无取代硫代双烯金属络合物的合成及其在夜视兼容技术中应用

为了研制夜视兼容照明器件用近红外滤光片,合成了最大吸收波长在近红外区域(855nm)的无取代基硫代双烯镍络合物(NIR DYE-01),其结构为(RCSCSR)2Ni(R=苯环)的近红外染料,单独以该染料为原料制备了近红外吸收滤光片,透射曲线表明滤光片具备(780nm～930nm)波段的近红外吸收能力;将该染料与近红外吸收剂IR-01配合制备近红外吸收滤光片,透射曲线表明滤光片具备(600nm～930nm)波段的近红外吸收能力,NR值测试结果表明近红外滤光片的光谱辐亮度符合夜视兼容的要求.     

硫代双烯型近红外染料及其在PMMA滤光片中的光稳定性

合成了3个最大吸收波长在近红外区域的硫代双烯镍络合物,用元素分析、核磁共振氢谱、质谱及红外光谱表征了中间体及产物的结构,并测试了染料在溶液和PMMA滤光片中的光谱性质.结果表明,染料的最大吸收波长与溶剂的极性成正比,其中结构为(RCSCSR)2Ni(R=C6H4-C(CH3)3)的染料,自身的光稳定性最好;当掺杂在PMMA滤光片中时,它们的最大吸收波长位置与在溶剂中的相近,光稳定性能比在溶液中好.     

近红外吸收滤光片的制备与性能研究

将两种近红外吸收剂添加到丙烯酸树脂基体中再与PET薄膜复合,制备了可用于夜视兼容照明的双层复合型近红外吸收滤光片.研究了两种近红外吸收剂的吸收特性,以及近红外吸收剂添加量与滤光片吸收性能的关系,并确定了两种近红外吸收剂的用量.所制备的滤光片在660 ～930 nm波长范围内的光线平均透过率为0.10％,能有效吸收发光器...     

Cu(Ⅱ)有机磷酸酯配合物与甲基丙烯酸甲酯共聚物的近红外吸收性能研究

以苯甲酸铜和磷酸甲基丙烯酰氧乙基酯反应,制备了一种近红外吸收剂,将其与甲基丙烯酸甲酯共聚,制备了近红外吸收滤光片,研究了该滤光片的近红外吸收性能,紫外-可见-近红外光谱表明:Cu(Ⅱ)有机磷酸酯配合物与甲基丙烯酸甲酯共聚物具有良好的近红外吸收性能,随着聚合物中Cu(Ⅱ)含量的增加,滤光片吸收近红外线强度和吸收波长范围都随之增大,Cu(Ⅱ)含量为10.5%的共聚物滤光片在685～1070nm波长范围红外线透过率低于0.01%,光谱辐射计测试的该样品的光谱辐亮度值在740～930nm波长范围内低于1×10-12.     

近红外吸收PVB薄膜的制备及性能分析

以聚乙烯醇缩丁醛(PVB)为基体,近红外吸收染料NIR775和NIR858为添加剂,采用熔融混合、模压成型的方法制备了近红外吸收滤光薄膜。热失重分析(TG)表明:两种近红外吸收染料都具有较好的热稳定性。透射光谱显示薄膜同时具有较好的近红外吸收性能和较高的可见光透过率。当近红外吸收染料NIR775和NIR858的含量分别为0.2 wt%和0.4 wt%时,薄膜在660~930 nm波段的平均光透过率为0.148%,在400~630 nm波段的平均光透过率为23.578%。薄膜具有较好的耐热老化性能。近红外吸收染料在基材中的分散不均匀,有颗粒存在。     

基于酞菁类和二亚铵类近红外吸收染料的等离子显示器滤光膜的性能对比研究

等离子显示器中的潘宁气体在放电过程中会产生近红外线、氖黄光,干扰遥控器等设备,影响观看效果,需安装滤光膜。文章对以酞菁类、二亚铵类为近红外吸收染料的PDP滤光膜进行了对比研究,实验结果表明,酞菁类、二亚铵类滤光膜具有良好的耐湿热、耐高温性能,二亚铵类滤光膜相对于酞菁类滤光膜具有较好的光稳定性能,且可见光区透过率可达到60%以上,适合应用于高透过率PDP滤光膜。     

近红外吸收染料

本文叙述近红外吸收染料在光学与光电子技术中应用，如红外照相、染料激光、光和电子照相等。     

Eddy公司低成本导弹告警系统

Eddy公司与Johns Hopkins大学应用物理实验室（APL）的研究者合作,研制并成功测试了一种低成本系统,采用可见光近红外光谱区域技术用于导弹告警,降低了成本,提高了性能．该传感器系统包括一个传统光学组件、一个磁光滤光片（MOF）、摄像机组件和处理器组件．关键技术是大视角磁光滤光片,开发该技术最初是为研究太阳．Eddy公司已经设计并制作了用于太阳物理和其他民用的窄视场磁光滤光片．这种合作研究的结果是设计的磁光滤光片组件发生了戏剧化的改变,提高了滤光片的通量并降低了使用功率,可在一般军用或民用条件下使用．长度由传统的5in缩减到约为1．5in．     

用激光进行的非侵入血液抽样

对于待研究的每种分子，必须使两种波长透过血液样品。一种波长必须位于所研究气体分子的特征吸收带以内（例如，对于CO，大约为5．13微米）。而另一种波长应在附近的波长处，不为分子所吸收。把吸收信号的大小标准化为非吸收信号的大小，就可以确定吸收气体的绝对浓度。本发明的关键在于，各种血液气体只在红外区内分立波长处有吸收，与在可见和近红外区内它们的连续吸收和重迭吸收不同。     

微型长波近红外物联网节点及实验研究

研制基于线性渐变滤光片和InGaAs焦平面的微型化物联网节点,实现长波近红外光谱数据的采集和无线传输,针对节点的波长范围、分辨率、波长准确性和波长稳定性等参数指标开展性能研究实验.实验结果表明,节点的波长范围为950~1 700 nm,光谱分辨率随波长增加而增大,约为峰值波长的1%,与滤光片特性相符,波长准确性优于1.3 nm,波长重复性优于0.1 nm,可以满足物联网中的近红外光谱分析应用需求.     

Ultrasmall Semiconducting Polymer Dots with Rapid Clearance for Second Near‐Infrared Photoacoustic Imaging and Photothermal Cancer Therapy

Phototheranostic agents in the second near‐infrared (NIR‐II) window (1000–1700 nm) are emerging as a promising theranostic platform for precision medicine due to enhanced penetration depth and minimized tissue exposure. The development of metabolizable NIR‐II nanoagents for imaging‐guided therapy are essential for noninvasive disease diagnosis and precise ablation of tumors. Herein, metabolizable highly absorbing NIR‐II conjugated polymer dots (Pdots) are reported for the first time for photoacoustic imaging guided photothermal therapy (PTT). The unique design of low‐bandgap D‐A π‐conjugated polymer (DPP‐BTzTD) together with modified nanoreprecipitation conditions allows to fabricate NIR‐II absorbing Pdots with ultrasmall (4 nm) particle size. Extensive experimental tests demonstrate that the constructed Pdots exhibit good biocompatibility, excellent photostability, bright photoacoustic signals, and high photothermal conversion efficiency (53%). In addition, upon tail‐vein intravenous injection of tumor‐bearing mice, Pdots also show high‐efficient tumor ablation capability with rapid excretion from the body. In particular, both in vitro and in vivo assays indicate that the Pdots possess remarkable PTT performance under irradiation with a 1064 nm laser with 0.5 W cm^?2, which is much lower than its maximum permissible exposure limit of 1 W cm^?2. This pilot study thus paves a novel avenue for the development of organic semiconducting nanoagents for future clinical translation.     

All‐in‐One Phototheranostics: Single Laser Triggers NIR‐II Fluorescence/Photoacoustic Imaging Guided Photothermal/Photodynamic/Chemo Combination Therapy

Development of single near‐infrared (NIR) laser triggered phototheranostics for multimodal imaging guided combination therapy is highly desirable but is still a big challenge. Herein, a novel small‐molecule dye DPP‐BT is designed and synthesized, which shows strong absorption in the first NIR window (NIR‐I) and fluorescence emission in the second NIR region (NIR‐II). Such a dye not only acts as a dual‐modal contrast agent for NIR‐II fluorescence and photoacoustic (PA) imaging, but also serves as a combined therapeutic agent for photothermal therapy (PTT) and photodynamic therapy (PDT). The single NIR laser triggered all‐in‐one phototheranostic nanoparticles are constructed by encapsulating the dye DPP‐BT, chemotherapy drug DOX, and natural phase‐change materials with a folic acid functionalized amphiphile. Notably, under NIR laser irradiation, DOX can effectively release from such nanoparticles via NIR‐induced hyperthermia of DPP‐BT. By intravenous injection of such nanoparticles into Hela tumor‐bearing mice, the tumor size and location can be accurately observed via NIR‐II fluorescence/PA dual‐modal imaging. From in vitro and in vivo therapy results, such nanoparticles simultaneously present remarkable antitumor efficacy by PTT/PDT/chemo combination therapy, which is triggered by a single NIR laser. Overall, this work provides an innovative strategy to design and construct all‐in‐one nanoplatforms for clinical phototheranostics.     

PEGylated Micelle Nanoparticles Encapsulating a Non‐Fluorescent Near‐Infrared Organic Dye as a Safe and Highly‐Effective Photothermal Agent for In Vivo Cancer Therapy

Photothermal therapy (PTT), as a minimally invasive and highly effective cancer treatment approach, has received widespread attention in recent years. Tremendous effort has been devoted to explore various types of photothermal agents with high near‐infrared (NIR) absorbance for PTT cancer treatment. Despite many exciting progresses in the area, effective yet safe photothermal agents with good biocompatibility and biodegradability are still highly desired. In this work, a new organic PTT agent based on polyethylene glycol (PEG) coated micelle nanoparticles encapsulating a heptamethine indocyanine dye IR825 is developed, showing a strong NIR absorption band and a rather low quantum yield, for in vivo photothermal treatment of cancer. It is found that the IR825–PEG nanoparticles show ultra‐high in vivo tumor uptake after intravenous injection, and appear to be an excellent PTT agent for tumor ablation under a low‐power laser irradiation, without rendering any appreciable toxicity to the treated animals. Compared with inorganic nanomaterials and conjugated polymers being explored in PTT, the NIR‐absorbing micelle nanoparticles presented here may have the least safety concern while showing excellent treatment efficacy, and thus may be a new photothermal agent potentially useful in clinical applications.     

Molecularly Engineered Near‐Infrared Light‐Emitting Electrochemical Cells

The development of near‐infrared (NIR) luminescent materials has emerged as a promising research field with important applications in solid‐state lighting (SSL), night‐vision‐readable displays, and the telecommunication industry. Over the past two decades, remarkable advances in the development of light‐emitting electrochemical cells (LECs) have stunned the SSL community, which has in turn driven the quest for new classes of stable, more efficient NIR emissive molecules. In this review, an overview of the state of the art in the field of near‐infrared light‐emitting electrochemical cells (NIR‐LEC) is provided based on three families of emissive compounds developed over the past 25 years: i) transition metal complexes, ii) ionic polymers, and iii) host–guest materials. In this context, ionic and conductive emitters are particularly attractive since their emission can be tuned via molecular design, which involves varying the chemical nature and substitution pattern of their ancillary ligands. Herein, the challenges and current limitations of the latter approach are highlighted, particularly with respect to developing NIR‐LECs with high external quantum efficiencies. Finally, useful guidelines for the discovery of new, efficient emitters for tailored NIR‐LEC applications are presented, together with an outlook towards the design of new NIR‐SSL materials.     

Highly Efficient Solid‐State Near‐Infrared Emitting Material Based on Triphenylamine and Diphenylfumaronitrile with an EQE of 2.58% in Nondoped Organic Light‐Emitting Diode

The development of efficient near‐infrared (NIR) emitting material is of current focus. Donor–acceptor (D–A) architecture has been proved to be an effective strategy to obtain narrow energy gap. Herein, a D–A‐type NIR fluorescent compound 2,3‐bis(4′‐(diphenylamino)‐[1,1′‐biphenyl]‐4‐yl)fumaronitrile (TPATCN) is synthesized and fully characterized. As revealed by theoretical calculations and photophysical experiments, TPATCN exerts the advantages of the relatively large dipole moment of the charge transfer state and a certain degree of orbital overlap of the local excited state. A highly mixed or hybrid local and charge transfer excited state might occur to simultaneously achieve both a large fraction of singlet formation and a high quantum efficiency in D–A system. TPATCN exhibits strong NIR fluorescence with the corresponding thin film quantum efficiency of 33% and the crystal efficiency of 72%. Remarkably, the external quantum efficiency of nondoped NIR organic light‐emitting diode (OLED) reaches 2.58% and remains fairly constant over a range of 100–300 mA cm^?2, which is among the best results for NIR OLEDs reported so far.     

激光辅助照明主动近红外成像系统

研制了一种激光辅助照明主动近红外成像组件。该组件使用半导体激光光纤耦合器件作为夜视光源,通过其在暗场自然环境下的成像验证了光源补光性能和选用的CCD芯片对特定波段光源具有较高的响应度。该组件可实现全天候成像,不受外界照度的制约,可广泛应用于科研、监控等领域。     

Molecular Imaging in the Second Near‐Infrared Window

In the past decade, noticeable progress has been achieved regarding fluorescence imaging in the second near‐infrared (NIR‐II) window. Fluorescence imaging in the NIR‐II window demonstrates superiorities of deep tissue penetration and high spatial and temporal resolution, which are beneficial for profiling physiological processes. Meanwhile, molecular imaging has emerged as an efficient tool to decipher biological activities on the molecular and cellular level. Extending molecular imaging into the NIR‐II window would enhance the imaging performance, providing more detailed and accurate information of the biological system. In this progress report, selected achievements made in NIR‐II molecular imaging are summarized. The organization of this report is based on strategies underlying rational designs of NIR‐II imaging probes, and their applications in molecular imaging are highlighted. This progress report may provide guidance and reference for further development of functional NIR‐II probes designed for high‐performance molecular imaging.     

用近红外光谱技术快速测定聚氯乙稀K值的新方法——正交信号校正法

本文基于正交投影的正交校正算法(OSC),建立了聚氯乙稀近红外光谱与其K值之间关系的数学模型,提出了用近红外漫反射光谱技术快速检测聚氯乙稀K值的新方法。研究结果表明,原始光谱经正交信号校正处理后,聚氯乙稀K值化学测定值与近红外预测值的相关系数和标准差为R=0.9825、RMSEP=0.5933,预测结果的相对误差在0.5%以内,且正交信号校正算法能取得比单纯使用偏最小二乘回归更好的预测效果,模型更为简单。为用近红外光谱快速测定聚氯乙稀的K值提供了一条新途径。