无卤阻燃剂的研究进展

介绍了金属化合物阻燃剂、磷系阻燃剂、硅系阻燃剂、硼系阻燃剂的作用机理和应用范围,并对近年来阻燃剂领域的发展动态进行了阐述。     

阻燃剂的现状与未来

本文全面而系统地论述了几类重要阻燃剂(溴系、氟系、有机磷系及膨胀型阻燃剂)的特点、现状及前景,囊括了71种国内外工业生产的阻燃剂的性能,简述了全球的阻燃剂市场,特别是分析了90年阻燃技术发展进程中的若干问题。     

新型无卤阻燃剂的研究进展

综述了无机金属化合物阻燃剂、磷系阻燃剂、硅系阻燃剂及氮系阻燃剂等几类新型的无卤阻燃剂的目前研究发展情况,简要介绍了其有关阻燃机理及将来的发展方向。     

新世纪前10年全球阻燃剂发展预测

本文回顾了１９７０～１９９９年这３０年间全球阻燃剂的发展历程,概述了卤系阻燃剂遇到的严峻挑战和一些新型的阻燃剂的兴起;预测了新世纪前１０年全球阻燃剂的发展趋势,主要是卤系、磷系、氮系、无机阻燃剂及抑烟剂的应用前景。     

磷系阻燃剂发展现状与趋势

简述了我国阻燃剂的市场现状和前景,介绍了磷系阻燃剂的阻燃机理,论述了国内外磷系阻燃剂的分类、特点并介绍了该类阻燃剂的机理及研究现状和发展趋势。     

无卤阻燃剂的研究进展

通过对磷系、氮系、硅系和膨胀型石墨阻燃剂阻燃机理的分析,论述了无卤阻燃剂的发展动向及几种具有发展前途的新型阻燃剂,阐明了无卤、高效、低烟、低毒、环保型阻燃剂的研究是阻燃剂的发展方向.     

阻燃尼龙66的研究进展

介绍了阻燃尼龙(PA)66近几年的研究进展,详细阐述了卤系阻燃剂、磷系阻燃剂、氮系阻燃剂及无机填料型阻燃剂等对PA66的阻燃效果及研究现状,并展望了阻燃PA66未来的发展方向.     

无卤阻燃高冲击强度聚苯乙烯体系研究进展

综述了用合金化及添加蒙脱土、磷系阻燃剂、氮系阻燃剂、碳系阻燃剂、无机金属系阻燃剂等方法制备无卤阻燃高冲击强度聚苯乙烯的研究进展及阻燃机理;展望了无卤阻燃高冲击强度聚苯乙烯的发展方向。     

EVA用阻燃剂阻燃机理及应用研究进展

总结了近年来国内采用无机镁铝阻燃剂、磷系阻燃剂、氮系阻燃剂、硅系阻燃剂、膨胀类阻燃剂对乙烯-醋酸乙烯酯共聚物(EVA)阻燃改性研究进展,对每种类型阻燃剂的优缺点、阻燃机理以及各类阻燃剂对EVA基复合材料性能的影响进行了归纳,并对EVA用阻燃剂研究的发展方向予以展望,期望为研发更为高效的EVA用阻燃剂提供有效参考。     

硅系阻燃剂研究进展

从添加型硅系阻燃剂、含硅本质阻燃高聚物、聚合物／层状硅酸盐纳米复合阻燃材料等方面，阐述了硅系阻燃剂近几年的发展情况；介绍了有机硅系阻燃剂、无机硅系阻燃剂；评述了硅系阻燃剂具有高效、低毒、抑烟和促进成炭等优点；综述了含硅基团共聚物、含硅接枝共聚物及聚合物／层状硅酸盐纳米复合材料的结构和阻燃性能。     

聚丙烯阻燃剂及其发展趋势

介绍了聚丙烯(PP)阻燃剂种类和机理,综述了PP阻燃剂研究进展和发展趋势。高效、低毒、低烟、低成本、多功能、新型复合“绿色”阻燃剂是21世纪PP阻燃剂研究的重点。     

Non-halogen-containing flame-retardant ethylene-propylene copolymer compositions for cable insulation with nitrogen- and sulfur-containing fire retardants

The effects of ammonium salts of sulfaminic acids, containing aliphatic and arylaliphatic hydrocarbon chains, respectively, in a combination with inorganic fire retardants and fillers, on the properties of ethylene-propylene copolymer compositions (EPCC) for cable insulation were studied. The additive action of the organic fire retardants and antimony oxide in a weight ratio of 3:1 was proved. EPCC indicated a limited oxygen index (LOI) of 37–39% and a diminished smoke release and belonged to UL class zero. The thermal destruction of the system consisting of a copolymer blend and fire retardant, as well as the individual organic and inorganic fire retardants, was studied using dynamic thermal analyses (DTA, TG, DTG). The combination of fire retardants caused a decrease of both the heat release and weight loss over the EPCC surface. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 63: 581–588, 1997     

阻燃剂在塑料工业中的应用实例

对四溴双酚A、五溴二苯醚、六溴环十二烷等阻燃剂在聚丙烯、环氧树脂、酚醛树脂、PETP树脂、不饱和聚酯等材料中进行了试探性的应用,并对今后如何加快阻燃剂的发展提出了初步的看法。     

锡酸锌－新型的锡基阻燃剂

本文简要介绍了锡酸锌阻燃剂的发展，合成和性质，同时介绍了它的用途及优于别种阻燃剂的一些特点，并针对省内非阻燃剂研究和后产提出建议。     

Flame retardants and heat release: review of data on individual polymers

This is part of a project considering whether flame retardants affect polymer heat release, a critical issue to assess whether adding flame retardants decreases fire hazard. The work investigated the following. (1) Fire properties affecting fire hazard, confirming that heat release rate is the key fire property most strongly influencing fire hazard. (2) Ways to assess heat release and whether full‐scale fire heat release rate can be predicted from small‐scale test results, confirming that cone calorimeter and Ohio State University data are adequate to predict full‐scale heat release. (3) Analysis of key 1988 NBS/NIST study comparing the fire hazard of flame retarded products versus non‐flame retarded products for the same application. This confirmed that the study demonstrated that flame retardants lower fire hazard and that the levels of additives in the flame retarded products used were not excessive. (4) Review of studies investigating effects of flame retardants on various polymeric systems. The overall conclusion is that flame retardants does indeed improve fire safety (when used appropriately) primarily because they decrease heat release. Part 2 of the project (separately) considers the key polymers that need to be potentially flame retarded and reviews recent studies on effects of flame retardants on heat released by such polymers. Copyright © 2014 John Wiley & Sons, Ltd.     

Fire performance of wood (Pinus radiata) treated with fire retardants and a wood preservative

In this work, we co‐formulated an oil‐borne copper naphthenate/permethrin wood preservative system with synthetic polymer‐based fire‐retardant additives prior to the impregnation of Pinus radiata sapwood. We evaluated what effect, if any, the preservative had upon the fire performance properties of the fire retardants and whether the fire retardants impacted on the fungicidal and termiticidal efficacy of the preservative. The fire retardants included halogenated and phosphorus‐based systems. A mass loss calorimeter, in conjunction with a thermopile, was used to measure the time to ignition and the peak heat release rate (PHRR) from which the fire performance index (FPI) was determined. The preservative properties were evaluated using termite and soil‐block decay bioassays. In summary, we found that the rate of fire growth was reduced when the fire retardants were used in combination with the wood preservative. We also found that the PHRR was a better determinant of fire performance than the FPI. The performance of the wood preservative was enhanced against fungal decay and termite attack when used in combination with the fire retardants. The fire retardants also demonstrated some wood preservative properties of their own. Copyright © 2008 John Wiley & Sons, Ltd.     

溴系阻燃剂与环境

介绍阻燃剂与环境的关系，从全球火灾发生状况入手，阐述了火灾与防火标准制定的关系，以及火灾与阻燃剂使用的关系，并重点论述了聚合型和反应型溴系阻燃剂在防火方面发挥的重要作用和对环境的影响．以及阻燃剂在合成树脂中的应用。     

木材构造对木材化学阻燃浸渍处理方法的影响

从木材构造对化学阻燃浸渍处理工艺影响的角度,指出在木材化学阻燃浸渍处理过程中,影响阻燃剂在木材中渗透性的木材主要微观构造有浸提物、纹孔等,分析了木材中水分的存在状态和木材中水分的移动与木材化学阻燃浸渍处理工艺的关系。探讨了强化木材化学阻燃浸渍处理的方法。采用微波技术提高木材的渗透性,采用超声波技术强化阻燃剂的浸渍。实验表明是一条可行的技术路线。     

无机磷系阻燃剂

无机磷系阻燃剂包括红磷（微胶囊化红磷）、聚磷酸铵、磷酸盐（如磷酸氢二铵、磷酸二氢铵、磷酸铵等）。介绍了红磷、聚磷酸铵、磷酸盐等无机阻燃剂的性质、生产过程、产品标准和用途等。概括了无机磷系阻燃剂生产、性能和阻燃应用研究情况。     

阻燃剂在膨胀型防火涂料中的应用

根据阻燃剂的分类,阐述了各类阻燃剂的阻燃机理。评述了国内外几种阻燃性好的阻燃剂的应用。提出了膨胀型防火涂料中阻燃体系及阻燃剂的选用原则。