共查询到19条相似文献,搜索用时 312 毫秒
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SiC/Fe-Cr合金界面反应的研究 总被引:3,自引:0,他引:3
使用XRD、EMPA和 SEM等对 900~1150℃高温处理后的SiC/Fe-20Cr合金界面反应区的显微结构和反应动力学进行了研究.界面反应区分为SiC反应区和金属反应区两部分:SiC反应区由组成为Fe3Si、Cr3Si和Cr7C3的白亮基体和其间随机分布的细小石墨颗粒构成;金后反应区则是一个由(Cr;Fe)7C3构成的均匀组织。SiC/Fe-20Cr合金界面反应为扩散控制,反应动力学方程为 K=1.9×10-4exp((-235×103)/RT)m2·s-1.金属反应区介于SiC反应区和合金之间,阻挡合金中的Fe原子通过它向SiC反应区中扩散,抑制界面反应,这种作用随合金中Cr含量的增加而加强. 相似文献
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LiNiO2热分解反应动力学研究 总被引:1,自引:0,他引:1
用DTA和XRD研究了LiNiO2在空气中的热分解过程为:LiNiO2(s)→(650~720℃)Li2Ni8O10(s)+4Li2O(s)+O2(g)→(850~950℃)Li2O(s)+8NiO(s)+1/2O2(g) →(1000~1150℃)NiO(s)+Li2O(g)用 Doyle-Ozawa法和 Kissinger法计算了各反应阶段的表观活化能分别为 747.18±1.0 kJ·mol-1、932.46±1.0 kJ·mol-1和 1126.97±1.0 kJ·mol-1.用 Kissinger法确定了反应级数和频率因子,确定了三个阶段的动力学方程分别为 dα/dt=1.736x1039e-90000/T(1-α)1.057; dα/dt=1806×1039e-111500/T(1-α)0.844;dα/dt=4.262×1042e-135000/T(1-α)1.275 相似文献
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利用电介质的平均能带模型计算了R型六方铁氧体BaTi2Fe4O11和BaSn2Fe4O11的化学键参数,得到BaTi2Fe4O11的2a、4f、4e、6g各晶位平均共价性分别为0.062、0.354、 0.309、 0.361; BaSn2Fe4O11的相应晶位平均共价性分别为0.062、 0.353、 0.183、0.255.应用化学环境因子计算了57Fe、119Sn在R结构中的穆斯堡尔同质异能位移。确定了57Fe,119Sn的价态和占位情况. 相似文献
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PbBr2-PbF2-P2O5玻璃的结构研究 总被引:3,自引:0,他引:3
采用红外光谱(IR)和X射线光电子能谱(XPS)等方法研究了PbBr2-PbF2-P2O5系铅卤磷酸盐玻璃的结构。结果表明,Pb^2 离子在玻璃中起着网络修饰阳离子和网络形成体的双重作用。当P2O5含量为60mol%时,Pb^2 离子主要是作为网络修饰体;当P2O5含量降低到50mol%时,一部分Pb^2 离子能够进入玻璃网络形成[PbO4]四面体或P-O-Pb键。Br^-和F^-离子达到一定浓度时就会进入玻璃网络,形成[PO4-nXn](X=Br或F,n=0-4)四面体使磷酸盐链长变短。玻璃中P2O5的含量不变时P-O-P键的比例也基本保持不变;当P2O5的含量降低时,P-O-P键和P-O^-键的含量都减少,P-O-Pb键的含量则明显增加。 相似文献
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Oxyfluoride glasses with the composition 50SiO2 · 50PbF2 · xErF3 (x=4 and 5) by molar ratio were developed. Transparent glass ceramics were obtained by heat-treating the 50SiO2 · 50PbF2 · xErF3 glasses at the first crystallization temperatures. X-ray diffraction analysis of the transparent glass ceramics revealed that fluorite type -PbF2:Er3+ solid solution regions of about 13.0 nm in diameter are precipitated in the glass matrix. The formation of this -PbF2:Er3+ solid solution was also supported by Eu3+ fluorescence spectra which were measured on specimens in which Eu substituted for Er. Under 800 nm laser excitation, the Er3+ upconversion luminescence of 50SiO2 · 50PbF2 · xErF3 glasses was barely detectable, but the 50SiO2 · 50PbF2 · xErF3 glass ceramics gave Er3+ upconversion luminescence at a very high efficiency. The reason for the highly efficient Er3+ upconversion luminescence in the 50SiO2 · 50PbF2 · xErF3 glass ceramics can be explained in terms of the very small multiphonon relaxation rates that are anticipated from consideration of the Eu3+ emission spectra. 相似文献
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离子交换法制备波导放大器的磷酸盐铒玻璃研究 总被引:3,自引:0,他引:3
研究了不同Al2O3、Na2O、La2O3、Y2O3及AlF3含量的磷酸盐铒玻璃的物理化学性质和光谱性质,通过恒温水浴失重测试的方法探讨了玻璃组分Al2O3、Na2O、La2O3、Y2O3及AlF3对磷酸盐玻璃化学稳定性的影响.结果表明,Al2O3含量增加,玻璃化学稳定性提高,添加少量的AlF3会降低玻璃的化学稳定性,与La2O3相比Y2O3对提高玻璃的热稳定性有益.通过对比不同组分玻璃样品的热性质、机械性质以及析晶、光谱性质的结果,初步得出了一个比较适于离子交换过程的磷酸盐铒玻璃成分. 相似文献
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Yang LI Jianhu YANG Shiqing XU Guonian WANG Lili HU Laserglass Laboratory Shanghai Institute of Optics & Fine Mechanics Chinese Academy of Sciences Shanghai China Graduate School of the Chinese Academy of Sciences Beijing China 《材料科学技术学报》2005,21(3):391-394
The physical and thermal properties of P2O5-Al2O3-BaO-La2O3 glasses were investigated. The effects of glass compositions on the transition temperature, thermal expansion coefficient, density, hardness and refractive index of glasses were studied. The highest hardness of the glasses is 4143.891 MPa and the lowest thermal expansion coefficient of the glasses is 71.770×10-7/℃. A phosphate glass with high mechanical strength and good thermal characteristic is obtained. 相似文献
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以SnO—BaO—P2O5三元系统玻璃为研究对象,利用差示量热扫描分析仪、热膨胀仪、拉曼光谱仪,分析了玻璃的结构以及玻璃转变温度和热膨胀系数与玻璃组成的关系.获得了该体系玻璃的形成区域,测得该系统的玻璃转变温度为260~360℃和热膨胀系数为12~14×10^-6℃.研究发现,当P2O5=45mol%不变时,玻璃转变温度随着SnO含量的增加而降低;当BaO=10mol%不变时,玻璃转变温度随着SnO含量的增加先降低后升高.研究表明,该体系玻璃可以作为低温环保封接玻璃潜在的基质材料. 相似文献
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从成本和低温化考虑,磷酸盐低熔封接玻璃最有可能取代商业铅基低熔玻璃。总结了近20年来研究较多的SnO-MO(M=Zn,Mg,Ca)-P2O5、ZnO-Sb2O3-P2O5、Na2O-CuO-P2O5、Na2O-Fe2O3-P2O5、硼磷酸盐和磷酸盐氧氮低熔玻璃系统的玻璃形成范围、制备方法、结构特征、性能参数和应用范围,总结的玻璃性能主要包括化学稳定性、转变温度、软化温度和热膨胀系数;指出硼磷酸盐、Na2O-CuO-P2O5、ZnO-SnO(Sb2O3)-P2O5、铁磷酸盐系统玻璃的化学稳定性基本达到或优于商业铅基低熔封接玻璃,磷酸和硼磷酸盐系统适用于中低温封接,而SnO-ZnO-P2O5和Na2O-CuO-P2O5应用于低温封接仍需解决转变温度大幅浮动、成本高及热膨胀系数等问题。 相似文献
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T JermoumiMustapha Hafid N NiegischM Mennig A SabirN Toreis 《Materials Research Bulletin》2002,37(1):49-57
Experimental determination of the properties of less studied zinc-iron-phosphate glasses was investigated. Glasses of the general composition (50−x)ZnO-xFe2O3-50P2O5, mol%, with x=0, 10, 20, 30 and 40, was chosen for these investigations. These studies included, glass forming, glass density, thermal expansion coefficient, dilatometric softening temperature, an initial test of chemical durability and vibrational properties. It is shown that an Fe/P ratio of the compositions at about 0.6 and 0.8 and the O/P ratio at 3.4 and 3.8 could be considered as chemically durable phosphate candidates. 相似文献
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Rapidly quenched glassy films in the V2O5-PbO system were prepared using a twin-roller type apparatus. The glass formation region was 0–60 mol% PbO. The first crystallization temperature increased from 210 C for the V2O5 glass to 292 C for the glass of 60 mol% PbO. The metastable unknown phase was first crystallized in the glasses around 50 mol% PbO. Infrared absorption spectra of the glasses were measured. Electrical conductivity of the glasses decreased with increasing of PbO content. The electrical behaviour of the glasses is discussed based on the glass structure estimated from the infrared spectral data. 相似文献