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分析了我国石化公司CO2的排放来源,介绍了当前国内石化公司CO2减排所面临的挑战、机遇和商机,并提出了应对策略。认为应重点关注CO2高排放装置的节能与减排工作,加强节能管理,开展CO2综合利用技术的研究与应用,开发和利用生物能源、生物燃料等可再生能源,灵活运用各种减排政策和机制,参与温室气体减排活动。 相似文献
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火电厂和IGCC及煤气化SOFC混合循环减排CO2的分析 总被引:7,自引:2,他引:5
二氧化碳减排已经成为缓解全球气候变化的一个重要议题 .目前 ,火电厂排放的 CO2约占中国 CO2 排放量的 1 /3左右 ,减少其 CO2 排放可以通过提高能量转化效率和回收封存 CO2 两种主要方式 .常规锅炉汽机电厂、IGCC以及煤气化 -固体氧化物燃料电池 ( SOFC)混合循环分别代表了现在、近期及未来燃煤电厂的典型配置 ,超临界及超超临界电厂效率可以达到 40 %以上 ,采用GEH型等先进燃气轮机的 IGCC可提高到 5 0 %以上 ,而混合循环电厂的效率则有望达到 60 %以上 .利用 Aspen Plus TM对这三种电厂进行了模拟 ,考察了三者在回收 CO2 前后性能的变化 .在此基础上 ,分析了减排 CO2 及征收排放税等措施对各电厂发电成本的影响 ,进而就未来如何促进电厂减排 CO2 进行了探讨 . 相似文献
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CO2是最主要的温室气体,其减排和回收利用关系到可持续发展.世界CO2排放185亿~242亿t/a,只有1亿t/a得到利用.主要产品是液体CO2.我国CO2排放已超过30亿t/a,只有80万t/a得到有效利用.利用方式是干冰和液体CO2.液体CO2需求量增长速度为15%~20%,未来5年后年需量达到200万t以上. 相似文献
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The structure identification and carbonation characteristics of several potassium-based supported sorbents for CO2 capture were investigated with TGA,XRD,XRF,SEM and N2 adsorption method.Potassium-based sorbents were prepared by impregnation with potassium carbonate on supports,such as cocoanut activated charcoal(AC1),coal active carbon(AC2),silica gel(SG)and diatomite(DT)using the iso-volume impregnation method.The results showed that the K2CO3 loading amounts of AC1,AC2,SG and DT were 24.1%,22.5%,21.7% and 19.1% respectively.The surface area and pore volume of K2CO3/AC1 and K2CO3/AC2 were larger than others.In contrast,those of K2CO3/DT were small.For K2CO3/SG,pore volume was large but surface area was small.K2CO3/AC1 and K2CO3/AC2 showed excellent carbonation capacity.However,the carbonation capacities of K2CO3/SG and K2CO3/DT were low.The difference in carbonation capacity of those sorbents were attributed to the difference in pore structure,leading to different supported sorbents. 相似文献
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活性炭担载金属氧化物用于热煤气脱硫 总被引:2,自引:0,他引:2
以热煤气脱硫并回收单质硫为目的,考察了活性炭担载金属氧化物(M/AC)在中温范围150—250℃内,催化氧化硫化氢生成单质硫的研究。担载量1%(质量分数)的M/AC通过等体积浸渍法制得,在固定床上评价了其脱硫活性,并考察了温度、反应气氛等工艺条件对脱硫效果的影响。M/AC脱硫的活性顺序为:Mn/ACCu/ACCe/ACFe/ACCo/ACV/AC。通过DTG分析,硫化氢选择性氧化的主要产物是单质硫。M/AC上金属氧化物起主要的催化作用,催化硫化氢和氧气反应生成单质硫,生成的单质硫被吸附在活性炭的孔道中。 相似文献
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Jinxiao Dou Yongqi Zhao Arash Tahmasebi Jianglong Yu 《Korean Journal of Chemical Engineering》2016,33(10):2849-2857
The sulfidation and regeneration properties of lignite char-supported iron-based sorbent for coke oven gas (COG) desulfurization prepared by mechanical stirring (MS), ultrasonic assisted impregnation (UAI), and high pressure impregnation (HPI) were investigated in a fixed-bed reactor. During desulfurization, the effects of process parameters on sulfidation properties were studied systematically. The physical and chemical properties of the sorbents were analyzed by X-ray diffraction (XRD), scanning electron microscope coupled with energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared (FTIR) and BET surface area analysis. The results of desulfurization experiments showed that high pressure impregnation (HPI) enhanced the sulfidation properties of the sorbents at the breakthrough time for char-supported iron sorbents. HPI method also increased the surface area and pore volume of sorbents. Sulfur capacity of sorbents was enhanced with increasing sulfidation temperatures and reached its maximum value at 400 °C. It was observed that the presence of steam in coke oven gas can inhibit the desulfurization performance of sorbent. SO2 regeneration of sorbent resulted in formation of elemental sulfur. HPIF10 sorbent showed good stability during sulfide-regeneration cycles without changing its performance significantly. 相似文献
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采用浸渍法制备了双金属Ru-Nix/AC系列催化剂,并采用X射线衍射(XRD)、程序升温还原(H2-TPR)和CO脉冲吸附等表征手段对催化剂进行了表征。在邻苯二甲酸二异辛酯(DOP)加氢制备环己烷1,2-二甲酸二异辛酯(DEHCH)反应中评估了该系列催化剂的性能,并讨论了Ni在其中的作用。发现掺杂Ni后RuNi/AC催化剂对于DOP生成环己烷1,2-二甲酸二异辛酯的选择性有明显提高(99.7%),远高于未掺杂Ni的Ru/AC催化剂(77.7%)。而且催化活性会随着Ni的质量比增加而增加,并在m(Ru)∶m(Ni)为0.6∶5.0时加氢活性达到最大。H2-TPR结果比对发现,Ru金属的存在可以降低Ni金属的还原温度,说明2种金属之间存在相互作用,同时也佐证了Ru和Ni之间的协同效应。 相似文献
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CaO based sorbents have great potential for commercial use to capture CO_2 of power plants. In the demand of producing sorbents with better cyclic performance, CaO-based sorbents derived from different kinds of calcium precursors, containing calcium carbonate(CC-CaO), calcium gluconate monohydrate(CG-CaO), calcium citrate(CCi-CaO) and calcium acetate monohydrate(CA-CaO), were tested cyclically and compared using simultaneous thermal analyzer(STA). And further study was conducted on the sorbents modified with citric acid monohydrate and 50% gluconic acid solution by wet mixing combustion synthesis. The modified sorbents showed better performance and higher pore parameters as well as porous microstructure with more organic acid added. After 20 cycles of carbonation and calcination, the C2CCi8(CaO: citric acid = 2:8 by mass ratio) and C2G8(CaO: gluconic acid = 2:8 by mass ratio) sorbent possess CO_2 capture capacity of 0.45 g·g~(-1)(g CO_2 per g sorbents) and 0.52 g·g~(-1) respectively. The citric acid was more effective for modification than gluconic acid for extended 50 cycles. Furthermore, good linear relationship between CaO conversion and specific surface area as well as pore volume were determined, of which the specific surface area showed closer correlation with CaO conversion. 相似文献
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分别以活性炭(AC)、γ-Al2O3、MgO、TiO2为载体,氯铂酸为活性金属前驱体,采用等体积浸渍法制得不同载体负载的Pt催化剂,考察了它们对环己烯基环己酮(dimer)脱氢制备邻苯基苯酚(OPP)的催化活性和选择性。并用X射线衍射(XRD)、X射线光电子能谱(XPS)、H2程序升温脱附(H2-TPD)、CO2程序升温脱附(CO2-TPD)等对催化剂进行表征。结果表明,载体对所制备的催化剂表面Pt含量、酸碱性和对氢吸附能力等微观性能有影响,以γ-Al2O3为载体制备的Pt-K/γ-Al2O3催化剂,由于催化剂表面Pt质量分数高达0.41%,碱性强和碱中心多,利于氢和中间产物在催化剂表面的吸附,从而提高环己烯基环己酮的转化率和OPP选择性。Pt/γ-Al2O3催化剂在LHSV 0.12 h-1、H2空速33 mL/(g.h)、反应温度380℃的条件下,在200 t/a的工业化装置运转8 000h后,环己酮二聚物转化率仍能达99%以上,OPP选择性达90%以上。 相似文献
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A commercial activated carbon (AC) was used as a catalyst support either in its original form or after two different oxidation treatments, namely air oxidation and HNO3 oxidation, aiming at the enhancement of its textural and surface chemical characteristics. These properties were determined by N2 adsorption and temperature programmed desorption (TPD), respectively. Monometallic Pt and bimetallic Pt–Sn catalysts were prepared on the AC supports. Impregnation was used in the preparation of the monometallic samples. For the bimetallic samples, coimpregnation and a sequential impregnation procedure, in which the Sn precursor is introduced prior to Pt, were used. The Pt load was kept fixed as 1 wt.% for all monometallic and bimetallic samples. Two different Sn loads, 0.25 and 0.50 wt.%, were used for the bimetallic samples in order to investigate the effects of Sn load on the catalytic properties. The catalyst samples were characterized by H2 adsorption, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and structure insensitive benzene hydrogenation. The activities of all samples were measured in CO oxidation. The results indicate the strong effects of the surface chemistry of the AC supports, the Pt:Sn ratio, the preparation procedure and the reduction procedure, on the CO oxidation activities of the catalysts. 相似文献