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RDX-CMDB推进剂的催化热分解Ⅰ.高压热分解与燃速相关性研究 总被引:2,自引:2,他引:0
用高压差示扫描量热仪(PDSC)研究了一种RDX-CMDB推进剂在所选用燃速催化剂(没食子高铅、对氨基苯甲酸铜和炭黑)作用下的热分解,并对比了纳米和非纳米催化剂对其热分解的影响。结果表明,压力和不同复合组成的燃速催化剂对PDSC特征量和RDX的相对放热量有影响;在14 MPa压力范围内PDSC的特征量和压力可用一经验方程,通过二元回归与燃速关联。该方程能得到表征压力(压强)和放热速度对燃速的贡献程度的参数,能反映较高压力(8~14 MPa)下推进剂燃速的平台效应和不同复合组成的燃速催化剂的影响。 相似文献
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用高压差示扫描量热仪(PDSC)研究了一种RDX-CMDB推进剂在所选用燃速催化剂(没食子高铅、对氨基苯甲酸铜和炭黑)作用下的热分解,并对比了纳米和非纳米催化剂对其热分解的影响。结果表明,压力和不同复合组成的燃速催化剂对PDSC特征量和RDX的相对放热量有影响;在14MPa压力范围内PDSC的特征量和压力可用一经验方程,通过二元回归与燃速关联。该方程能得到表征压力(压强)和放热速度对燃速的贡献程度的参数,能反映较高压力(8-14MPa)下推进剂燃速的平台效应和不同复合组成的燃速催化剂的影响。 相似文献
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利用高压差示扫描量热(PDSC)法研究了高氯酸铵/铝粉—复合改性双基(AP/Al-CM-DB)推进剂在1.0~13.0 MPa压强范围内的燃速与高压热分解特性的相关性。研究结果表明,AP/Al-CMDB推进剂在1.0~13.0 MPa压强范围内的燃速与高压热分解的相关性模型中需将压强p和放热速度ΔHd/Δθ两个影响因子对推进剂燃速的影响程度分开独立考虑,该相关性符合模型关系式u=kupa[ΔHd/Δθ]b,利用该相关性模型所得的燃速计算值与实测值之间的误差低于2.50%. 相似文献
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有机铜盐对RDX-CMDB推进剂的燃烧性能和高压热分解的影响 总被引:1,自引:1,他引:0
研究了三种有机铜盐燃烧催化剂β-雷索辛酸铜(β-Cu)、3-硝基-1,2,4三唑-5-酮铜盐(NTO-Cu)和2,4-二硝基咪唑铜(NI-Cu)对RDX-CMDB推进剂不同压强下的燃烧性能和热分解的影响。结果表明,三种有机铜盐燃烧催化剂对RDX-CMDB推进剂的燃烧性能和差示扫描量热法(DSC)特征量有一定影响;β-Cu、NTO-Cu和NI-Cu三种有机铜盐可使RDX-CMDB推进剂热分解的第一个分解峰温Tp1提前1~4℃,并将第二个分解峰温Tp2提前5~11℃;RDX-CMDB推进剂的燃速和DSC特征量随压强的升高而增大,在1~10MPa压强下该类推进剂的燃速与DSC特征量呈线性相关。 相似文献
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RDX-CMDB推进剂的催化热分解Ⅱ. 分解气体产物和催化作用机理 总被引:4,自引:2,他引:2
用热重-差示扫描量热-傅立叶转换红外-质谱(TG-DSC-FTIR-MS)联用技术研究了RDX-CMDB推进剂在所选用燃速催化剂(没食子高铅、对氨基苯甲酸铜和炭黑)作用下的热分解。对添加催化剂(纳米和普通)和不添加催化剂的RDX-CMDB推进剂热分解主要气体产物变化进行了分析,讨论了燃速催化剂对热分解特征量的影响,初步探索了催化剂的作用机理。结果表明,所研究的燃速催化剂能改变推进剂中RDX的初期热分解机理,使放热的C—N键断裂在与吸热的N—NO2键断裂的竞争反应中占优,放热量增大;也使双基组分放出有负生成热的CH2O的相对量增加;纳米铝盐-铜盐-炭黑三元复配催化效果最好。 相似文献
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用燃速测试和高压差示扫描量热法(PDSC)试验,研究了N,N-二硝基哌嗪(DNP)逐渐取代改性双基推进剂(CMDB)中的黑索今(RDX)后,对推进剂燃烧性能和热分解特性的影响.研究结果表明,DNP的加入减缓了CMDB推进剂中RDX的热分解反应,使CMDB推进剂燃速降低,压强指数变小,且高压下(12~18 MPa)燃速降低幅度更加明显.当DNP含量增加到20%(DN3)时,DNP的放热分解峰从推进剂主分解放热峰中分离出来,此放热峰在9 MPa下出现肩峰. 相似文献
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The stability under illumination of transmission-mode GaAs photocathode sealed in the third generation intensifier is investigated by use of spectral response testing instruments. The variations of spectral response with the illumination times under weak and intense illumination are compared. The variations of photoemission performance parameters are also characterized. The results show that during initial several weak illuminations photocathode behaves no evident decay and a maximum sensitivity is achieved, while under intense illumination the sensitivity of photocathode begin to decrease largely at the first illumination. The calculated performance parameters show that the variation of surface escape probability with illumination times is a direct cause of instability of photocathode. It is also found that under intense illumination peak wavelength is moved towards short-wave and peak response is decreased, which shows that the ability of long-wave response of photocathode is decreased. 相似文献
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A Passive Acoustic Radar is presented as a necessary complement to electromagnetic wave radar, which will be expected to be an effective means for detecting cruise missiles. Acoustic characteristics of supersonic flying projectiles with diverse shapes are expounded via experiment. It is pointed out that simulation experiment could be implemented using bullet or shell instead of cruise missile. Based on theoretical analysis and experiment, the ““acoustic fingerprint““ character of cruise missile is illustrated to identify it in a strong noise environment. After establishing a locating mathematical model, the technique of acoustic embattling is utilized to resolve a problem of confirming the time of early-warning, considering the fact that velocity of sound is much slower than that of light. Thereby, a whole system of passive acoustic radar for detecting supersonic cruise missile is formed. 相似文献
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The test scheme of static postponing time given in our actual national military test standard on shrapnels used to control riot is a nine-point test scheme on the combined action of three kinds of temperatures and three kinds of pressures,the consumed ammunitions are more excessive. Statistic analysis and tentative checkout about a lot of test data are done,feasibility gists are put forward for optimizing of the test design scheme. The optimizing design and data analysis of test scheme of the item are done by managing uniformity design theory, two scientific and reasonable six-point test schemes are confirmed. The feasibility and reliability of the optimizing design schemes put forward above are proved ulteriorly by test validating. The gained schemes not only have good design uniformity and little ammunition wastage and meet the test demand, but also have better forecast ability for the result data of other points using the mathematic models from the actual test points. 相似文献
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A novel image restoration scheme, which is super-resolution image restoration algorithm Poisson-maximum-afterword-probability based on Markvo constraint (MPMAP) combined with evaluating image detail parameter D, has been proposed. The advantage of super-resolution algorithm MPMAP incorporated with parameter D lies in the fact that superresolution algorithm MPMAP model is discrete, which is in accordance with remote-sensing imaging model, and the algorithm MPMAP is proved applicable to linear and non-linear imaging models with a unique solution when noise is not severe. According to simulation experiments for practical images, super-resolution algorithm MPMAP can retain image details better than most of traditional restoration methods; at the same time, the proposed parameter D can help to identify real point spread function (PSF) value of degradation process. Processing result of practical remote-sensing images by MPMAP combined with parameter D are given, it illustrates that MPMAP restoration scheme combined PSF estimation has a better restoration result than that of Photoshop processing, based on the same original images. It is proved that the proposed scheme is helpful to offset the lack of resolution of the original remote-sensing images and has its extensive application foreground. 相似文献
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A nonlinear terrain following(TF) and terrain avoidance(TA) controller is proposed for missile control systems. Based on classical TF algorithm (adaptive angle method), a new method for TF controller is proposed by using angle of attack. A method of obtaining terrain outline data from digital elevation map (DEM) for TF control is discussed in order to save store space. A TA algorithm is proposed by using bank-to-turn technique. The block control model, which is suitable for backstepping design, is given for nonlinear model of missile. Making full use of the characteristics of the system and combining block control principle and backstepping technique, a robust controller design method is proposed. Uncertainties in every sub-block are allowed, and can be canceled by using the idea of nonlinear damping. It is proved that the state tracking errors are converged to a neighborhood of the origin exponentially. Finally, nonlinear six-degree-of-freedom simulation results for the missile model are presented to demonstrate the effectiveness of the proposed control law. 相似文献
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The design problem of non-fragile estimator is addressed for a class of perturbed linear continuous systems. The perturbations occur on the plant and estimator parameters. The estimator designed should force the error system to achieve the desired decay rate and force the steady error variance less than the specified upper bound irrdevancy of the admissible plant perturbations and estimator perturbations. Consistency problem of the decay rate with the variance upper bound is first considered via linear matrix inequality (LMI) approach. The solution of the estimator parameter under specifications to be consistent is then discussed. The consistency condition of specifications and estimator parameter solution are transformed to feasible or minimum problems subject to a set of LMI respectively. The method is illustrated by a numerical example. 相似文献
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The improved scene-based adaptive nonuniformity correction (NUC) algorithms using a neural network (NNT) approach for infrared image sequences are presented and analyzed. The retlna-like neural networks using steepest descent model was the first proposed infrared focal plane arrays (IRFPA) nonuniformity compensation method, which can perform parameter estimation of the sensors over time on a frame by frame basis. To increase the strength and the robustness of the NNT algorithm and to avoid the presence of ghosting artifacts, some optimization techniques, including momentum term, regularization factor and adaptive learning rate, were executed in the parameter learning process. In this paper, the local median filtering result of Xij ( n ) is proposed as an alternative value of desired network output of neuron Xij ( n ), denoted as Tij ( n ), which is the local spatial average of Xij ( n ) in traditional NNT methods. Noticeably, the NUC algorithm is inter-frame adaptive in nature and does not rely on any statistical assumptions on the scene data in the image sequence. Applications of this algorithm to the simulated video sequences and real infrared data taken with PV320 show that the correction results of image sequence are better than that of using original NNT approach, especially for the short-time image sequences (several hundred frames) subjected to the dense impulse noises with a number of dead or saturated pixels. 相似文献
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The disadvantages of IR images mostly include high noise, blurry edge and so on. The characteristics make the existent smoothing methods ineffective in preserving edge, To solve this problem, a piecewise moment filter (PMF) is put forward. By using moment and piecewise linear theory, the filter can preserve edge. Based on the statistical model of random noise, a related-coefficient method is presented to estimate the variance of noise. The edge region and model are then detected by the estimated variance. The expectation of first-order derivatives is used in getting the reliable offset of edge. At last, a fast moment filter of double-stair edge model is used to gain the piecewise smoothing results and reduce the calculation. The experimental result shows that the new method has a better capability than other methods in suppressing noise and preserving edge. 相似文献
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A best linear unbiased estimation (BLUE) algorithm for bistatic sonar localization is proposed. The Cramer-Rao bound for bistatic Sonar and the geometrical dilution of precision (GDOP) in different conditions are given. The simulation results show that the location accuracy of BLUE algorithm is higher than the weighted least square method. 相似文献
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A fault diagnosis method of working position gear in a tank gearbox is put forward based on simulating the fault of working position gear in an actual tank, extracting the envelope of vibration signal by Hilbert transformation amplitude demodulation method, and zooming the low-frequency band to envelope signal. 相似文献