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建立了串联组合柱固相萃取-气相色谱-质谱法检测鸡蛋中160种农药多残留的分析方法。鸡蛋样品用乙腈均质和超声波提取,提取液采用C18和PSA串联组合柱净化,气相色谱-质谱仪(GC-MS)分析。GC-MS采用SIM模式,外标法定量。在优化过的条件下进行测试,本法检出限(S/N≥3)为0.01~0.05 mg/kg,在加标水平为0.05 mg/kg时,方法回收率为63.2%~126%,相对标准偏差为2.3%~13%。 相似文献
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目的建立固相萃取-气相色谱法(SPE-GC-ECD)测定塑料食品包装材料中7种短链氯化石蜡(SCCPs)的检测技术。方法利用丙酮和正己烷的混合溶液在50℃下超声萃取塑料食品包装材料中7种SCCPs成分,SCCPs经硅胶固相萃取柱净化,采用气相色谱-电子捕获检测器进行定性与定量测定。结果在0.1~100.0 mg/kg范围内,SCCPs质量浓度与色谱峰面积呈良好的线性关系,线性相关系数均大于0.9997;检出限为0.01~0.10 mg/kg,加标回收率为86.4%~102.7%,相对标准偏差为1.2%~3.7%。结论该方法准确度高、精密度好、检出限低,可为塑料食品包装材料中SCCPs的检测提供新方法。 相似文献
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QuEChERS提取-气相色谱法测定木棉花中有机磷类残留 总被引:1,自引:0,他引:1
建立同时测定木棉花中9种有机磷农药的Qu ECh ERS提取-气相色谱快速检测方法。样品经乙腈溶解,Qu ECh ERS试剂萃取,分散固相萃取净化后,气相色谱-火焰光度检测器检测,在优化条件下,结果显示:9种农药均具有良好的线性关系,相关系数不低于0.995,检出限为0.012~0.316mg/kg,加标回收率为81.6%~103.4%,相对标准偏差为1.6%~4.8%。该方法具有检测结果准确可靠、简便快速等优点。 相似文献
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固相萃取-气相色谱-质谱联用法检测进出口蔬菜产品中百菌清残留 总被引:1,自引:0,他引:1
建立了固相萃取-气相色谱-质谱法检测蔬菜中百菌清残留的分析方法。样品用乙腈-水-磷酸混合液提取,经液液分配、Florisil/Na2SO4柱净化后过滤膜上机。采用选择离子扫描方式,外标法定量。通过优化前处理和上机条件,在最优条件下进行测试,实验结果百菌清的定量检出限为0.001mg/kg,在加标水平0.005~0.1mg/kg范围内,回收率为78.65%~90.67%,相对标准偏差为3.5%~5.8%。该方法简便、快速、净化效果理想,能满足残留分析的要求,可用于进出口蔬菜中百菌清残留的检测。 相似文献
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《现代测量与实验室管理》2015,(6)
建立了同时测定化妆品中6种硝基酚的固相萃取-超高效液相色谱分析方法。样品采用乙腈为提取溶剂,经超声提取后再做高速离心处理;上清液以Oasis HLB固相萃取柱净化,收集甲醇洗脱液,采用色谱分析。液相色谱分析方法:选择全氟苯基色谱柱,以乙腈和乙酸铵及0.1%甲酸作为流动相,梯度洗脱,检测波长为220nm,在优化的固相萃取前处理和液相色谱分离分析条件下,净化效果满足要求。6种硝基酚类化合物在20min内实现完全基线分离,检出限为0.02~0.04mg/L,回收率为86.3%~103.6%,相对标准偏差为3.4%~7.1%。本方法准确、快速、灵敏度高,可用于化妆品的实际检验。 相似文献
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大体积水样专用柱固相萃取-超高效液相色谱串联质谱测定水中5类40种抗生素类药物残留 总被引:1,自引:0,他引:1
目的:建立大体积水样专用柱固相萃取柱富集净化-超高效液相色谱-串联质谱(LC-MS/MS)法,同时测定水体中5类40种抗生素。方法:水样通过大体积水样专用柱萃取富集后,用5%氨化甲醇洗脱,以C18反相色谱柱为分析柱,乙腈-0.1%甲酸溶液为流动相,采用LC-MS/MS进行定性定量分析。选择电喷雾正电离源(ESI+),多反应监测模式(MRM),外标法定量。结果:5类40种抗生素在1~500 ng/L范围内均具有良好的线性关系,方法的检出限(S/N=3,1000倍浓缩)为0.1~10 ng/L。以自来水、闽江水和内河水作为基底,加标质量浓度为40 ng/L和100 ng/L时,抗生素的平均加标回收率分别为68.0%~120.3%和67.9%~117.7%,相对标准偏差(RSD)分别为2.0%~14.9%和1.8%~16.6%。结论:建立的大体积水专用柱固相萃取净化、富集,超高效液相色谱-串联质谱(LC-MS/MS)联用技术,可用于测定同时测定水体中5类40种抗生素。 相似文献
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固相萃取-气相色谱法测定葡萄酒中16种有机磷农药残留 总被引:5,自引:0,他引:5
利用固相萃取(SPE)/气相色谱火焰光度(GC-FPD)技术建立了葡萄酒中16种有机磷农药残留量分析方法。样品加水稀释,过HLB小柱和LC-NH2小柱净化,浓缩、定容后,用气相色谱测定,外标法定量。各农药的方法定量限(LOQ)均为为0.01 mg/kg。添加回收实验,16种有机磷农药添加浓度为0.01-0.10 mg/kg时,添加回收率为65.3-92.3%,变异系数≤10%。 相似文献
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A method is proposed for estimating the parameters of a mixture of exponential and Weibull distributions for which the accuracy of preliminary estimates obtained by graphical analysis is refined in accordance with the criterion of maximum likelihood. The efficiency of the proposed method is supported by the results of statistical modeling. 相似文献
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O'Brien RS 《Radiation protection dosimetry》2003,105(1-4):95-100
Australia has several uranium mines and a large number of mineral sand mines, with associated processing facilities. Exposures resulting from these mining and processing operations usually involve intakes of mixtures of radionuclides. This work describes the development of a suite of first order, linear compartment models, based on the ICRP Publication 66 respiratory tract model, and an analytical solution to the decay equations, for assessing the consequences of such intakes. The computer programs based on these models directly compute excretion, organ retention and organ and whole-body doses for intakes of either single radionuclides or any mixture of radionuclides belonging to the same radioactive decay chain. The intake can be via inhalation, ingestion or injection, and can be acute, chronic or of limited duration. The starting concentration and degree of secular (dis)equilibrium can be specified for each radionuclide. No assumptions need to be made about the relative magnitudes of the radioactive half-lives of the different nuclides. 相似文献
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本文根据多年的实践检定经验 ,参照JJF1 0 59- 1 999《测量不确定度评定与表示》以及《测量不确定度表达 1 0讲》 ,对卧式金属罐容量的测量结果不确定度进行了评定。 相似文献
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Liebert A Wabnitz H Grosenick D Möller M Macdonald R Rinneberg H 《Applied optics》2003,42(28):5785-5792
A novel method for the determination of the optical properties of tissue from time-domain measurements is presented. The data analysis is based on the evaluation of the first moment and the second centralized moment, i.e., the mean time of flight and the variance of the measured distribution of times of flight (DTOF) of photons injected by short (picosecond) laser pulses. Analytical expressions are derived for calculation of absorption and of reduced scattering coefficients from these moments by application of diffusion theory for infinite and semi-infinite homogeneous media. The proposed method was tested on experimental data obtained with phantoms, and results for absorption and reduced scattering coefficients obtained by the proposed method are compared with those obtained by fitting of the same data with analytical solutions of the diffusion equation. Furthermore, the accuracy of the moment analysis was investigated for a range of integration limits of the DTOF. The moment analysis may serve as a comparatively fast method for evaluating optical properties with sufficient accuracy and can be used, e.g., for on-line monitoring of optical properties of biological tissue. 相似文献
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V. T. Bublik A. I. Voronin E. A. Vygovskaya V. F. Ponomarev N. Yu. Tabachkova O. V. Toropova 《Inorganic Materials》2011,47(14):1563-1568
An analysis of anisotropy of the properties of a Bi2Se0.3Te2.7 solid solution was carried out using construction of demonstrative surfaces for thermoelectric effectiveness and thermal
expansion coefficients. It is shown that the texture is an important factor forming anisotropy of properties and technological
fitness of ingots for manufacturing modules. Anisotropy of properties based on the studies of the ingot textures obtained
using the float-zone method and Bridgman method (growing thermoelectric plates in a flat cavity) was studied. 相似文献
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