5083铝合金慢应变速率拉伸下的应力腐蚀行为

采用慢应变速率拉伸(SSRT)测试法及扫描电镜(SEM)与透射电镜(TEM)分析手段,研究了预变形量及应变速率对5083铝合金在空气和3.5%NaCl溶液中应力腐蚀开裂(SCC)行为的影响。结果表明:在空气中,5083铝合金几乎不发生SCC现象,其断口均呈现韧性断裂形貌;在3.5%NaCl溶液中,5083铝合金具有SCC敏感性,其断口呈现局部沿晶界或相界断裂形貌,随着应变速率的减小,应力腐蚀敏感指数(ISSRT)增大,当应变速率减至1×10-6s-1时,其应力腐蚀断口呈现典型的解理脆断特征;(Mg5Al8)等第二相析出及预变形后位错增多是导致5083铝合金SCC敏感性增大的主要原因。     

高速列车用Al7SiMg合金的应力腐蚀性能研究

对高速列车铸件用的Al7SiMg铝合金试样,分别在空气和NaCl水溶液环境中进行慢应变速率拉伸性能测试,比较其测试数据结果及断口形貌,研究Al7SiMg合金的应力腐蚀性能。研究结果表明:在质量分数为3.5%的NaCl水溶液环境中的拉伸性能略低于空气中的,在空气环境中测得的抗拉强度与NaCl水溶液环境中测得的抗拉强度之比值为0.96,而相应的两种环境中测得的伸长率之比例为0.85,计算得到的I_(SSRT)指数为0.049。观察试样断口形貌可以看出,Al7SiMg合金试样在质量分数为3.5%的NaCl水溶液环境中与空气中拉伸均表现出韧性断裂为主、存有少量沿晶开裂的特征,Al7SiMg合金的应力腐蚀并不敏感。     

氢对Al-8％Mg合金应力腐蚀开裂的影响

铝合金中氢对应力腐蚀开裂的作用,最近以来颇为引人关注。铝合金在应力腐蚀介质中所产生的脆性以及氢脆和应力腐蚀开裂之间的密切关系在许多文献中已有所论述。然而,对氢脆和应力腐蚀开裂之间关系的详细情况并非都非常清楚了。有些作者也研究了Al—8％Mg合金的这些现象,并观察到合金有相当大的脆性,也发现它们两者有着密切的关系。本文的目的在于阐明氢对Al—8％Mg合金应力腐蚀开裂的影响,并以氢脆的观点解释应力腐蚀     

Al-xMg-3.1Zn铝合金的应力腐蚀开裂行为及其机制

通过慢应变速率拉伸实验和动态电解充氢实验分别研究了Al-x Mg-3.1Zn铝合金的应力腐蚀开裂行为及其氢脆行为。结合宏观断口和微观断口形貌分析研究了合金发生应力腐蚀开裂的进程。通过对合金应力腐蚀开裂的机制进行分析阐明了合金中Mg元素含量对合金应力腐蚀开裂行为的影响。结果表明:在该合金体系中存在应力腐蚀开裂,且合金的应力腐蚀敏感性随合金中Mg含量的降低而降低,这与合金的阳极溶解行为与氢脆行为随Mg元素含量降低而减弱有着直接的关系。在这当中,合金中晶界析出相的数量随Mg元素含量降低而减少起到了至关重要的作用。     

热力管网波纹管开裂原因分析

对某热力管网使用5年后开裂破损的316L不锈钢波纹管进行了宏观形貌、金相组织、断口形貌及腐蚀产物的分析同时分析了波纹管开裂的原因.结果表明，波纹管开裂属应力腐蚀;造成应力腐蚀的介质是波纹管所处环境中（井室水中）的氯化物;应力来自波纹管的工作应力和加工应力.并提出了相应的防范措施.     

铸造铝合金A356抗应力腐蚀性能研究

研究铸造A356-T6铝合金在3．5％NaCl水溶液中的抗应力腐蚀性能,测定该环境条件下材料的应力腐蚀裂纹扩展速率及KIscc值,分析了合金的应力腐蚀机理。结果表明,A356-T6铝合金在3．5％NaCl水溶液中应力腐蚀敏感性较高。应力腐蚀开裂是阳极溶解和机械损伤共同作用的结果,其断口为穿晶脆断形貌。     

热电厂波纹管开裂原因分析

对某电厂使用几百小时而破损的3层不锈钢波纹管，进行了宏观、金相、断口形貌及腐蚀产物的分析.结果表明，波纹管破裂从内层开始，逐渐引发中间层和外层开裂；开裂是由于内层水蒸气结露，水蒸气中的氯化物浓缩而导致穿晶型应力腐蚀开裂；应力来自工作应力和冷加工残余应力.管壁上除环向裂纹，还有轴向裂纹,呈树枝状.     

铝合金焊接热裂缝断口形貌分析

本文用扫描电子显微镜及电子探针对Al—4.5Cu—Si—Mg合金焊缝金属结晶裂缝及多层焊时产生的液化裂缝断口进行了研究。同时,使用示波器测量并记录了结晶裂缝产生的温度,相应地分析了在不同结晶温度下开裂的结晶裂缝的断口形貌特征。对产生在焊缝金属中及近缝区基本金属中的液化裂缝断口形貌特征进行了分析。在此基础上,得出了从断口形貌上区分结晶裂缝与液化裂缝断口形貌特征。     

变电站电流互感器铝合金法兰腐蚀失效分析

针对沿海变电站电流互感器压力释放膜铝合金法兰的实际腐蚀失效问题开展研究。通过对铝合金法兰成分、腐蚀形貌及腐蚀产物成分等分析,结合实际服役环境特点和电化学腐蚀行为分析,研究了其腐蚀失效原因及机理。结果表明,沿海工业环境下,铝合金CT压力释放膜法兰发生腐蚀及应力腐蚀开裂(SCC),腐蚀产物以Al的氯化物为主;Cl~-和S~(2-)是造成其腐蚀失效的重要环境因素,Cl~-和应力协同作用导致其SCC,法兰应采用耐Cl、S腐蚀及抗SCC铝合金,加强表面防腐蚀设计,不应在没有防护措施的条件下直接使用7A05铝合金。     

铝合金显微组织的不均匀性与分级时效理论(上)

电子显微镜的广泛应用,使人们对铝合金的显微组织有了进一步的了解。热处理强化型铝合金显微组织的不均匀性,就是电子显微镜研究的重要成果之一。应力腐蚀敏感性高的Al—Zn—Mg系和Al—Zn—Mg—Cu系合金的通     

Correlations among stress corrosion cracking,grain-boundary microchemistry,and Zn content in high Zn-containing Al–Zn–Mg–Cu alloys

The correlations among the corrosion behaviour, grain-boundary microchemistry, and Zn content in Al–Zn–Mg–Cu alloys were studied using stress corrosion cracking (SCC) and intergranular corrosion (IGC) tests, combined with scanning electron microscopy (SEM) and high-angle angular dark field scanning transmission electron microscopy (HAADF-STEM) microstructural examinations. The results showed that the tensile strength enhancement of high Zn-containing Al–Zn–Mg–Cu alloys was mainly attributed to the high density nano-scale matrix precipitates. The SCC plateau velocity for the alloy with 11.0 wt.% Zn was about an order of magnitude greater than that of the alloy with 7.9 wt.% Zn, which was mainly associated with Zn enrichment in grain boundary precipitates and wide precipitates-free zones. The SCC mechanisms of different Zn-containing alloys were discussed based on fracture features, grain-boundary microchemistry, and electrochemical properties.     

Effect of high-temperature pre-precipitation on mechanical properties and stress corrosion cracking of Al-Zn-Mg alloys

1　INTRODUCTIONMediumandhighstrengthAl Zn Mgseriesaluminumalloysarethe primaryweldingstructurematerialsofaerocrafts ,transportationvehiclesandmilitaryequipments[1,2 ] ,duetoitsbetterweldabilityandexcellenttechnologicalproperty .Buttheexten siveutilizationofthesealloysishamperedbyitspoorstresscorrosioncracking (SCC)resistance[3,4 ] .Ac cordingly ,manystudieshavebeenconcernedwithsuchaproblemashowtoimprovestresscorrosionre sistanceofAl Zn Mgalloyswithnon deterioratedstrength[3,58] .Atpres…     

Effects of Pb and Cu additives on microstructure and wear corrosion resistance behaviour of PM Al–Si alloys

Abstract

The wear and wear corrosion resistance behaviour of Al–20Si–XPb–YCu (X=0–10 wt-%, Y=0–3 wt-%) alloys fabricated by a powder metallurgy (PM) technique and subsequent heat treatments were evaluated by a block on ring tribotest. The microstructure of all aluminium alloys was observed by optical microscopy and scanning electron microscopy with X-ray energy dispersive spectroscopy. The effects of applied potentials and environments including dry air and 3.5 wt-%NaCl aqueous solution were studied. The results of microstructure analysis indicated that Pb exhibited a bimodal distribution in the Pb containing alloys, and Cu particles become to form the intermetallic phase CuAl₂. Furthermore, the hardness rises significantly for both Pb and Cu containing alloys only after solid solution quenching treatment. The wear and corrosion results showed that the addition of both lead and copper would improve the wear resistance but lead to a higher corrosion rate whereas heat treatment had a beneficial effect of reducing the corrosion rate of most alloys with the exception of Al–Si alloy. Furthermore, by comparison of all alloys after heat treatment, the wear corrosion resistance of Al–Si alloy was inferior to the other alloys; consequent additions of Pb and Cu further improved its wear corrosion resistance. Moreover, at an anodic potential, the wear corrosion rate and current density of both Al–Si and Al–Si–Cu alloys containing particle Pb decrease significantly owing to a corrosion product layer composed of Al, O and Pb elements.     

Corrosion resistance of aluminum-lithium alloys under various climatic conditions

The corrosion resistance (stress corrosion cracking, exfoliation, intergranular corrosion) of a wide group of aluminum-lithium alloys has been studied under atmospheric conditions with various corrosion environments. Corrosion behavior of experimental and commercial batches of aluminum-lithium alloys has been established as a function of the chemical composition of the alloys and ratio of Cu/Mg, Li/Cu + Mg. Under atmospheric conditions, the best corrosion properties are those of an alloy with a Cu/Mg ratio of 0.5 and a ration of Li/Cu + Mg of 0.96. It has been proved that a decrease in Li/Cu + Mg to 0.56–0.76 leads to impairment of corrosion properties. Accelerated corrosion tests result in the same conclusions.     

纯镁和镁合金强流脉冲电子束表面合金化性能

利用强流脉冲电子束对纯镁及镁合金AZ31和AZ91HP进行表面合金化处理。用光学显微镜和扫描电镜对表面处理层形貌和组织进行了分析,腐蚀性能和摩擦磨损测试表明:纯镁表面合金化铝后,样品抗5%NaCl溶液腐蚀性能得到显著提高,维钝电流降低2个数量级以上;而镁合金AZ31以及AZ91HP表面合金化Cr、TiN后,耐磨性均得到提高。     

Cu／Mg比对AA7085显微组织与性能影响

采用熔铸法制备具有不同Cu／MgLk（0．67,1．0,1．06,1．6）的AA7085铝合金。采用金相显微镜、扫描电镜、力学性能测试和腐蚀测试研究Cu／Mg比对基体合金显微组织、力学性能和腐蚀行为的影响。结果表明,当Cu／Mg比为1．6时,AA7085铝合金具有更好的抑制再结晶能力和抗腐蚀性能。当Cu／Mg比为0．67时,铝合金具有更为优越的力学性能,其抗拉强度与屈服强度分别达到586和550MPa。而当Cu／Mg比为1．0时,合金的力学性能和耐腐蚀性能均下降。     

晶界结构在不同热处理下对铝镁合金腐蚀规律的研究现状

铝镁合金是未来应用汽车领域发展具有很大潜力的一类重要材料.通常,在商品中的铝镁合金,镁的质量分数在0.5%～13%.汽车制造商通常选用镁的质量分数在4.5%以上,然而研究发现,当镁的质量分数超过3%的时候,会引起晶界间腐蚀,从而造成应力腐蚀开裂.此现象未见文献对其进行系统的分析和研究.本文主要介绍铝镁合金在不同的热处理...     

铝合金在海洋环境中的腐蚀研究(Ⅱ)--海水全浸区16年暴露试验总结

总结了铝合金在青岛海域海水全浸区暴露16年的腐蚀结果，防锈铝LF2Y2，LF6M（BL），F21M，180YS在海水全浸区有好的耐蚀性，工业纯铝L4M，锻铝LD2CS的耐蚀性较差，无包铝层的硬铝LY12CZ和超硬铝LC4CS在海水中的耐蚀性很差，硬铝，超硬铝的包铝层起牺牲阳极作用，使基体受到保护，海生物污损对铝合金在海水中的腐蚀有明显影响，镁、锰能提高铝的耐海水腐蚀性，硅明显降低铝的耐蚀性，铜严重损害铝的耐蚀性，腐蚀电位较负的铝合金耐海水腐蚀性较好，腐蚀电位较正的铝合金耐海水腐蚀性较差。     

Stress-corrosion cracking of aged AlCuMg alloys in NaCl solution

Pitting potentials and stress corrosion life-times of AlCuMg alloys (mainly 2024 alloy) with various ageing structures have been measured in a de-aerated 1M NaCl solution under conditions of controlled potential. The aged alloy, which has the higher susceptibility to stress-corrosion cracking, showed two pitting potentials corresponding to pitting at the grain boundaries and within the grains. The susceptibility of the alloys to intergranular stress-corrosion cracking occurred at potentials above the pitting potential of the grain boundaries. The intergranular stress-corrosion cracking is caused not by the dissolution of the grain boundary precipitates (S phase) but by the pitting dissolution of the solute-denuded zones along the grain boundaries. Aspects of SCC in the alloys are similar to those in the Al-4%Cu alloy without Mg.