水性丙烯酸改性醇酸树脂的研制

采用以豆油酸、三羟甲基丙烷、间苯二甲酸、顺丁烯二酸酐、苯甲酸为原料合成基础醇酸树脂,然后将丙烯酸单体、苯乙烯单体、甲基丙烯酸甲酯与其接枝共聚,再用胺中和后制得水性丙烯酸改性醇酸树脂,该树脂水溶性优异、颜色浅、干率好,耐候性获得极大提高。     

水溶性自干醇酸树脂的合成研究

以六氢苯酐、间苯二甲酸、亚麻酸、水性单体及三羟甲基丙烷为主要原料合成了水溶性自干醇酸树脂，测试了由该树脂配制的自干涂料的性能；讨论了工艺条件对醇酸树脂性质及涂膜性能的影响。     

改性水性醇酸树脂的研究进展

介绍了国内外改性水性醇酸树脂的研究进展,重点介绍了丙烯酸、苯乙烯、聚氨酯、环氧树脂单体改性和多种单体共同改性水性醇酸树脂的研究,包括改性水性醇酸树脂的制备、表征和所得出的结论。并对我国水性醇酸树脂的发展和进一步研究进行了展望。     

水性醇酸树脂的改性研究最新进展

介绍了国内外水性醇酸树脂改性的研究进展和近年的研究热点,重点介绍了以丙烯酸、苯乙烯、聚氨酯等改性水性醇酸树脂,以及用几种单体共同改性水性醇树脂等,还介绍了用无机纳米材料及其他材料对水性醇酸树脂的改性研究,并对我国水性醇酸树脂的发展和进一步研究进行了展望.     

水溶性涂料的发展(一)

水性涂料在环境适应性涂料中占有重要地位,阐述了水性涂料的特点及类型。展示了水性化方法,例如成盐法、引入非离子基团法和形成两性离子中间体法。论述了各种水溶性树脂体系,包括水溶性油、水溶性聚丁二烯加成物、水溶性醇酸树脂、改性水溶性醇酸树脂和水溶性丙烯酸树脂。     

醇酸树脂及其涂料

适于片状模塑料用涂料的水溶性醇酸树脂组合物;改性水性醇酸树脂及其在水性氨基涂料中的应用.     

国内水性醇酸树脂涂料改性的研究进展

介绍了国内水性醇酸树脂涂料方面的改性研究,包括地沟油基改性水性醇酸树脂、废弃聚对苯二甲酸乙二醇酯(PET)瓶降解制备花椒籽油水性醇酸树脂、亚麻油基自干型水性醇酸树脂、顺丁烯二酸酐(MA)改性水性醇酸树脂、环氧树脂改性水性醇酸树脂、羟基丙烯酸树脂改性水溶性醇酸树脂、环氧树脂/丙烯酸改性水性醇酸树脂、水性丙烯酸乳液/水性醇酸树脂杂化涂料、仿贻贝粘附蛋白(PHEA-DOPA)/甲基丙烯酸缩水甘油酯(GMA)改性水性醇酸涂料、有机硅丙烯酸酯聚氨酯改性水性醇酸防腐涂料、纳米二氧化硅/聚苯胺/氧化石墨烯改性水性涂料和异氰酸酯功能化石墨烯/醇酸防腐涂料等。     

水性醇酸树脂合成及改性研究进展

对合成水性醇酸树脂所用的原料（多元醇、多元酸和水性单体等）进行了介绍;讨论了醇酸树脂的水性化的工艺路线和改性方法。     

水性醇酸树脂改性的最新研究进展

简要介绍了水性醇酸树脂的特点,阐述了几种水性醇酸树脂的改性方法,如丙烯酸改性、聚氨酯改性、苯乙烯改性、环氧改性、纳米材料改性、有机硅改性和多种单体复合改性等,提出了水性醇酸树脂存在的问题并对应用前景进行了展望。     

水性醇酸树脂的研究进展

醇酸树脂具有漆膜附着力好、防腐蚀性能强及良好的施工性,被广泛应用于油漆、涂料、粘合剂、船舶等领域。但醇酸树脂大多以有机溶剂为分散介质,对环境和人类健康会不利,因此,醇酸树脂的水性化研究已迫在眉睫。首先,综述了水性醇酸树脂的合成原理及制备方法;其次,探讨了影响水性醇酸树脂性能的因素,例如:脂肪酸和植物油、多元醇、亲水单体、油度、酸值等,同时介绍了水性醇酸树脂的改性研究进展;最后,对水性醇酸树脂的发展趋势进行了展望。     

Effect of different polymers on the efficiency of water‐borne methyl amine adduct as corrosion inhibitor for surface coatings

Styrene/acrylic emulsion copolymer and water‐based short oil urethane alkyd resin were used as binders to prepare water‐based, environmentally friendly paints by using 0.5% emulsified methylamine adduct as corrosion inhibitor. The choice of the two above‐mentioned binders was based on the fact that styrene/acrylic emulsion copolymer is a nonconvertible binder, whereas short oil urethane alkyd resin is a convertible binder. The physical, chemical, mechanical, and corrosion properties of the paint films were evaluated and compared with a commercially known anticorrosive water‐based paint. It was found that the prepared paints have unique desirable properties such as the following: they do not contain anticorrosive pigments (which contain heavy metals in their main chemical structure); they are solvent‐free; and they can be produced to match any color. Corrosion tests on the films of the formulated paints revealed that the short oil urethane alkyd resin is superior to the styrene/acrylic copolymer. Moreover, the corrosion inhibition properties of the paint films prepared from both binders are comparable with the commercially available paints containing anticorrosive pigments. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 879–885, 2002     

Optimized synthesis and properties of surfactant-free water-reducible acrylate-alkyd resin emulsion

In this work, a modified alkyd resin (basic alkyd resin) was synthesized using maleic anhydride (MAH) to replace part of phthalic anhydride (PA) to achieve the target product acrylate-grafted-alkyd hybrid resin. The resin was then dispersed in water to form water-reducible emulsion. The properties were examined, including the extent of neutralization of final emulsion, ratio of MAH/PA in basic alkyd resin, mole ratio of basic alkyd resin to modified vinyl monomers, mole ratio of vinyl monomers (MMA/St/AA) on water dispersion stability of emulsion, particle size, drying time and mechanical properties. The optimal synthesis conditions produced a final emulsion particle size of 81.1 nm with good storage stability, hydrolytic stability and shorter drying time. The optimized synthesis conditions were identified as 80% neutralization, 1:0.8 mole ratio of basic alkyd resin to modified monomers, 4:3:2 modified monomers MMA/St/AA and 0.18 mole ratio of MAH/PA.     

低成本低VOC自干醇酸树脂涂料的研究

利用聚糖树脂在高速搅拌下将水分散到醇酸树脂中形成稳定的油包水乳液,将此油包水乳液添加到自干醇酸涂料中,既可减少醇酸树脂涂料中树脂的用量、降低成本,又可以降低溶剂(VOC)的排放量。     

苯丙乳液改性的研究进展

综述了近年来苯丙乳液改性的研究与应用进展,主要介绍了有机硅、有机氟、环氧树脂、纳米材料、蒙脱土、水溶性醇酸树脂对苯丙乳液的改性研究,指出了改性苯丙乳液的研究前景。     

醇酸改性硝化纤维素水乳液的制备研究

采用醇酸树脂相反转乳化法制备了硝化纤维素乳液。分析了反相乳液聚合过程中电导率的变化规律,研究了乳化剂HLB值、乳化剂用量和乳化温度等因素对乳液临界含水量Rf值及其稳定性的影响。     

Synthesis and performance of alkyd–acrylic hybrid binders

Preparation and properties of alkyd–acrylic hybrids have been studied. Hybrids with different alkyd–acrylic ratios and acrylic parts were prepared via free radical polymerization of acrylic monomers in a presence of an unsaturated alkyd resin using emulsion polymerization technique. The binders were characterized according to their solid content, conversion, viscosity, pH and particle size. Evidence on formation of true copolymer was obtained via NMR spectroscopy and molecular weight and glass transition temperature measurements, as well as via performance studies. The performance evaluation was focused on investigation of drying, penetration and water repellency ability, as well as on film formation and surface topography studies. The binders were compared to references of an alkyd emulsion, acrylic latex and a blend made of them. The results showed that alkyd–acrylic hybrids with synergistic and improved properties can be prepared.     

醇酸树脂再现活力

在醇酸树脂生产中使用可再生资源占60%～70%,近些年来重又受到广泛重视。特别在高固体分、乳液、水分散体和水性杂化醇酸树脂方面的开发取得很大进展,使其获得新的应用前景,再现活力。介绍了制备聚氨酯/醇酸与丙烯酸/醇酸水分散体树脂的基本方法。     

水性苯丙共聚物改性醇酸树脂的制备及性能

以油酸、季戊四醇、邻苯二甲酸酐、苯甲酸为原料，采用丙二醇甲醚醋酸酯（PMA）为溶剂合成了基体醇酸树脂；用过氧化苯甲酰、过氧化苯甲酸叔丁酯双引发剂、分步引发烯类单体共聚，制备了一种苯丙烯树脂，并对醇酸树脂改性制得了水性醇酸树脂。考察了不同油度对水性醇酸树脂结构与性能的影响。通过FTIR、TGA、DLS分别对树脂的结构、稳定性和乳液性能进行了表征。测定了树脂的漆膜性能，包括耐水性、表干时间、硬度、电化学性能。结果表明，n（油酸）∶n（季戊四醇）∶n(邻苯二甲酸酐)∶n（苯甲酸）=1∶1∶1∶0.3，油度为47%时，聚合物乳液粒径为74.4 nm，PDI为0.262，胶膜的吸水率为14.5%，接触角为70.87?，有较好的耐水性。改性醇酸树脂的表干时间缩短为0.5 h，实干时间缩短为24 h，硬度达HB。     

水溶性醇酸氨基烘漆的研制

采用饱和脂肪酸、苯酐、三羟甲基丙烷、新戊二醇和偏苯三酸酐合成水溶性醇酸树脂,与甲醚化三聚氰胺甲醛树脂制备水溶性醇酸氨基烘漆。该水溶性醇酸氨基烘漆的漆膜性能均达到并超过溶剂型醇酸氨基烘漆的漆膜性能。讨论了酸值、羟值、油度、氨基树脂、中和剂、助溶剂和树脂结构等因素对树脂合成及应用性能的影响。水溶性醇酸氨基烘漆与水性醇酸防锈底漆配套使用具有优异的防腐性能。     

水溶性涂料用醇酸树脂的研制

全面探讨制备涂料用水溶性醇酸树脂过程中原料及配比、合成工艺设计、反应条件控制、性能指标控制等诸多因素对树脂性能的影响,结果表明科学优选原料组分、合理控制反应工艺,是制备水溶性醇酸树脂的关键,为研制优质水溶性醇酸涂料奠定了坚实的基础。