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研究偶联剂(Si69和B-69)与离子液体溴化1-丁基-3-甲基咪唑(BMIM)单用和并用改性白炭黑补强天然橡胶(NR)的性能。结果表明:与未改性白炭黑补强NR胶料相比,偶联剂Si69、偶联剂B-69和BMIM改性白炭黑补强NR胶料的硫化速率加快,Payne效应减弱,物理性能和耐磨性能提高,滚动阻力降低,偶联剂Si69改性白炭黑的效果优于偶联剂B-69;与偶联剂单用改性白炭黑补强NR胶料相比,偶联剂/BMIM并用改性白炭黑补强NR胶料的硫化速率加快,白炭黑与NR相互作用增强,交联密度增大,物理性能和耐磨性能显著提高,滚动阻力降低,偶联剂B-69/BMIM并用改性白炭黑补强NR胶料的滚动阻力小于偶联剂Si69/BMIM并用改性白炭黑补强NR胶料,抗湿滑性能相差不大;BMIM改性白炭黑补强NR胶料的综合性能最佳。 相似文献
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研究硅烷偶联剂(偶联剂Si69和KH570)和表面活性剂[聚乙二醇(PEG)和十八醇]作为白炭黑改性剂对天然橡胶(NR)性能的影响。结果表明:与无改性剂胶料相比,添加改性剂胶料的硫化速度加快,填料网络结构降低;两种偶联剂和PEG胶料的交联密度增大,300%定伸应力、撕裂强度和耐磨性能提高;两种偶联剂胶料的拉伸强度提高,两种表面活性剂胶料的拉伸强度降低;两种偶联剂和十八醇胶料的结合胶质量分数增大。改性剂有助于改善白炭黑的分散性能及其与橡胶基体的作用,偶联剂Si69对白炭黑胶料的改性效果最好。 相似文献
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以全钢载重子午线轮胎用高白炭黑含量胶料配方为基体,研究硅烷偶联剂Si69与活性剂PEG4000协同作用改性白炭黑对胶料性能的影响。结果表明:硅烷偶联剂Si69和活性剂PEG4000对提高白炭黑分散效果不存在协同作用;对降低胶料的门尼粘度、延长t10及提高硫化胶的抗硫化返原率、硬度、定伸应力和降低生热方面存在明显的协同作用;硅烷偶联剂Si69用量为5.2份、活性剂PEG4000用量为3份时,胶料的门尼粘度和硫化胶的生热最低,硫化胶的定伸应力、拉伸强度和拉断伸长率均较高,综合性能较佳。 相似文献
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考察白炭黑改性工艺对白炭黑胶料性能的影响,研究白炭黑表面原位接枝改性剂XM的应用。结果表明:用白炭黑预混炼改性工艺和白炭黑预处理改性工艺对白炭黑进行有机化改性,白炭黑胶料的性能提高;与白炭黑预混炼改性工艺胶料相比,白炭黑预处理改性工艺胶料的混炼工艺简单,形成的乙醇气体少,偶联剂Si69用量小,强度性能、耐磨性能、耐屈挠性能和抗刺扎性能提高,生热明显降低;采用改性剂XM改性白炭黑,胶料的加工安全性能和抗硫化返原性能提高,拉伸强度、拉断伸长率、撕裂强度和正硫化时的定伸应力提高,耐热老化性能较好。改性剂XM的应用为解决硅烷偶联剂产生乙醇气体和影响胶料加工安全性能提供了思路。 相似文献
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本文选用双-(γ-三乙氧基硅基丙基)四硫化物(Si-69)为改性剂,利用球磨法制备了接枝改性白炭黑。利用热失重法(TG)分析了改性剂用量和改性时间等因素对接枝率的影响。将改性白炭黑用于天然橡胶(NR)/ 反式聚异戊二烯(TPI)的补强中,比较了未改性白炭黑和改性白炭黑对胶料的硫化性能、物理机械性能和动态性能等的影响。结果表明,在0~12份范围内,改性剂用量越大,白炭黑接枝率越高,但综合物理机械性能最佳值则出现在改性剂用量为10份时。在15~45 min范围内,改性时间对白炭黑接枝率影响不明显,但当改性时间为45 min时,综合物理机械性能最佳。白炭黑经接枝改性后改善了其在橡胶基体中的分散性和与橡胶基体的相容性,添加改性白炭黑胶料的抗湿滑性能、滚动阻力和动态生热性能均有改善。 相似文献
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乙烯酮(双乙烯酮)是十分重要的化工中间体,其下游产品较多。江苏某化工厂开发生产乙烯酮(双乙烯酮)下游产品三十多个,年生产规模三万多吨,是国内以乙烯酮(双乙烯酮)为中间体生产精细化学品的综合骨干企业。针对乙烯酮(双乙烯酮)下游产品废水特点,该厂结合企业实际,开展了产品优化,结构调整,清洁生产,资源循环利用,节水降耗等工作,从源头削减了污染物的生产。同时投资二千多万元新建预处理装置三套,6000m3/d废水生化处理装置一套,使全厂乙烯酮(双乙烯酮)下游产品的废水得到了有效的治理。 相似文献
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The miscibility of various amorphous polybutadienes with mixed microstructures of 1,4 addition units (cis, 1,4 and trans 1,4) and 1,2 addition units have been investigated. The studies here involved optical transparency, differential scanning calorimetry, and small angle light scattering. It was found that a 90 percent (cis) 1, 4 addition polybutadiene was immiscible with high (91 percent) 1,2 addition polybutadiene. Reduction of the 1,2 content to 71 percent induced an upper critical solution temperature (UCST) with the cis 1,4 polymer. Polybutadienes with 50 percent and 10 percent 1,2 contents were miscible above the crystalline melting temperature of the cis 1,4 polybutadiene. Immiscibility of the 91 percent 1,2 addition polymer was also found with a 10 percent 1,2 polybutadiene. The latter polymer also exhibits an UCST with the 71 percent 1,2 polymer. The results are used to interpret the characteristics of blends of polybutadienes of varying microstructure. 相似文献
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以F类粉煤灰为例,详细介绍了测定粉煤灰中烧失量的步骤、计算数学模型、影响测量不确定度的因素以及各项测量不确定度分量评定,人员、设备、材料、方法、环境都是影响测量不确定的因素。 相似文献
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The objective of the study was to explore the effect of the degree of deacetylation (DD) of the chitosan used on the degradation rate and rate constant during ultrasonic degradation. Chitin was extracted from red shrimp process waste. Four different DD chitosans were prepared from chitin by alkali deacetylation. Those chitosans were degraded by ultrasonic radiation to different molecular weights. Changes of the molecular weight were determined by light scattering, and data of molecular weight changes were used to calculate the degradation rate and rate constant. The results were as follows: The molecular weight of chitosans decreased with an increasing ultrasonication time. The curves of the molecular weight versus the ultrasonication time were broken at 1‐h treatment. The degradation rate and rate constant of sonolysis decreased with an increasing ultrasonication time. This may be because the chances of being attacked by the cavitation energy increased with an increasing molecular weight species and may be because smaller molecular weight species have shorter relaxation times and, thus, can alleviate the sonication stress easier. However, the degradation rate and rate constant of sonolysis increased with an increasing DD of the chitosan used. This may be because the flexibilitier molecules of higher DD chitosans are more susceptible to the shear force of elongation flow generated by the cavitation field or due to the bond energy difference of acetamido and β‐1,4‐glucoside linkage or hydrogen bonds. Breakage of the β‐1,4‐glucoside linkage will result in lower molecular weight and an increasing reaction rate and rate constant. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3526–3531, 2003 相似文献
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我厂3号回转窑(Φ4m×60m)生产线在1996年年底由SP窑(产量912t/d)改为NSP窑(产量1320t/d),预分解系统为四级旋风预热器带离线式分解炉 相似文献
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Conclusions It is significant that the purification on a single passage of viscose through porous ceramic corresponds to the result of a two-stage filtration of it in industrial filter-presses with standard fillings.Kiev Combine. Kiev Technological Institute of Light Industry. Translated from Khimicheskie Volokna, No. 3, pp. 20–22, May–June, 1969. 相似文献