共查询到20条相似文献,搜索用时 46 毫秒
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综述了纳米填料/橡胶复合体系在熔融态或高弹态贮存停放过程中,影响其结构形态变化的因素,以及贮存停放对复合体系流变性能、物理机械性能和导电性能的影响,并评述了相关的理论模型。纳米填料/橡胶复合体系在熔融贮存过程中的结构变化主要受橡胶的黏度、填料特性及其用量、填料与橡胶之间的相互作用以及加工性能的影响。填料网络结构的絮凝程度强化使复合体系流变性能、动态力学性能降低,但导电性能提高。相关的填料聚集动力学和填料絮凝模型大部分是唯象模型。 相似文献
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正上世纪60年代初开始,在过去的几十年里,对熵在橡胶熔体流变性能中的作用,尤其是流动不稳定性进行了深入研究。尤其研究了橡胶和软化剂间的相互作用,及其对流变数据的影响。另外,还进行了磁流变研究,通过外部磁场影响流变性能。通过流变和介电分析深入研究了高温下橡胶熔体中填料的网状结构。这证实了我们纳米结构填料粒子补强橡胶的基本概念和基础理论。尤其是证明了相邻填料粒子间存在纳米级间隙,间隙由结合聚合物链填充。由于吸附性填料表面的 相似文献
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一种新的填料分散技术(一) 总被引:1,自引:0,他引:1
增强聚合物的性能不仅依赖于填料特性,还和填料的分散以及在聚合物-填料界面产生的相互作用有关。通过使用一种分散助剂和一些偶联剂,可以优化复合材料的最终性能。今天,硅烷被广泛用作偶联剂和增粘剂,而且还作为填料分散助剂用于聚合物基体中。道康宁(Dow Corning)公司的Valerie Smits、Pierre Chevalier、Damien Deheunynck和Scott Miller概述了硅烷处理对复合材料性能的影响,并介绍了分散助剂的新产品系列。 相似文献
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The dependencies of the notched Izod impact toughness of HDPE / CaCO3 blends on CaCO3 particle concentration and particle size are analyzed. It was found that the notched Izod impact strength (S) of HDPE / CaCO3 blends depends discontinuously on CaCO3 particle concentration. A brittle-ductile transition occurs when the CaCO3 volume fraction (Vf) increases to a critical value (Vηf). Furthermore, a brittle-ductile transition master curve can be constructed by taking the matrix ligament thickness (L) into account as a parameter instead of Vf. The results show that the critical matrix ligament thickness (Lc) is a single parameter for the transition and Lc = 5.2μm for HDPE / CaCO3 blends. The impact strength, however, varies considerably with CaCO3 particle size, which shows that CaCO3 particle size is another dominating parametor for the toughness of HDPE / CaCO3 blends. © 1993 John Wiley & Sons, Inc. 相似文献
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The Archimedes' principle and physical theory are attempted to analysis the densification and structure of the polystyrene (PS) composites by melt compounding with CaCO3 having different particle size. The difference between the measured specific volume (ν) andthe theoretically calculated specific volume (νmix), Δν = ν−νmix, can reflect the densification of the composites. It is clearly demonstrated that the PS composites become more condensed with the reduction of the CaCO3 particle size. Especially, when the content for nano‐CaCO3 achieves 2 wt%, the Δν value of the composites reaches the least, which shows the best densification. Meanwhile, the glass transition temperature (Tg) reaches the maximum value of about 100°C by differential scanning calorimetry (DSC) and thermal mechanical analysis (TMA), which indirectly reveals the composites microstructure more condensed. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) reveal that 2 wt% nano‐CaCO3 uniformly disperses in PS composites. The CaCO3 selected in this experiment has certain toughening effect on PS. The impact and tensile strength increase with addition of nano‐CaCO3, but the elongation at break decreases. When nano‐CaCO3 content achieved 2 wt%, the impact and tensile strength present the maximum value of 1.63 KJ/m2 and 44.5 MPa, which is higher than the pure PS and the composites filled with the same content of micro‐CaCO3. POLYM. COMPOS., 31:1258–1264, 2010. © 2009 Society of Plastics Engineers 相似文献
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以偶联改性纳米CaCO3和甲基丙烯酸甲酯(MMA)为原料,原位乳液聚合制得PMMA接枝包覆纳米CaCO3,以其与PVC熔融共混制备复合材料,研究了纳米CaCO3在共混体中的分散和与PVC界面的结合.与未改性纳米CaCO3相比,纳米CaCO3接枝包覆PMMA后,在PVC中的分散性能得到明显改善,粒子被分散得更加细小、均匀.PMMA接枝包覆纳米CaCO3与PVC界面间相容性能最好,比小分子改性CaCO3与PVC间的黏结作用更强.采用PMMA包覆纳米CaCO3粒子改性PVC,比未改性纳米CaCO3改性PVC有更好的冲击性能及拉伸性能. 相似文献
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本文研究了纳米CaCO3表面改性的影响因素,确定了最优改性剂和改性条件,并运用沉降实验、透射电镜(TEM)等表征手段对粉体的改性效果进行了分析。结果表明:以月桂酸钠为改性剂,用量为10%,pH值为7,改性时间为1h时,改性后的纳米CaCO3的亲油化度达到85.1%,能较好地分散于环己烷和二甲苯中。 相似文献
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The shear rheological properties of polystyrene (PS)/nano‐CaCO3 composites were studied to determine the plasticization of nano‐CaCO3 to PS. The composites were prepared by melt extrusion. A poly(styrene–butadiene–styrene) triblock copolymer (SBS), a poly(styrene–isoprene–styrene) triblock copolymer (SIS), SBS‐grafted maleic anhydride (SBS–MAH), and SIS‐grafted maleic anhydride were used as modifiers or compatibilizers. Because of the weak interaction between CaCO3 and the PS matrix, the composites with 1 and 3 phr CaCO3 loadings exhibited apparently higher melt shear rates under the same shear stress with respect to the matrix polymer. The storage moduli for the composites increased with low CaCO3 concentrations. The results showed that CaCO3 had some effects on the compatibility of PS/SBS (or SBS–MAH)/CaCO3 composites, in which SBS could effectively retard the movement of PS chain segments. The improvement of compatibility, due to the chemical interaction between CaCO3 and the grafted maleic anhydride, had obvious effects on the rheological behavior of the composites, the melt shear rate of the composites decreased greatly, and the results showed that nano‐CaCO3 could plasticize the PS matrix to some extent. Rheological methods provided an indirect but useful characterization of the composite structure. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006 相似文献
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The effects of 40 and 50 wt% of calcium carbonate on the mechanical properties of polypropylene were investigated by uniaxial tensile deformation at room temperature and at loading rates of 5, 50, and 125 mm/min. The results showed that the addition of calcium carbonate to polypropylene decreased yield strength while increasing modulus. The decreases yield strength was attributed to the poor adhesion between filler and matrix. The tensile toughness of polypropylene was improved by the addition of calcium carbonate particles at constant strain rate because of the plastic deformation of interparticle ligaments following particle‐matrix debonding. The (strain rate) sensitive behavior of the composites (at constant calcium carbonate content) was observed. J. VINYL ADDIT. TECHNOL., 19:271–275, 2013. © 2013 Society of Plastics Engineers 相似文献
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纳米级CaCO3填充HDPE复合材料的研制 总被引:53,自引:4,他引:49
研究了纳米级CaCO3填充HDPE体系的力学性能和流变性能,发现这种填充体系的脆韧变消失,且具有良好的加工性能和优良和综合性能。 相似文献
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稀土钛偶联剂对CaC03改性及其在PE-LLD中的应用研究 总被引:1,自引:0,他引:1
采用万能试验机、转矩流变仪和旋转黏度计等研究了新型稀土钛偶联剂对不同粒径重质碳酸钙(CaCO3)的偶联处理及其对PE—LLD/CaCO3复合体系的力学性能和流变性能的影响。结果表明,稀土钛偶联剂改性的不同粒径CaCO3填充的复合体系的力学性能和流变性能得到很大改善;其中,稀土钛偶联剂处理粒径18μm重质CaCO3效果最好,当偶联剂含量为1.2%(质量分数,下同)时,复合体系的断裂伸长率、拉伸强度和拉伸弹性模量分别比未改性的提高了14.7%、12.5%和10.3%,而最大扭矩和平衡扭矩比未改性的分别降低了11.4%和9.6%;其改性效果均优于钛酸酯和铝酸酯偶联剂。实验表明稀土钛偶联剂处理的CaCO3在非极性液体石蜡中有较好的分散性和相容性。 相似文献