Q550级桥梁钢动态再结晶行为研究

采用Gleeble-3500热模拟试验机模拟了屈服强度550 MPa级桥梁钢轧板单道次热压缩变形过程,得到了试验钢的真应力-真应变曲线,分析了变形温度和应变速率对动态再结晶行为的影响,并建立了试验钢的再结晶图。结果表明,在较高的变形温度和较低的应变速率下,动态再结晶易进行。实验在动态再结晶激活能为460.14 kJ/mol时,建立了试验钢动态再结晶动力学模型。     

Incoloy825高温合金热变形行为及动态再结晶模型

采用Gleeble-3800热模拟试验机，对Incoloy825高温合金在应变为0.92、温度为950～1150℃和应变速率为0.001～1 s^-1条件下进行单道次压缩试验。依据真应力-真应变曲线建立了动态再结晶临界方程和动态再结晶动力学模型。结果表明，Incoloy825高温合金热变形对温度和应变速率较为敏感，真应力-真应变曲线整体满足硬化-软化-稳态的流变过程，动态再结晶是Incoloy 825高温合金材料的主要软化机制。在热变形过程中，动态再结晶临界应变随变形温度的升高和应变速率的降低呈减小趋势。对动态再结晶动力学模型进行分析发现，动态再结晶百分含量随变形温度的升高和应变速率的降低而增大，表明高变形温度和低应变速率对动态再结晶具有促进作用。     

薄带连铸耐大气腐蚀钢的热变形行为及本构方程

采用热模拟压缩试验机研究了适合薄带连铸生产的全新成分的耐大气腐蚀钢在变形温度900～1 200℃、应变速率0.1～30 s-1条件下的高温变形行为,得到了该钢的真应力-真应变曲线,分析了该钢在热变形过程中的动态再结晶行为,从材料本身角度回归得到了该钢高温热变形本构方程。结果表明:在薄带连铸工艺条件下生产耐大气腐蚀钢,在轧制温度1 050℃及以上时,压下量达到20%及以上,就会发生动态再结晶;而在轧制温度900℃时,压下量即使达到40%及以上,也不会发生动态再结晶。通过本构方程计算得到的峰值应力预测值与试验值相吻合,可以较好地描述适合薄带连铸工艺全新成分的耐大气腐蚀钢的高温热变形行为。     

CSP轧制DC04深冲钢时的动态再结晶研究

利用Gleeble-1500热模拟试验机对DC04系列深冲钢进行了单道次压缩试验,得到该钢种连铸坯在进行CSP轧制时高温变形过程中的真应力-应变曲线,通过回归分析得到其动态再结晶数学模型为:Z=ε觶exp(194.021RT);动态再结晶的判定条件分别为Z=8.817×107exp(15.736εc)、Z=8.009×107exp(9.928εs)。在此基础上建立动态再结晶的三维模型图,利用该模型图可有效避免轧制时产生的混晶现象。     

GH1016合金的动态再结晶行为

利用GLEEBLE-3500热模拟试验机完成了变形温度为1000～1150℃,应变速率为0. 1～10 s~(-1),变形量分别为20%、40%和60%的热压缩试验,获得了各试验条件下GH1016合金的真应力-真应变曲线,并利用数据拟合的手段求得了GH1016合金的临界变形条件方程。同时,得到了所有变形条件下的再结晶组织,分析了变形工艺对GH1016合金的动态再结晶过程的影响规律,最终获得了GH1016合金在试验条件下的动态再结晶状态图,可为生产现场的锻造工艺的合理制定提供理论参考依据,尤其适用于GH1016合金的精锻工艺的制定和优化。     

热变形参数对GH690合金晶粒细化的影响

采用Gleeble-3500热模拟试验机进行高温等温压缩试验,研究了热变形参数对GH690合金晶粒细化的影响.结果表明:当变形程度较小时,随着真应变的增加,GH690合金动态再结晶的晶粒尺寸逐渐减小,但当真应变达到0.5后,随着真应变继续增加,动态再结晶晶粒尺寸变化不大;动态再结晶晶粒尺寸随变形温度的升高而增大,随应变速率的增大而减小.建立起热变形条件即Z参数与动态再结晶晶粒尺寸的关系.     

GH625镍基合金的高温压缩变形行为及组织演变

在Gleeble-1500D热模拟机上采用等温压缩实验研究GH625合金的高温压缩变形行为,获得合金在温度为1000～1200℃、应变速率为10-2～10s-1的条件下的真应力—应变曲线,并在考虑摩擦和变形热效应的基础上对真应力—应变曲线进行修正。对修正后的峰值应力进行线性回归,得到合金的高温材料常数:Q=635.38kJ/mol,α=0.008404MPa-1,n=3.52。通过非线性回归建立GH625合金包含应变量的高温变形本构模型。在应变速率为0.1s-1时,随着热变形温度的升高,合金发生动态再结晶的体积分数随之增加,在1000～1100℃发生部分动态再结晶,当温度达到1200℃时,发生完全动态再结晶,此时平均晶粒尺寸约为22.21μm。     

65Mn钢的动态再结晶行为

采用Gleeble-3500热模拟试验机对65Mn钢进行热压缩试验,变形温度850~1150℃、应变速率0.02~20 s~(-1),最大真应变1.0,研究材料在上述试验条件下的动态再结晶行为,以及变形条件对再结晶晶粒尺寸的影响。结果表明:试验钢的真应力-真应变曲线在高温、低应变速率条件下出现明显峰值,随着温度的升高和应变速率的降低,临界应变变小,有利于动态再结晶发生;奥氏体再结晶晶粒尺寸与变形参数相关,应变速率降低,再结晶晶粒尺寸增大;变形温度降低,有利于再结晶晶粒尺寸细化。     

变形条件对2124铝合金超厚板流变行为与显微组织的影响

在Gleeble-1500热/力机上进行了变形条件对2124铝合金超厚板流变行为与显微组织的影响规律的系列实验研究,得到了不同变形条件下2124铝合金超厚板高温压缩成形过程中的流变曲线。实验结果表明,2124铝合金在0.01s-1~1s-1范围内,高温压缩变形过程存在近稳态流变特征,近稳态流变应力随着应变速率的降低和变形温度的升高而降低。当应变速率为10s-1时,真应力-真应变曲线出现锯齿状,说明合金发生动态再结晶现象。利用OM和TEM分别研究了变形温度、应变速率、应变量对2124铝合金高温压缩变形显微组织的影响,在此基础上,分析并建立了2124铝合金热压缩变形发生动态再结晶的临界条件。     

Q345D静态再结晶行为的分析

在Gleeble-3500热模拟试验机上进行双道次热压缩试验,得到了Q345D钢在不同工艺参数条件下的真应力-真应变曲线,采用应力补偿法计算了相应的静态软化百分数。研究了应变大小、变形温度及变形后保温时间对Q345D钢静态再结晶的影响,得到了再结晶的终止温度范围,为实际轧制工艺提供了理论依据。     

Effects of Post-weld Heat Treatment on Microstructure,Mechanical Properties and the Role of Weld Reinforcement in 2219 Aluminum Alloy TIG-Welded Joints

In as-welded state, each region of 2219 aluminum alloy TIG-welded joint shows diff erent microstructure and microhardness due to the diff erent welding heat cycles and the resulting evolution of second phases. After the post-weld heat treatment, both the amount and the size of the eutectic structure or θ phases decreased. Correspondingly, both the Cu content in α-Al matrix and the microhardness increased to a similar level in each region of the joint, and the tensile strength of the entire joint was greatly improved. Post-weld heat treatment played the role of solid solution strengthening and aging strengthening. After the post-weld heat treatment, the weld performance became similar to other regions, but weld reinforcements lost their reinforcing eff ect on the weld and their existence was more of an adverse eff ect. The joint without weld reinforcements after the post-weld heat treatment had the optimal tensile properties, and the specimens randomly crack in the weld zone.     

The First Phase of the SRIF Industrialized Base in ＂West Area＂ Has Been Put into Operation

After nearly two years＇ tense construction, the first phase of industrialized base of Shenyang Research Institute of Foundry （SRIF）, located at the Tiexi Casting and Forging Industrial Park in the west of Tiexi District, has now been completed and formally put into operation.     

Theoretical Analysis for the Motion and Temperature of Melt Droplets in Spray Degassing Process

The motion of melt droplets in spray degassing process was analyzed theoretically. The height of the treatment tank in spray degassing process could be determined by the results of theoretical calculation of motion of melt droplets. To know whether the melt droplets would solidify during spraying process, the balance temperature of melt droplets was also theoretically analyzed. Then proof experiments for theoretical results about temperature of melt droplets were carried. In comparison, the experimental results were nearly similar to the calculation results.     

Growth Kinetics of Single Inclusion Particle in Molten Melts

On the basis of the single-particle framework, a new theory on inclusion growth in metallurgical melts is developed to study the kinetics of inclusion growth on account of reaction and collision. The studies show that the early growth of inclusion depends on reaction growth and Brawnian motion collision, and where the former is decisive, the late growth depends on turbulence collision and Stokes＇ collision, and where the former is dominant; collision growth is very quick during the smelting process, lessened in the refining process, but nearly negligible in the continuous casting process.     

An Easy Way to Quantify the Adhesion Energy of Nanostructured Cu/X(X=Cr,Ta,Mo,Nb,Zr) Multilayer Films Adherent to Polyimide Substrates

An approach based on film buckling under simple uniaxial tensile testing was utilized in this paper to quantitatively estimate the interfacial energy of the nanostructured multilayer films(NMFs) adherent to flexible substrates. The interfacial energies of polyimide-supported NMFs are determined to be *5.0 J/m2 for Cu/Cr, *4.1 J/m2 for Cu/Ta,*2.8 J/m2 for Cu/Mo, *1.1 J/m2 for Cu/Nb, and *1.2 J/m2 for Cu/Zr NMFs. Furthermore, a linear relationship between the adhesion energy and the interfacial shear strength is clearly demonstrated for the Cu-based NMFs, which is highly indicative of the applicability and reliability of the modified models.     

High-Speed Friction Stir Welding of SiC_p/Al–Mg–Si–Cu Composite

A 17 vol% SiCp/Al–Mg–Si–Cu composite plate with a thickness of 3 mm was successfully friction stir welded(FSWed) at a very high welding speed of 2000 mm/min for the first time. Microstructural observation indicated that the coarsening of the precipitates was greatly inhibited in the heat-affected zone of the FSW joint at high welding speed, due to the significantly reduced peak temperature and duration at high temperature. Therefore, prominent enhancement of the hardness was achieved at the lowest hardness zone of the FSW joint at this high welding speed, which was similar to that of the nugget zone. Furthermore, the ultimate tensile strength of the joint was as high as 369 MPa, which was much higher than that obtained at low welding speed of 100 mm/min(298 MPa). This study provides an effective method to weld aluminum matrix composite with superior quality and high welding efficiency.     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

A STUDY OF TEMPERATURE-DEPENDENT VALENCE BOND STRUCTURE OF TITANIUM

On the basis of energy and shape method for the determination of the valence bond (VB) structures of crystal, the valence bond structure of titanium is redetermined at room temperature and calculated in the whole temperature range of 0-1943K. The outer shell electronic distribution of Ti is e_c~(2.9907) · (s_c~(0.4980) d_c~(2.4927)) ef1.0093 in crystal. The temperature dependences of the VB structures of hcp and bcc phases are the same. The VB structures of hcp and bcc phases monotonically increase or decrease with the increase in temperature, but show discontinuous changes at the phase-transformation temperature 1155K.     

Structural Optimization of Electromagnetic Swirling Flow in Nozzle of Slab Continuous Casting

During the slab continuous casting process, the flow field of molten steel in the mold plays a decisive role in the quality of the slab. In this paper, electromagnetic swirling flow in nozzle technology is proposed to control the flow field in mold.This technology can drive molten steel to rotate inside the submerged entry nozzle by electromagnetic force, thereby controlling the flow field. This research shows that it can reduce the impact of molten steel on the bottom of nozzle and partly reduce the negative pressure at the upper part of nozzle outlet which is even eliminated by optimizing the structure and angle of nozzle. The area of heat flux of the mold wall becomes larger, and the crest value of heat flux gets lower than that without swirling in nozzle and any nozzle optimization. The meniscus fluctuates smoothly, and the flow velocity at the top surface is within a reasonable range. The temperature field distribution in the mold is uniform which was beneficial to the growth of equiaxed crystal and decreased element segregation.     

Effect of Rare Earth Doping on Impedance,Modulus and Conductivity Properties of Multiferroic Composites:0.5(BiLa_xFe_(1-x)O_3)–0.5(PbTiO_3)

The Lanthanum-doped bismuth ferrite–lead titanate compositions of 0.5(Bi LaxFe1-xO3)–0.5(Pb Ti O3)(x = 0.05,0.10,0.15,0.20)(BLxF1-x-PT) were prepared by mixed oxide method.Structural characterization was performed by X-ray diffraction and shows a tetragonal structure at room temperature.The lattice parameter c/a ratio decreases with increasing of La(x = 0.05–0.20) concentration of the composites.The effect of charge carrier/ion hopping mechanism,conductivity,relaxation process and impedance parameters was studied using an impedance analyzer in a wide frequency range(102–106Hz) at different temperatures.The nature of Nyquist plot confirms the presence of bulk effects only,and non-Debye type of relaxation processes occurs in the composites.The electrical modulus exhibits an important role of the hopping mechanism in the electrical transport process of the materials.The ac conductivity and dc conductivity of the materials were studied,and the activation energy found to be 0.81,0.77,0.76 and 0.74 e V for all compositions of x = 0.05–0.20 at different temperatures(200–300 °C).