快速凝固Al-Sr中间合金及其变质效果

快速凝固使Ａｌ－Ｓｒ合金产生了微观组织细化、缺陷密度增加、成分均匀化以及固溶体过饱和化等变化。在Ａｌ－Ｓｒ合金快速凝固条带（以下称激冷带）横截面上出现“双区”组织。冷却速度达到１０６Ｋ／ｓ激冷带的激冷侧晶粒达到纳米级。变质实验结果表明：不同冷却速度下形成的Ａｌ－Ｓｒ中间合金具有不同的变质效果，快速凝固的Ａｌ－Ｓｒ中间合金达到与常规Ａｌ－Ｓｒ中间合金相同的变质度，其用量减少５０％～６０％，潜伏期缩短５０％左右。     

Al-Ti-B-Sr对Al-Si-Mg合金的变质细化作用

用快速凝固和热变形处理的Ａｌ－Ｔｉ－Ｂ－Ｓｒ中间合金,对Ａｌ－Ｓｉ－Ｍｇ铝轮毂材料进行处理,试验结果表明：Ａｌ－Ｔｉ－Ｂ－Ｓｒ中间合金可以对Ａａ－７Ｓｉ－０．３５Ｍｇ合金有效地细化与变质;改善Ａｌ－Ｔｉ－Ｂ－Ｓｒ的细化与变质效果,Ａｌ－Ｓｉ－Ｍｇ合金的抗拉强度和延伸率较Ａｌ－Ｔｉ－Ｂ、Ａｌ－Ｓｒ两种中间俣金分别外入时提高了约１０％和２５％。     

Al-5%Ti-1%B对Sr变质Al-13.0%Si合金组织影响的研究

Ｓｒ八方为质剂加入到Ａｌ－Ｓｉ合金中能导致共晶硅的形态从粗大的片状转变为细小的纤维状,但同时也促进了柱状枝晶的形成。当Ａｌ－５％Ｔｉ－１％Ｂ加入量低于０．８％时,α枝晶有等轴化趋向,柱状枝晶的主干长度缩短,对共晶硅的形态与尺寸没有显著的影响,尽管共晶团尺寸略有下降。但当Ａ－５％Ｔｉ－１％Ｂ加入量超过０．８％后,其对Ｓｒ变质作用的有害影响显现出来,α－Ａｌ枝晶数量减少,出现初晶硅,共晶硅尺寸变大。随     

ZLD102合金熔炼工艺的改进

ＺＬＤ１０２合金熔炼工艺的改进ＺＬＤ１０２合金主要成分为１０．０～１３．０％Ｓｉ，余为Ａｌ。熔炼ＺＬＤ１０２合金之类Ａｌ－Ｓｉ合金的常规工艺是，先将纯Ｓｉ破碎成２０～５０ｍｍ的纯Ｓｉ块，在高温下加入铝熔体中，制成Ａｌ－Ｓｉ中间合金锭；用Ａｌ－Ｓｉ中间...     

Al—Sr合金变质处理的研究和应用

简介了Ａｌ－Ｓｉ合金变质处理的发展过程，用Ａｌ－Ｓｒ合金对ＺＬ１０４合金进行了变质试验，指出了Ａｌ－Ｓｒ合金变质剂的变质工艺参数，认为Ａｌ－Ｓｒ合金变质剂有长效性，质量稳定，操作简便，不污染环境等优点，有推广前途。     

Sr对ZL104合金的变质人艇

研究了Ａｌ－Ｓｒ中间合金对ＺＬ１０４合金中共晶Ｓｉ相的变质规律。结果表明，Ｓｒ对共晶Ｓｉ有很好的变质效果，Ｓｉ相由长针状变成尺寸为１－２μｍ的圆点状颗粒，变质效果长达４ｈ不衰退。变质后力学性能有较大提高。     

Al-3Ti-4B细化剂和Al-10Sr变质剂对 ZL104合金的联合作用

单一的Ａｌ－３Ｔｉ－４Ｂ细化剂可使０４合金获得１００－１２０μｍ左右的等轴枝晶,抗衰退期至少达２４０ｍｉｎ;单一的Ａｌ－１０Ｓｒ变质剂至少能在４８０ｍｉｎ内使ＺＬ１０４合金昌硅充分变质,当同时加入Ａｌ－３Ｔｉ－４Ｂ细化剂和Ａｌ－１０Ｓｒ变质剂时,有效变质时间大为缩短,晶粒稍有长大,其原因系因Ａｌ－１０Ｓｒ和Ａｌ－３Ｔｉ－４Ｂ反应生成了ＳｒＢ６。     

Ba变质对亚共晶Al—Si合金初生α固溶性的细化作用

用含钡中间合金处理亚共晶Ａｌ－Ｓｉ合金，重点研究了Ｂａ元素细化α固溶体的效果和机理。研究表明：当合金中残留含Ｂａ量为０．０５％－０．０８％时，无论是硅晶体还是α固溶体均获得了最佳的变质和细化效果，力学性能也出现了峰值效应。扫描电镜和电子探针结果表明：Ｂａ元素主要吸附在α固溶体的枝晶间和枝晶前沿，因阻碍α固溶体的过快生长和促进枝晶分枝，熔断等耐起到了细化作用。     

锶变质AlSi7Mg0.3合金力学性能衰退的研究

在生产条件下研究了保温时间对锶变质ＡｌＳｉ７Ｍｇ０．３合金力学性能的影响。保温时间延续６０ｍｉｎ以后，合金伸长率和冲击韧度下降了２０％，抗拉强度下降了５％，而硬度未发生变化。在此期间锶含量质量分数（０．００４％～０．００５％Ｓｒ）皆超过有效变质临界下限值（０．００３％Ｓｒ）。铝合金力学性能的衰退可能与吸气引起的密度降低、针孔数量增加有关。     

Al3Ti4B细化剂和Al10Sr变质剂和ZL107合金显微组织的影响

研究了Ａ１３Ｔｉ４Ｂ细化剂和Ａｌ１０Ｓｒ变质剂地ＺＬ１０７合金显微组织的影响。结果表明：第一Ａｌ３Ｔｉ４Ｂ细化剂的添加量大于０．６％时,可使ＺＬ１０７合金获得１００－１２０μｍ左右的等轴枝晶,且其抗衰退期至少不小于２４０ｍｉｎ,但对共晶硅没有变质作用,而一定量的Ａｌ１０Ｓｒ变质剂除了至少能在２４０ｍｉｎ内使共晶硅充分变质外,还对初生α（Ａｌ）晶粒具有一定的细化作用;当Ａｌ３Ｔｉ４Ｂ细化剂和Ａｌ１０     

压铸条件下过共晶铝硅合金P变质的必要性

在铝合金压铸生产过程中,Al-P中间合金变质处理和压力铸造工艺都能够使过共晶铝硅合金中的初晶硅晶粒细化.探讨Al-P中间合金变质处理,分别在压铸工艺条件下和普通金属型条件下,对过共晶Al-15Si合金组织的不同影响.试验表明,压铸条件下未经Al-P变质的和经Al-P变质的Al-15Si合金与金属型条件下未经Al-P变质的Al-15Si相比,初晶Si尺寸分别减小50%和75%左右;在相同的压铸工艺条件下,Al-P变质后Al-15Si合金初晶Si尺寸,比未经过Al-P变质的Al-15Si合金初晶Si尺寸减小40%左右.论证了在Al-Si系过共晶铝合金压铸件生产过程中,Al-P中间合金进行变质处理的必要性.     

Al-20％Si中间合金对Al-Si合金共晶Si变质行为的影响

研究了Al-20％Si中间合金对铸造Al-Si合金显微组织的影响.结果表明:向Al-Si合金熔体中加入1％的Al-20％Si中间合金,Al-7％Si合金中的共晶Si由粗大的板片状变为细密的纤维状或点状,变质效果较好,而对共晶Al- 12％Si合金的变质效果较弱;浇注温度对合金显微组织影响较大,适当降低浇注温度,有利于铸件组织的细化;变质温度越低越有利于颗粒状Si相成为形核核心,抑制枝晶组织的形成长大;在变质温度为650℃时,Al-20％Si中间合金对Al-7％Si合金变质有效时间是3h左右.     

Rolling of Plates and Sheets from As-Cast Ti-6Al-4V-0.1B

Trace boron addition (~0.1 wt.%) to conventional titanium alloys reduces the as-cast prior-beta grain size by an order of magnitude to about 200 μm, a grain size typically observed after ingot breakdown. In this study, the feasibility of producing plate and sheet by hot rolling of as-cast Ti-6Al-4V-0.1B (wt.%) was evaluated. Starting from an initial thickness of 25 mm, as-cast Ti-6Al-4V-0.1B was successfully rolled to 2 mm sheet in a multistep rolling process. As-cast Ti-6Al-4V (without boron addition) rolled under similar conditions exhibited severe cracking. Tensile properties of the sheets and plates made from the boron-containing alloy met or exceeded AMS 4911 specifications for Ti-6Al-4V plates and sheets produced by conventional processing route. The process of making plate and sheet stock from cast titanium alloy ingots, without recourse to expensive ingot breakdown, can significantly reduce the number of expensive and time-consuming processing steps for making titanium alloy components, thereby enhancing the affordability and expanding the range of titanium applications.     

冷却速度对A356铝合金变质效果的影响

采用不同铸型的阶梯形试样,分别添加量为0．04％的Al—10％Sr中间合金和1％的三元钠盐变质剂对A356熔体进行变质处理。研究了冷却速度对A356合金变质效果的影响和这两种变质剂对冷却速度的敏感性。结果表明：冷却速度越大,枝晶间距越小,变质效果越好;Na变质对于冷却速度的敏感性高于Sr。     

Effect of a grain refiner cum modifier on mechanical properties of Al-7Si and Al-11Si alloys

This study evaluates the influence of grain refiners/modifiers on the mechanical properties of the Al-7Si and Al-11Si alloys with an experiment of quantitative and qualitative correlations with the microstructure. Modification of Al-Si alloys with strontium additions and grain refinement with Al-Ti, Al-B and Al-T-B master alloy additions are demonstrated to be efficient on Al-Si alloys. A single master alloy with combined additions of Sr and Ti and/or B was prepared and the microstructure and mechanical properties were studied. The results show that boron rich (Al-3B-Sr and Al-1Ti-3B-Sr) master alloys are more efficient than Ti rich (Al-3Ti-Sr and Al-5Ti-1B-Sr) master alloys considering their combined grain refinement and modification effect on Al-7Si and Al-11Si alloys. However, the presence of Sr does not influence the grain refinement. Similarly, presence of grain refiner does not influence the modification of eutectic Si.     

Sr变质对蛇形通道浇注Al-22Si-Cu合金组织的影响

采用纯铜蛇形通道浇注和Sr变质的复合工艺,对Al-22Si-Cu过共晶合金组织与性能进行研究。结果表明,蛇形通道工艺可将初生Si晶粒尺寸从90μm细化至28.03μm。随着Sr含量增加,初生Si的析出温度降低,合金的孪晶密度和初生Si尺寸均先增大后减小,当Sr含量为0.09%时达到最大值;共晶Si由长针状转变为纤维状;Sr含量为0.12%时,合金的抗拉强度达到212.32MPa。     

Modification of Sr on 4004 Aluminum Alloy

As a brazing foil, 4004 Al alloy has good welding performance. However, the high Si content decreases the plasticity of the alloy. To improve the plasticity of 4004 Al alloy and subsequently improve the productivity of 4004 Al foil or 434 composite foil, 4004 Al alloy was modified by Al-10%Sr master alloy. Modification effects of an additional amount of Sr, modification temperature, and holding time on 4004 aluminum alloy were studied by orthogonal design. The results showed that the greatest impact parameter of 4004 aluminum alloy modification was the additional amount of Sr, followed by holding time and modification temperature. The optimum modification parameters obtained by orthogonal design were as follows: Sr addition of 0.04%, holding time of 60 min, and modification temperature of 760°C. The effect of Sr addition on modification was analyzed in detail based on orthogonal results. With increasing of Sr addition, elongation of 4004 alloy increased at first, and decreased after reaching the maximum value.     

Al-5Ti-1B对Al-Si合金磷变质行为影响机理的研究

研究了熔炼条件及Al-5Ti-1B中间合金加入量对P变质ZL109合金凝固组织的影响，并着重对其影响机理进行了探讨。结果发现在中频感应炉熔炼条件下，加入适量Al-5Ti-1B对初晶硅有明显的细化作用，而在静置炉（电阻炉）熔炼条件下，这种作用却不明显；同时发现，无论是在电阻炉还是感应炉熔炼条件下，加入过量的Al-5Ti-1B都会使合金中的初晶硅粗化。EPMA分析发现，加入Al-5Ti-1B后合金的初晶硅中心有Ti元素富集。分析认为Al-5Ti-1B中的TiB：粒子对AlP质点具有吸附作用，从而对Al-P中间合金的变质效果产生影响。     

电热法生产过共晶Al-Si合金的组织与性能研究

对电热法生产铝硅合金配制的Al-20Si合金进行了P-RE复合变质处理,对变质后的微观组织和力学性能进行了分析.结果表明,合金经复合变质后,合金的初晶硅尺寸得到明显细化,共晶硅由长针状变为短杆状或者细小的颗粒状;其抗拉强度由182MPa提高到205MPa,提高12.6%了,其伸长率由0.22%提高到0.26%,提高了18.2%.然而与纯铝配制的过共晶铝硅合金相比,其抗拉强度和伸长率都相对较低,原因在于电热法生产铝硅合金配制的过共晶铝硅合金中Fe含量较高.     

Variation of microstructure of RE-containing AlSi20Cu2Ni1RE0.6 alloy with different cobalt contents

Cobalt is generally considered as the element that can promote the high-temperature mechanical properties of Al-Si alloys. In order to develop new hypereutectic Al-Si alloys that can be used at high temperature, the changes of microstructure of Al-20Si-2Cu-1Ni-0.6RE-xCo alloy with different contents of Co were studied in this paper. The results show that, under P-RE complex modification of the alloy melt, the content of Co varying from 0 to 1.5% had little influence on the refining effect of primary Si and modification effect of eutectic Si, but the amount of acicular RE-bearing Al-RE-Ni-Co-Si compounds gradually increased with the increase of Co content. In addition, Co could also modify the morphology of Fe-bearing phases, which solidified as particles instead of long needles. The addition of Co even has an adverse effect on the tensile strength of this RE-containing hypereutectic Al-Si alloy.