Pool boiling heat transfer from a horizontal tube coated with oxide ceramics

Pool boiling heat transfer from a horizontal copper tube coated with 0.2 mm of aluminum oxide-titanium oxide ceramics has been investigated for several pure fluids (refrigerants and hydrocarbons) and three propane/n-butane mixtures. The heat transfer coefficient shows a similar dependence on heat flux and normalized saturation pressure as with a metallic heating tube. At normalized saturation pressures p/p_c0.1, the absolute values of the heat transfer coefficient are just as high as for a sandblasted copper tube of similar surface roughness and at lower saturation pressures even higher. The negative influence of the low thermal conductivity of the ceramics is completely compensated or even overcompensated by the positive influence of the microstructure which results in a higher nucleation site density. This is especially effective in pool boiling of mixtures.     

Influence of the heat flux in mixture boiling: experiments and correlations

Heat transfer at nucleate pool boiling of the binary and ternary refrigerant mixtures R404A, R407C and R507 at the outside of a horizontal tube with emery ground surface has been investigated in a wide range of pressures and heat fluxes. Together with experimental data of Bednar and Bier for wide boiling ethane/n-butane mixtures, the results of these comparatively narrow boiling mixtures are used to investigate the influence of heat flux q on the heat transfer coefficient as predicted by various correlations for nucleate boiling of mixtures. At comparatively high saturation pressures with experimental -values markedly smaller than the molar average of the pure components, the ,q-relationships predicted differ significantly from the experimental, particularly for wide boiling mixtures.     

Effect of bulk lubricant concentration on the excess surface density during R134a pool boiling

This paper investigates the effect that the bulk lubricant concentration has on the non-adiabatic lubricant excess surface density on a roughened, horizontal flat pool-boiling surface. Both pool boiling heat transfer data and lubricant excess surface density data are given for pure R134a and three different mixtures of R134a and a polyolester lubricant (POE). A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of an R134a/POE lubricant mixture on a test surface. The lubricant is preferentially drawn out of the bulk refrigerant/lubricant mixture by the boiling process and accumulates on the surface in excess of the bulk concentration. The excess lubricant resides in an approximately 40 μm layer on the surface and influences the boiling performance. The lubricant excess surface density measurements were used to modify an existing dimensionless excess surface density parameter so that it is valid for different reduced pressures. The dimensionless parameter is a key component for a refrigerant/lubricant pool-boiling model given in the literature. In support of improving the boiling model, both the excess measurements and heat transfer data are provided for pure R134a and three R134a/lubricant mixtures at 277.6 K. The heat transfer data show that the lubricant excess layer causes an average enhancement of the heat flux of approximately 24% for the 0.5% lubricant mass fraction mixture relative to pure R134a heat fluxes between 5 and 20 kW/m². Conversely, both 1 and 2% lubricant mass fraction mixtures experienced an average degradation of approximately 60% in the heat flux relative to pure R134a heat fluxes between approximately 4 and 20 kW/m². This study is an effort toward generating data to support a boiling model to predict whether lubricants degrade or improve boiling performance.     

The effect of lubricant concentration, miscibility, and viscosity on R134a pool boiling

This paper presents pool boiling heat transfer data for 12 different R134a/lubricant mixtures and pure R134a on a Turbo-BII™-HP surface. The mixtures were designed to examine the effects of lubricant mass fraction, viscosity, and miscibility on the heat transfer performance of R134a. The magnitude of the effect of each parameter on the heat transfer was quantified with a regression analysis. The mechanistic cause of each effect was given based on new theoretical interpretation and/or one from the literature. The model illustrates that large improvements over pure R134a heat transfer can be obtained for R134a/lubricant mixtures with small lubricant mass fraction, high lubricant viscosity, and a large critical solution temperature (CST). The ratio of the heat flux of the R134a/lubricant mixture to that of the pure R134a for fixed wall superheat was given as a function of pure R134a heat flux for all 12 mixtures. The lubricant that had the largest CST with R134a exhibited the greatest heat transfer: 100%±20% greater than that of pure R134a. By contrast, the heat transfer of the mixture with the lubricant that had the smallest viscosity and the smallest CST with R134a was 55%±9% less than that of pure R134a. High-speed films of the pure and mixture pool boiling were taken to observe the effect of the lubricant on the nucleate boiling.     

R134a单元式风冷冷风空调机蒸发器设计

以理论模型为基础，对R134a单元式风冷冷风机组翅片管式蒸发器进行设计。应用管内流动沸腾换热模型仿真分析R134a的质量流量对沸腾换热的影响，利用外掠翅片管束换热关联式计算管外翅片侧表面换热系数，进而得出翅片管蒸发器总传热系数，利用计算结果进行设计。     

The influence of a low viscosity oil on the pool boiling heat transfer of the refrigerant R507Influence d'une huile à faible viscosité sur le transfert de chaleur lors de l'ébullition libre du frigorigène R507

This paper describes the influence of a low viscosity polyolester based lubricating oil on the pool boiling heat transfer of the refrigerant R507. The pool boiling heat transfer coefficients for this refrigerant–oil mixture are measured on a smooth tube and on an enhanced tube. The investigation is made for oil mass fractions up to 10% and for saturation temperatures between −28.6°C and +20.1°C. For the smooth tube the heat transfer increases for increasing oil mass fractions up to 3% at lower saturation temperatures. At higher saturation temperatures the heat transfer decreases for increasing oil mass fractions for both tubes. For oil mass fractions greater than 1% at the higher saturation temperatures a range of decreasing heat transfer coefficient is found for increasing heat flux. The effect is caused by the different miscibility of the oil and the components of the refrigerant mixture.     

Effect of refrigerant oil additive on R134a and R123 boiling heat transfer performance

This paper investigates the effect that an additive had on the boiling performance of an R134a/polyolester lubricant (POE) mixture and an R123/naphthenic mineral oil mixture on a roughened, horizontal flat surface. Both pool boiling heat transfer data and lubricant excess surface density data are given for the R134a/POE (98% mass fraction/2% mass fraction) mixture before and after use of the additive. A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of the R134a/POE lubricant mixture before and after use of the additive. The measurements obtained from the spectrofluorometer suggest that the additive increases the total mass of lubricant on the boiling surface. The heat transfer data show that the additive caused an average and a maximum enhancement of the R134a/POE heat flux between 5 kW m⁻² and 22 kW m⁻² of approximately 73% and 95%, respectively. Conversely, for nearly the same heat flux range, the additive caused essentially no change in the pool boiling heat flux of an R123/mineral oil mixture. The lubricant excess surface density and interfacial surface tension measurements of this study were used to form the basis of a hypothesis for predicting when additives will enhance or degrade refrigerant/lubricant pool boiling.     

R134a臣卧式螺旋管内流动沸腾换热特性实验研究

对R134a在水平直管和螺旋管内的沸腾换热特性进行了实验研究.在三个不同的蒸发温度(5℃、10℃和20℃),工质R134a的质量流量范围为100～400kg/(m~2·s)和干度范围为0.1～0.8的条件下,实验得到了R134a在水平直管和螺旋管内的沸腾换热系数随其质量流量和干度的变化关系,将水平直管和螺旋管内的沸腾换热特性数据进行了比较,结果显示,在实验条件下,卧式螺旋管的传热系数比直管的平均增加13.7%.     

Enhancement of R123 pool boiling by the addition of hydrocarbonsAmélioration de l'ébullition libre du R123 par l'ajout d'hydrocarbures

This paper presents pool boiling heat transfer data for 10 different R123/hydrocarbon mixtures. The data consisted of pool boiling performance of a GEWA-T^™ surface for pure R123 and for 10 dilute solutions of five different hydrocarbons: (1) pentane, (2) isopentane, (3) hexane, (4) cyclohexane, and (5) heptane with R123. The heat flux and the wall superheat were measured for each fluid at 277.6 K. A maximum (19±3.5)% increase over the pure R123 heat flux was achieved with the addition of 0.5% mass isopentane to R123. Other mixtures of isopentane, pentane, hexane, and cyclohexane with R123 exhibited smaller maximums than that of the R123/isopentane (99.5/0.5) mixture. Presumably, a layer enriched in hydrocarbon at the heat transfer surface caused the heat transfer enhancement. Conversely, an R123/heptane (99.5/0.5) mixture and an R123/cylcohexane (99.5/0.5) mixture exhibited only degradations with respect to the pure component performance for all test conditions. Several characteristics of the hydrocarbons were examined to determine their influence on the boiling heat transfer performance: molecular weight, molecular structure, composition, surface tension, and vapor pressure.     

Experimental measurements for condensation of downward-flowing R123/R134a in a staggered bundle of horizontal low-finned tubes with four fin geometriesMesures expérimentales de la condensation lors de l'éoulement vertical d'un mélange de R123 et de R134a sur un faisceau de tubes en quinconce munis de quatre types d'ailettes

Experiments were conducted to obtain row-by-row heat and mass transfer data during condensation of downward-flowing zeotropic mixture R123/R134a in a staggered bundle of horizontal low-finned tubes. The vapor temperature and the mass fraction of R134a at the tube bundle inlet were about 50°C and 14%, respectively. The refrigerant mass velocity ranged from 9 to 34 kg m⁻² s⁻¹, and the condensation temperature difference from 1.9 to 12 K. Four kinds of low-finned tubes with different fin geometry were tested. The highest heat transfer coefficient was obtained with a tube which showed the highest performance for R123. However, the diference among the tubes was much smaller for the mixture than for R123. The heat transfer coefficient and the vapor-phase mass transfer coefficient decreased significantly with decreasing mass velocity. The mass transfer coefficient increased with condensation temperature difference, which was due to the effect of suction associated with condensation. On the basis of the analogy between heat and mass transfer, a dimensionless correlation of the mass transfer coefficient was developed for each tube.     

Effect of bulk lubricant concentration on the excess surface density during R123 pool boiling

This paper investigates the effect that bulk lubricant concentration has on the non-adiabatic lubricant excess surface density on a roughened, horizontal flat (plain) pool-boiling surface. Both pool boiling heat transfer data and lubricant excess surface density data are given for pure R123 and three different mixtures of R123 and a naphthenic mineral oil. A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of a R123/lubricant mixture on a test surface. The fluorescent technique was used to measure the effect of bulk lubricant concentration on the lubricant excess layer during refrigerant/lubricant mixture boiling. The refrigerant preferentially boils, thus, concentrating and accumulating the lubricant on the surface in excess of the bulk concentration. The excess lubricant resides in a very thin layer on the surface and influences the boiling performance. Accordingly, the ability to measure the effect of bulk lubricant composition on the lubricant excess density and in turn the effect on the heat transfer would lead to a fundamental understanding of the mechanism by which lubricants can degrade or improve boiling performance. In support of this effort, heat transfer data are provided for pure R123 and three R123/lubricant mixtures at 277.6 K. For heat fluxes between approximately 25 to 45 kW/m², an average enhancement of the heat flux of 9 and 5% was achieved for the 0.5 and 1% lubricant mass fractions, respectively, and an average degradation of 5% in the heat flux was obtained for the 1.8% lubricant mass fraction mixture.

Résumé

This paper investigates the effect that bulk lubricant concentration has on the non-adiabatic lubricant excess surface density on a roughened, horizontal flat (plain) pool-boiling surface. Both pool boiling heat transfer data and lubricant excess surface density data are given for pure R123 and three different mixtures of R123 and a naphthenic mineral oil. A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of a R123/lubricant mixture on a test surface. The fluorescent technique was used to measure the effect of bulk lubricant concentration on the lubricant excess layer during refrigerant/lubricant mixture boiling. The refrigerant preferentially boils, thus, concentrating and accumulating the lubricant on the surface in excess of the bulk concentration. The excess lubricant resides in a very thin layer on the surface and influences the boiling performance. Accordingly, the ability to measure the effect of bulk lubricant composition on the lubricant excess density and in turn the effect on the heat transfer would lead to a fundamental understanding of the mechanism by which lubricants can degrade or improve boiling performance. In support of this effort, heat transfer data are provided for pure R123 and three R123/lubricant mixtures at 277.6 K. For heat fluxes between approximately 25 kW/m² to 45 kW/m², an average enhancement of the heat flux of 9% and 5% was achieved for the 0.5% and 1% lubricant mass fractions, respectively, and an average degradation of 5% in the heat flux was obtained for the 1.8% lubricant mass fraction mixture.     

R290在水平微细圆管内沸腾换热特性研究

本文研究了R290在内径为1 mm、2 mm和4 mm水平微细圆管内的沸腾流动换热特性,在饱和温度为15℃条件下,质量流速为50～600 kg/(m~2·s)、干度为0～1、热流密度为5～20 k W/m~2时,对沸腾传热系数的影响进行了分析。通过实验发现,增大质量流速对传热系数具有增强作用,质量流速对传热系数的影响在低干度区域比高干度区域小。在热流密度方面,传热系数随着热流密度的增大而增大,且在1 mm和2 mm管内观察到了临界干度对传热系数的影响,这时传热系数有断崖式下降的趋势。在管径对于传热系数的影响方面,通过对不同管径换热特性的横向对比,发现在一定工况下传热系数随着管径的减小有所上升。此外本文还对R290已有的部分关联式进行了适配性验证。     

Review on pool boiling heat transfer of carbon dioxide

Although application of carbon dioxide as working fluid in many fields of refrigeration technology has been recommended very often in the recent past, the data on nucleate boiling heat transfer of carbon dioxide in free convection are very scarce in the open literature and new investigations are almost entirely focussed on forced convective flow boiling. In the interpretation of the respective results, heat transfer to carbon dioxide is often characterized as being superior to other refrigerants due to the outstandingly favourable thermophysical properties of carbon dioxide for boiling heat transfer. Different from this view, the discussion of recent results on pool boiling heat transfer of carbon dioxide in this review demonstrates that the high heat transfer coefficients measured for carbon dioxide in comparison to hydrocarbon or halocarbon refrigerants are mainly due to the fact that application of carbon dioxide is mostly envisaged for conditions where reduced saturation pressure p*=p_s/p_c (p_c, critical pressure) is higher than for common refrigerants.

In the first part of the review, the three main influences—by heat flux, saturation pressure and fluid properties—on pool boiling of carbon dioxide are discussed using recent measurements for CO₂ by Kotthoff et al. [S. Kotthoff, U. Chandra, D. Gorenflo, A. Luke, New measurements of pool boiling heat transfer for carbon dioxide in a wide temperature range, Proceedings of the Sixth IIR-Gustav Lorentzen Conference, Glasgow, 2004 [paper 2/A/3.30]; see also S. Kotthoff, U. Chandra, D. Gorenflo, Neue Messungen zum Behältersieden von Kohlendioxid in einem grösseren Temperaturbereich, DKV-Tagungsbericht 22 (2004) [Bd.II. 1] 233–256 and other organic substances (Gorenflo et al.) [D. Gorenflo, S. Kotthoff, U. Chandra, New measurements of pool boiling heat transfer with hydrocarbons and other organics for update of VDI—Heat Atlas calculation method, Proceedings of the Sixth IIR-Gustav Lorentzen Conference, Glasgow, 2004 [paper 1/C/1.00]; Kotthoff and Gorenflo, [S. Kotthoff, D. Gorenflo, Influence of the fluid on pool boiling heat transfer of refrigerants and other organic substances, Proceedings of the IIR-Commission B1 Conference, Vicenza, 2005 [paper #TP-98]. In the second part, a comparison is given with the few former data available and with new results of Loebl and Kraus [S. Loebl, W.E. Kraus, Pool boiling heat transfer of carbon dioxide on a horizontal tube, Proceedings of the Sixth IIR-Gustav Lorentzen Conference, Glasgow, 2004 [paper 1/A/1.20]; S. Loebl, W.E. Kraus, Zum Wärmeübergang bei der Verdampfung von Kohlendioxid am horizontalen Rohr, DKV-Tagungsbericht 22 (2004) [Bd.II.1] 219–232 on the influence of the heating wall (material and surface roughness). Finally, analogies between nucleate pool boiling and new flow boiling data are shown for those domains of flow boiling in which nucleation provides the dominant contribution to heat transfer and convective effects are of secondary importance.     

Refrigerant R134a vaporisation heat transfer and pressure drop inside a small brazed plate heat exchanger

This paper presents the experimental heat transfer coefficients and pressure drop measured during refrigerant R134a vaporisation inside a small brazed plate heat exchanger (BPHE): the effects of heat flux, refrigerant mass flux, saturation temperature and outlet conditions are investigated. The BPHE tested consists of 10 plates, 72 mm in width and 310 mm in length, which present a macro-scale herringbone corrugation with an inclination angle of 65° and corrugation amplitude of 2 mm.The experimental results are reported in terms of refrigerant side heat transfer coefficients and frictional pressure drop. The heat transfer coefficients show great sensitivity both to heat flux and outlet conditions and weak sensitivity to saturation temperature. The frictional pressure drop shows a linear dependence on the kinetic energy per unit volume of the refrigerant flow.The experimental heat transfer coefficients are also compared with two well-known correlations for nucleate pool boiling and a correlation for frictional pressure drop is proposed.     

Evaporation of R407C and R410A in a horizontal herringbone microfin tube: heat transfer and pressure drop

Based on experimental data for R134a, the present work deals with the development of a prediction method for heat transfer in herringbone microfin tubes. As is shown in earlier works, heat transfer coefficients for the investigated herringbone microfin tube tend to peak at lower vapour qualities than in helical microfin tubes. Correlations developed for other tube types fail to describe this behaviour. A hypothesis that the position of the peak is related to the point where the average film thickness becomes smaller than the fin height is tested and found to be consistent with observed behaviour. The proposed method accounts for this hypothesis and incorporates the well-known Steiner and Taborek correlation for the calculation of flow boiling heat transfer coefficients. The correlation is modified by introducing a surface enhancement factor and adjusting the two-phase multiplier. Experimental data for R134a are predicted with an average residual of 1.5% and a standard deviation of 21%. Tested against experimental data for mixtures R410A and R407C, the proposed method overpredicts experimental data by around 60%. An alternative adjustment of the two-phase multiplier, in order to better predict mixture data, is discussed.     

In-tube condensation of mixture of R134a and ester oil: empirical correlations

This paper presents a comparative study of the condensation heat transfer coefficients in a smooth tube when operating with pure refrigerant R134a and its mixture with lubricant Castrol “icematic sw”. The lubricant is synthetic polyol ester based oil commonly used in lubricating the compressors. Two concentrations of R134a-oil mixtures of 2% and 5% oil (by mass) were analysed for a range of saturation temperatures of refrigerant R134a between 35 °C and 45 °C. The mass flow rate of the refrigerant and the mixtures was carefully maintained at 1 g/s, with a vapour quality varying between 1.0 and 0. The effects of vapour quality, flow rate, saturation temperature and temperature difference between saturation and tube wall on the heat transfer coefficient are investigated by analysing the experimental data. The experimental results were then compared with predictions from earlier models [Int J Heat Mass Transfer (1979), 185; 6th Int Heat Transfer Congress 3 (1974) 309; Int J Refrig 18 (1995) 524; Trans ASME 120 (1998) 193]. Finally two new empirical models were developed to predict the two-phase condensation heat transfer coefficient for pure refrigerant R134a and a mixture of refrigerant R134a with Castrol “icematic sw”.     

R404A和R410A应用于平行流冷凝器的模拟分析比较

采用分布参数法对平行流冷凝器建立数学模型，对目前广泛使用的制冷剂R134a和低温制冷剂R404A和R410A在平行流冷凝器中的换热和流动性能进行模拟计算和分析比较。分别在相同和不同工况下。比较3种制冷剂的换热系数及压降等换热和流动性能参数。结果表明，在采用平行流冷凝器的汽车空调工况范围内，R410AR404A的流动和传热性能均优于R134a，更适宜用于汽车空调用平行流冷凝器。     

Experimental correlation of pool boiling heat transfer for HFC134a on enhanced tubes: Turbo-E

The objectives of this paper are to study the heat transfer characteristics for enhanced surface tubes in the pool boiling and to provide a guideline for the design conditions for the evaporator using HFC134a. The shape of tube surfaces, the wall superheat, and the saturation temperature are considered as the key parameters. Copper tubes (d_o = 19.05 mm) are treated with different helix angles and the saturation temperatures are controlled from 3 to 16 °C. It is found that the pool boiling heat transfer coefficient decreases with increasing the wall superheat. It is also found that boiling heat transfer coefficients for Turbo-II and Turbo-III are 1.5–3.0 times and 1.2–2.0 times higher than that for Turbo-I without the helix angle, respectively. The higher heat transfer performance from Turbo-II and Turbo-III can be explained by the “bubble detention” phenomenon on the surface without the helix angle for the Turbo-I. The experimental correlations for the pool boiling heat transfer on the present enhanced tubes without (Type I) and with the helix angle (Type II and Type III) are developed with the error bands of ±30%, respectively.     

Experimental and theoretical study on flow condensation with non-azeotropic refrigerant mixtures of R32/R134a

Experiments on flow condensation have been conducted with both pure R32, R134a and their mixtures inside a tube (10 m long, 6 mm ID), with a mass flux of 131–369 kg m⁻²s⁻¹ and average condensation temperature of 23–40°C. The experimental heat transfer coefficients are compared with those predicted from correlations. The maximum mean heat transfer coefficient reduction (from a linear interpolation of the single component values) occurs at a concentration of roughly 30% R32 for the same mass flux basis, and is approximately 20% at Gr = 190 kg m⁻²s⁻¹, 16% at Gr = 300 kg m⁻²s⁻¹. Non-ideal properties of the mixture have a certain, but relatively small, influence on the degradation. Among others, temperature and concentration gradients, slip, etc. are also causes of heat transfer degradation.     

Prediction of evaporation heat transfer coefficient and pressure drop of refrigerant mixtures

A study on the prediction of heat transfer coefficient (HTC) and pressure drop of refrigerant mixtures is reported. HTCs and pressure drops of prospective mixtures to replace R12 and R22 are predicted on the same cooling capacity basis. Results indicate that nucleate boiling is suppressed at qualities greater than 20.0% for all mixtures and evaporation becomes the main heat transfer mechanism. For the same capacity, some mixtures containing R32 and R152a show 8.0–10.0% increase in HTCs. Some mixtures with large volatility difference exhibit as much as 55.0% reduction compared with R12 and R22, caused by mass transfer resistance and property degradation due to mixing (32.0%) and reduced mass flow rates (23.0%). Other mixtures with moderate volatility difference exhibit 20.0–30.0% degradation due mainly to reduced mass flow rates. The overall impact of heat transfer degradation, however, is insignificant if major heat transfer resistance exists in the heat transfer fluid side (air system). If the resistance in the heat transfer fluid side is of the same order of magnitude as that on the refrigerant side (water system), considerable reduction in overall HTC of up to 20% is expected. A study of the effect of uncertainties in transport properties on heat transfer shows that transport properties of liquid affect heat transfer more than other properties. Uncertainty of 10.0% in transport properties causes a change of less than 6% in heat transfer prediction.