂涂层结合强度测量方法,提出了一种回转体零件涂层抗拉结合强度测量方法,并对该方法进行了理论分析,给出了具体操作要点和步骤。分析了回转体零件涂层结合强度与平面涂层结合强度测量结果之间产生差异的原因,并进行了试验验证。实际测量了相同工艺下基体半径为40mm的FeAlCrBSiNb回转体涂层和平面涂层的结合强度,测量结果分别为48.3MPa和51MPa,两者相差5.3%。结果表明,在试样基体半径尽可能大或涂层实际面积与投影面积相差尽可能小的条件下,利用该方法可以测得较为准确的回转体零件涂层结合强度。     

涂层和未涂层铝基体上接触应力的有限元模拟

基于对涂层／基体系统上产生的接触应力的分析,研究了软基体上薄膜的磨损行为。应用有限元法对由压头向涂层或未涂层铝基体施加正压力的情况进行模拟。先在没有薄膜的系统 上对模型的精确性进行检验。然后通过改变薄膜的弹性模量比,开发出适用于铝基体上有两层硬薄膜试样的模型。同时还研究了薄膜厚度和载荷的影响。较厚的薄膜降低了模型上某些点的应力,但是增加了另一些点的应力,从弹性模量的角度来说,薄膜内的计算应力主要与     

智能变色涂层

介绍了智能变色涂层的几种主要类型及其在民用领域和军事领域的部分应用。常用的智能变色涂层有光致变色涂层、电致变色涂层、热致变色涂层、受压变色涂层等。这些涂层在传感器、显示技术、光学仪器、节能建筑以及军事伪装等领域有着广阔的应用前景。文中对现阶段各种智能变色涂层技术的局限和缺点进行了评述，并对不同类型变色涂层的常用制备方法和发展趋势进行了总结。     

Ni-Cr-Al合金电弧喷涂工艺对涂层结合强度的影响

为使Ni-Cr-Al合金电弧喷涂涂层获得优良的性能,以涂层结合强度为判据,通过正交试验对Ni-Cr-Al合金电弧喷涂工艺进行了优化。利用扫描电镜、能谱仪等手段对涂层和断口形貌进行分析,同时对涂层的显微硬度进行了测试。结果表明,喷涂距离、雾化空气压力、喷涂电流、喷涂电压对Ni-Cr-Al合金涂层结合强度具有不同的影响,确定优化后的工艺参数为喷涂电流160 A,喷涂电压32 V,雾化空气压力0.5 MPa,喷涂距离160 mm。在优化工艺参数条件下,电弧喷涂Ni-Cr-Al合金涂层组织呈现出典型的层状结构,其最大结合强度可达34.30 MPa,具有较好致密性和硬度。     

热障涂层的研究现状与发展趋势

热障涂层是一类高温防护涂层,由于其应用的广泛性,已成为近年来涂层研究领域的热点之一。对热障涂层国内外的研究进展进行了综述,重点阐述热障涂层成分的选择、热障涂层的结构设计、热障涂层的制备工艺、热障涂层的失效机理、寿命预测以及热障涂层的发展趋势。     

Prediction of fiber coating thickness via liquid-phase process

Two kinds of fiber coating processes, free coating and obstructed coating, are investigated theoretically and experimentally. In the free coating process, the entrainment of Newtonian liquid film onto a vertical fiber, which is continuously withdrawn from a coating liquid bath, is considered. A dimensionless analysis is applied to identify dimensionless groups governing the system in this process and the coating thickness is determined by two dimensionless parameters, Capillary number and Goucher number, and the fiber radius. The obstructed coating mechanism is studied numerically. The shear rate acting on the fiber surface is proportional to the fiber draw speed in an unpressurized applicator and can be minimized in a pressurized applicator through the applied external pressure. The calculated results were compared with the experimental data in the obstructed coating process and a good agreement was obtained.     

不同镀层产品的工艺性能与生产线设计

近20年来带钢连续热镀锌技术、装备以及相应的控制手段均得到了巨大发展,我国的镀锌产品已从单一的大锌花镀锌板发展到不同镀层产品,但是针对一些特殊镀层产品,我国尚处于研发阶段。因此结合国内外先进的热镀锌生产技术与生产线设计经验,探讨不同镀层产品的工艺性能与生产线设计具有重要意义。对不同镀层产品的化学成分、组织特点、物理性能及热浸镀工艺参数进行了对比分析;结合不同镀层元素的物理特性、氧化特性和与铁反应性对热浸镀过程的影响,以及镀层凝固特性对热浸镀工艺的要求,总结了不同镀层产品生产线实际参数设计,着重介绍了前处理设备、退火炉、锌锅、镀后冷却等关键设备选型配置。     

不同镀层重量的铝硅镀层加热时的镀层结构转变规律

采用扫描电镜和能谱分析仪研究了不同镀层重量的铝硅镀层热成形钢经不同温度和时间加热后的镀层结构转变规律。结果表明,不同重量的铝硅镀层在完全合金化后的镀层结构相同,由基体至表面依次为扩散层、Fe-Al层、Fe-Al-Si层和Fe-Al表面层;随着加热的进行,Fe-Al-Si层和扩散层逐渐增厚,Fe-Al-Si层中Si含量逐渐降低,厚镀层AS150未出现镀层层数减少的现象,薄镀层AS40、AS80出现镀层层数减少的情况。综合考虑铝硅镀层热成形钢加热后的镀层结构、性能变化和产品使用要求,对于1.4 mm厚22MnB5钢基板,薄镀层AS40、AS80的优选热处理工艺为900~930 ℃×3~6 min,厚镀层AS150的优选热处理工艺为900~930 ℃×4~6 min。     

Thermal coating development for impulse drying

A plasma-sprayed coating has been developed for the heated surface of rolls used in a new energy-efficient paper drying process, known as“Impulse Drying,” which could save the US paper industry an estimated $800 million annually in reduced energy costs. Because impulse drying rolls operate at substantially higher surface temperatures than conventional drying rolls, the thermal properties of the roll surface must be carefully tailored to control energy transfer to the paper and thus prevent sheet delamination or other undesirable effects. To meet this requirement, a plasma-sprayed thermal barrier coating has been developed to control thermal mass, heat transfer, and steam infiltration. A coated test platen significantly outperformed a comparable uncoated steel platen in preliminary experiments with a heavyweight grade of paper on a laboratory-scale impulse drying simulator. Based on these results, the coating was then tested on the roll of a pilot-scale impulse dryer. Compared to conventional wet pressing, linerboard that was impulse dried with the coated test roll showed marked improvements in water removal as well as improved physical properties, such as density and specific elastic modulus. The successful prototype coating design has three plasma-sprayed layers that are deposited sequentially: a nickel alloy bond coat, a thick, 17% porous zirconia thermal barrier, and a thin, 5 to 7% porous zirconia top coat. This work was performed in part at Sandia National Laboratories, operated for the US Department of Energy under contract No. DE-AC01-76DP00789. Work at the Institute of Paper Science and Technology was sponsored by the member companies of the Institute of Paper Science and Technology and by the US Department of Energy under contract No. FG02-85CE40738.     

Corrosion monitoring system design for coating wire of steel in ocean

The monitoring system design used in anti-corrosion of coating wire of steel in ocean were concerned. A corrosion monitoring system adapting to corrosion observation of coating wire of steel was introduced in details, including design and choice of software and hardware. This system will play an important role in the collection, procession, demonstration, deposition and accident alarm of corrosion data of oceanic coating wire of steel.     

两锥度线缆包覆挤出模优化设计

阐述了模壁剪切速率γw和口模的两锥度角α、β是影响线缆包覆层质量的重要因素,为使线缆质量和生产效率都达到最佳,从剪切速率γw的计算和两锥度角α、β的确定探讨线缆包覆模具的优化设计。     

Monitoring of a Zr-based conversion coating on galvanised steel and its performance against corrosion

ABSTRACT

New protective coatings with satisfactory performance and low impact are required by the surface treatment industry as effective Cr(VI)-free substitutes. Recently conversion coating systems containing Zr/Ti have shown great promise particularly for zinc finishes on steel and in this paper, we study the influence of bath conditions (e.g. pH and time) on conversion layers composed of a Zr-based film. The coating formation was studied by simultaneous monitoring of open circuit potential and surface pH using a novel cell design. Samples were subsequently characterised by electrochemical impedance spectroscopy in NaCl over a 24-hour period. The system demonstrates a correlation between pH of formation and corrosion resistance.     

Ceramic coating on ceramic with metallic bond coating

The change in structure and adhesion strength of the interface by heating in air has been investigated for a plasma- sprayed alumina coating on a ceramic substrate with a 50Ni- 50Cr alloy bond coating. A veined structure composed of NiO, NiCr ₂O₄, and NiAl₂O₄ oxides grew from the bond coating into cracks or pores in the top coating and the alumina substrate after heating at 1273 K for 20 h in air. The NiAl₂O₄ spinel may have formed by the oxidization of nickel, which subsequently reacted with the alumina coating or the substrate. The mechanism of the penetration of the spinel oxides into the cracks or pores is not clear. The adhesion strength of the coating is increased to about 15 MPa after heating at 1273 K for 20 h in air, compared to an as- sprayed coating strength of only 1.5 MPa.