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CuO—SnO2纳米晶粉料的Sol—Gel制备及表征 总被引:23,自引:2,他引:21
不用金属醇盐而以无起始物质,采用Sol-Gek法得到了平均晶粒尺寸为21-22nmCuO掺杂的SnO2粉料;运用X射线衍射(XRD),差热-失重分析(DTA-TG),透射电镜(TEM)及BET比表面(SA)测定等分析手段对粉料进行了表征,实验表明,CuO的掺杂抑制了SnO2晶粒的生长,以无机盐为原料,采用Sol-Gel法制取SnO2(CuO)纳米级晶料是切实可行的,将有利于产业化。 相似文献
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NiMn2O4纳米粉体的制备 总被引:4,自引:0,他引:4
用溶胶-凝胶法(sol-gel)合成NiMn2O4纳米级粉体,利用差热分析(DTA),热失重(TG),X射线衍射(XRD),透射电子显微镜(TEM)等广阔博征合成过程及纳米粉体的结构,研究结果表明,NiMn2O4纳米粉体相合成温度比传统固相反应方法合成温度低大约300℃,粉体的形状呈多面体形。 相似文献
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流态化CVD制备TiO2—Al2O3复合粒子 总被引:6,自引:0,他引:6
本文探讨了流态化CVD反应器中Ti(OC4H9)4水解制备TiO2-Al2O3复合粒子新工艺,借助于SEM、TEM、BET、XRF和EPMA等现代测试手段研究了复合粒子结构和包覆过程特征。结果表明,在流态化CVD反应器中Al2O3超细颗粒以团聚体形式存在,TiO2包覆量随Ti(OC4H9)4进料浓度升高而增加,但反应温度影响不大;在包覆过程中,同时存在成核和成膜,成核包覆使复合粒子比表面积增加,成 相似文献
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脉冲准分子激光CuO—SnO2薄膜沉积及其结构分析 总被引:4,自引:1,他引:3
采用脉冲准分子激光沉积(PLD)技术,分别在Si(111)单晶及玻璃基片上外延沉积了具有高α轴(200)取向的CuO掺杂的SnO2薄膜,X射线衍射(XRD)及透射电镜(TEM扫描附件)分析表明:在Si(111)片上沉400-500℃退火温度处理的薄膜,只有(200)峰存在;当退火温度升高一600-700℃时,SnO2的其余诸峰相应出现。薄膜呈多晶态,取向度降低,晶粒尺寸变大,晶粒分界明显,在玻璃基 相似文献
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Y2O3纳米晶的制备和表征 总被引:12,自引:0,他引:12
采用硬脂酸凝胶法制备了Y2O3纳米晶,用傅立叶交换红外光谱(FTIR),热重-差热(TG-DTA)对制备过程进行了表征。用X射线末衍射(XRD),透射电子显策镜(TEM)及BET比表面吸附对Y2O3纳米晶的粒径和形貌进行一表征。在600℃以上热处理得到立方晶系Y2O3纳米晶,其粒径随热自理的上升而增大,形貌由球形变为立方形。粒径分布窄,无硬团聚现象产生,用傅立叶变换红外光谱(FTIR)对其谱学特性 相似文献
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Li Y Zhang S Sritharan T Li X Liu Y Chen TP 《Journal of nanoscience and nanotechnology》2008,8(5):2618-2622
SrBi2Ta2O9 (SBT) is a bismuth layered perovskite with attractive ferroelectric properties for random access memory applications. Our previous studies showed that Nd-doped SBT (SNBT) thin films exhibited an improved remnant polarization and reduced coercivity. This paper concentrates on the effect of Ta nanobarrier in between the SNBT and the Pt layers. Without the nanobarrier, severe bismuth diffusion is revealed by the secondary ion mass spectroscopy. However, with a nano layer (up to 2 nm) of Ta metal, the interfacial diffusion is effectively suppressed even at 800 degrees C. Details of the composition profiling, film crystallinity and remnant polarization are discussed in view of the nanobarrier thickness. 相似文献
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Electrical properties of Li2O-La2O3-SiO2 electrode glasses after Ta2O5 doping and Ta implantation 总被引:1,自引:0,他引:1
Electrical conductivities, , of the Li2O-La2O3-SiO2 glasses were investigated as functions of Ta2O5 doping and Ta ion-implantation. A linear relationship between logarithm and the inverse of the sample temperature, T, was found in 2 to 4 mol% Ta2O5 doped Li2O-La2O3-SiO2 glasses. The conductivity increases as Ta2O5 content increases at sample temperatures above 100°C. Fluences of 50 keV Ta ions per cm2 from 5 × 1016 to 2 × 1017 were implanted into 0% and 2% Ta2O5 containing Li2O-La2O3-SiO2 glass samples. The activation energy of the conductivity was deduced from the relation between log and 1/T. It was found in implanted samples that the conductivity increased, but the activation energy and T
k–100 decreased, where T
k–100 is the sample temperature when the conductivity reaches 100 × 10–1 S/cm. However, the Ta2O5 containing implanted samples show higher conductivities, lower activation energies and lower T
k–100. X-ray photoelectron spectroscopy (XPS) was used to study the structural modification introduced by implantation. Bridging oxygen (BO) and non-bridging oxygen (NBO), were observed in all samples. The changes in relative concentrations of BO and NBO before and after implantation clearly indicate the structure modification which results in the increase of the conductivity. It was clearly demonstrated in this study that both doping Ta2O5 and implanting Ta ions enhance the conductivity of Li2O-La2O3-SiO2 electrode glasses. 相似文献
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Y. Wakisaka T. Sudayama K. Takubo T. Mizokawa N. L. Saini M. Arita H. Namatame M. Taniguchi N. Katayama M. Nohara H. Takagi 《Journal of Superconductivity and Novel Magnetism》2012,25(5):1231-1234
We report temperature-dependent angle-resolved photoemission spectroscopy measurement of Ta2NiSe5 which shows a semiconductor-semiconductor structural phase transition at around 330?K. Characteristically, flat band at the top of the valence band is observed, which is ascribed to the excitonic insulator effect. The top valence band shifts to higher binding energy and its bandwidth increases as the temperature decreases. As the system exceeds the transition temperature, the flat feature of the valence band weakens though the exciton fluctuations remain finite. 相似文献
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Kazumi Kato 《Journal of Materials Science: Materials in Electronics》2000,11(8):575-578
Sr2Ta2O7 and Sr2(Ta, Nb)2O7 thin films were prepared from molecular structure-controled alkoxide solutions. The Sr2Ta2O7 thin films initiated to crystallize at around 650 °C and showed random orientation. The surface topography developed was dependent on the solutions. In the thin films prepared from the ethanolic solution, grains formed at low temperatures. However, many small pores still remained and no grains were observed in the thin films prepared from the methoxyethanolic solution. In contrast, the 800 °C-annealed Sr2(Ta, Nb)2O7 thin films showed the (0 k 0) orientation as in Sr2Nb2O7 thin films. The dielectric constants and loss factors of the 750 °C-annealed Sr2Ta2O7 and Sr2(Ta0.7Nb0.3)2O7 thin films were around 90 and less than 0.05 at 100 kHz, respectively. 相似文献
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The scintillation of anodic tantalum oxide was investigated by counting the number of breakdown events during anodization at a constant current density. A theory is developed which qualitatively explains the variation in the number of breakdown pulses with time and voltage for different current densities and different electrolyte resistivities. The theory also allows definition of a limiting anodization voltage which increases with the logarithm of the current density. Several experiments are presented which are in agreement with the theory. 相似文献
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Takashi Ogihara Tadashi Ikemoto Nobuyasu Mizutani Masanori Kato Yukuaki Mitarai 《Journal of Materials Science》1986,21(8):2771-2774
The Ta2O5 powders synthesized by the hydrolysis of tantalum pentaethoxide, Ta(OC2H5)5 in alcoholic solution were monodispersed fine oxide particles, which were a uniform, spherical shape, non-agglomerate, and had a narrow size distribution. They grew to 1.2m after ageing for 1 h after hydrolysis. Powder X-ray diffraction and differential thermal analysisthermogravimetric analysis showed the particles were amorphous and hydrated. These particles lost the water at 290° C and gave well-crystalline Ta2O at 740° C. Throughout these thermal processes, the particle morphology was kept almost the same. 相似文献
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采用基于密度泛函理论的第一性原理平面波超软赝势法,对Ta掺杂锐钛矿相TiO2的电子结构和光学吸收性质进行计算。结果表明,TiO2中掺杂Ta后,杂质能级与导带底混合,禁带宽度明显减小;杂质能级的引入和禁带宽度的减小使得Ta掺杂锐钛矿相TiO2光吸收在可见光范围内出现明显吸收增强。 相似文献