pH敏感性材料在智能食品包装中的应用进展

随着消费者食品安全意识的增强,通过包装颜色变化对食品品质进行直观判断成为一个新的需求,智能包装近年来成为学界和产业界的共同关注点。pH敏感性材料与聚合物混合后获得的食品包装膜,在不同的pH条件下显示不同颜色,具有实时监测肉、虾、牛奶等食品新鲜程度的效果。本文介绍了化学显色剂和天然色素显色剂两大pH敏感性型指示器,分类介绍花青素、姜黄素、茜素、紫草素、甜菜碱等天然食品色素在不同pH下的变色机理,总结了pH敏感性材料与不同聚合物共混改性后在食品包装领域的研究进展、应用现状和研究趋势,为制备性能良好、绿色环保的智能食品包装提供参考。     

食品智能包装新鲜度指示剂研究进展

作为智能包装不可缺少的一部分——新鲜度指示剂,通过指示敏感材料,与食品腐败过程中产生的特定产物发生反应,并将反应结果转换成易于消费者直接观察和判断的信号,如：颜色信号、电信号、荧光信号等,为消费者提供实时质量监控信息,本文综述了食品智能包装新鲜度指示剂的分类,包括CO₂敏感型指示剂、TVB-N敏感型指示剂、pH敏感型指示剂及其成型工艺,涵盖了食品智能包装新鲜度指示剂的应用,旨在为食品智能包装新鲜度指示剂的发展提供参考,为食品损失和污染等传统包装问题提供了潜在的解决方案,其后续发展应朝着方便、快捷、实时显示食品质量变化的方向,以减少因食品质量差和安全问题带来的健康问题,研发新型的新鲜度指示剂,有利于将智能包装技术推广至更多的包装应用中,为产品质量提供理论指导与技术支撑。     

pH指示剂染料染色棉织物的各项性能分析北大核心

近年来酸致变色纺织品的发展引起了人们很大的兴趣,可用作传感系统,能以非破坏性的方式展示一种可视信号.基于传统的染色技术,使用pH敏感型染料染色棉织物开发一种p H纺织传感器,主要选取灿烂黄、茜素、刚果红3种染料进行研究.结果发现,3种pH指示剂染料表现出较好的结果,pH指示剂在织物上的性能与其在水溶液中的性能不同,在酸性和碱性条件下的最大吸收波长会发生红移,动态pH范围变宽.证明通过传统的染色技术使用pH指示剂染料染色棉织物来设计一种pH感应器是可行的.     

花青素pH响应型智能包装及其在食品新鲜度监测中的应用

随着消费者对食品安全和质量的要求不断提高，以及食品包装技术的发展进步，近年来食品智能包装发展迅速。pH响应型智能包装能通过感知食物或其周围pH值的变化产生颜色反应实现对食物新鲜程度和腐败程度的反馈，是研究的热点。花青素因其获得简便、安全性高和优异的pH响应性等特点被广泛研究。该文介绍了花青素的来源及结构，阐述了花青素在不同pH值下的变色机理，总结了基于花青素或富含花青素提取物的pH响应型智能膜的制备方法和其在食品新鲜度监测中的应用，指出了其在应用中的局限性及研究趋势。     

苋菜天然色素染色性能及应用

研究了苋菜红天然植物染料在不同条件下的稳定性及染色性能.通过测试染液可见吸收光谱、织物色度以及染色牢度来探讨pH、温度对苋菜红天然色素的影响及染料对丝绸织物的染色性能.结果显示:苋菜红天然染液颜色特征随pH改变而有所改变,在酸性条件下表现出比较稳定的红色调;染液在70℃以下热稳定性良好;金属离子媒染可以提升苋菜红染丝绸织物的染色深度和牢度.     

花青素与姜黄素在食品包装领域的应用

花青素和姜黄素对于活性包装至关重要,探讨其内在机理,可为花青素、姜黄素智能包装膜的相关研究提供理论参考。本文综述了花青素、姜黄素的结构和性质、提取方法、抗氧化活性、花青素和姜黄素在食品包装上的应用以及两种色素混合在食品包装上的应用。花青素和姜黄素由于其自身结构特点,在不同的pH下有不同的颜色,花青素作为颜色指示剂变色范围广,但性质不稳定,易受到外界因素影响。姜黄素稳定性高于花青素,但变色范围窄。此外,两者均具有很好的抗氧化活性,可作为颜色指示剂与抗氧化剂应用在食品包装中。花青素和姜黄素的变色特点、稳定性以及功能活性对食品新鲜度指示包装的性能具有显著的影响,将两种色素混合作为指示剂添加到食品包装中,有助于提高花青素的稳定性,从而获得更好的指示效果。     

新鲜度指示型智能包装的研究进展

食品新鲜度指示型智能包装是利用食品在贮藏过程中释放的某些特征气体与特定试剂产生的特征颜色反应、温度激活生物学反应及酶作用等引起指示剂发生明显的变化,从而帮助消费者直观、准确以及科学的判断食品品质与新鲜程度。因此,食品新鲜度指示剂在实际生活中具有重要的应用价值。本文在归纳和分析国内外新鲜度指示型智能包装的基础上,分别从食品新鲜度指示剂应用类型与新鲜度指示剂基材两个方面阐述了新鲜度指示剂的指示原理与研究现状以及指示剂基材的制作工艺与材料选择,对现有研究成果进行总结,指出了研究中依然存在的问题并对未来的研究方向进行展望以及提出合理性研究建议,旨在为今后更深入的食品新鲜度指示剂技术研究提供借鉴和参考。     

基于pH驱动法的姜黄素/明胶指示膜制备、表征及对刀额新对虾的新鲜度指示

摘 要：目的 为拓宽姜黄素(Curcumin, Cur)作为pH指示剂在水产品新鲜度可视化检测中的应用。 方法 本研究以明胶(Gelatin, Gel)为成膜基质, 姜黄素为指示剂, pH驱动法制备指示膜, 比较不同成膜pH值对指示膜微观结构、机械性能及颜色响应能力等指标的影响, 并应用于刀额新对虾(Metapenaeus ensis)新鲜度检测。结果 pH驱动法显著提高了姜黄素和明胶的相容性, 傅里叶变换红外光谱(Fourier transform infrared spectroscopy, FT-IR)分析表明, 姜黄素在pH驱动过程中主要通过氢键和疏水相互作用包埋于明胶网络中。X射线衍射(X-ray diffraction, XRD)和扫描电子显微镜(scanning electron microscopy, SEM)结果显示, 姜黄素在pH驱动过程中以无定形形态存在, 而不同成膜pH导致了姜黄素在指示膜内的溶解性差异, 影响了指示膜的微观结构。当最终成膜液为pH=7.0时, 指示膜具有最优异的柔韧性(断裂伸长率为49.46%)、阻隔性能(水蒸气透过率为18.64±0.31 10-10 g/m·Pa·s)和颜色响应能力。此外, 将性能最优的指示膜用于刀额新对虾(Metapenaeusensis)(4℃)新鲜度指示实验, 在实验期间指示膜出现明显的颜色变化, 并对应鲜度等级划分, 相关性分析表明指示膜色差值(ΔE)与pH值、挥发性盐基氮(total volatile basic nitrogen, TVB-N)含量存在显著正相关(R2=0.92806), 表明指示膜能够对鲜虾的新鲜度进行可视化实时监测。结论 pH驱动法制备的Gel/Cur指示膜可以作为水产品新鲜度实时检测的智能包装。[基金项目：国家重点研发计划(2018YFD0901003)、国家自然科学基金项目(31801607)、贺州学院博士科研启动基金项目(HZUBS202106) Fund：Supported by National Key Research and Development Program (2018YFD0901003), National Natural Science Foundation of China Project (31801607), Hezhou College Doctoral Research Start-up Fund Project (HZUBS202106) *通信作者：宋慕波，博士，教授，主要研究方向为农产品加工及贮藏工程。E-mail：202009002@hzxy.edu.cn *Corresponding author: SONG Mu-Bo, Ph.D, Professor, Hezhou University, No.3261 Xiaohe Dadao, Babu District, Hezhou City, Guangxi 542899, China. E-mail：202009002@hzxy.edu.cn ]     

壳聚糖、大豆分离蛋白基pH响应智能标签的制备及响应性研究

基于花青素的生物聚合物基pH响应型智能标签因其制备简单、成本低、环境友好备受研究者关注。该文对石榴汁在不同pH值下的颜色变化进行了研究；以石榴汁为指示剂分别制备了壳聚糖和大豆分离蛋白pH响应标签。石榴汁在不同的pH值下具有明显的颜色变化。石榴汁-壳聚糖响应标签具有较高的水分含量和透光率，对不同的pH值有明显的颜色变化。石榴汁的添加使壳聚糖标签具有极好的紫外线阻隔能力。石榴汁-大豆分离蛋白响应标签的pH响应性优于石榴汁-壳聚糖标签，但其形变能力差，易溶解。添加30%石榴汁的大豆分离蛋白响应标签的表面出现裂痕和气孔。傅里叶变换红外光谱分析表明在石榴汁和壳聚糖之间有氢键形成。扫描电子显微镜显示石榴汁-壳聚糖标签表明光滑、平整，石榴汁与壳聚糖具有良好的兼容性。鲜虾的保鲜试验表明，这2种pH响应标签具有应用于虾类保鲜的潜力，石榴汁-壳聚糖响应标签具有更加稳定的形态。     

苋菜红天然植物染料染色性能及应用

研究苋菜红天然植物染料在不同条件下稳定性及其染色性能。通过测试染液可见吸收光谱、织物色度指标以及染色牢度来探讨酸碱、温度对苋菜红天然染料的影响及染料在丝绸织物的染色应用。研究结果显示:苋菜红天然染液颜色特征随pH值改变而有所改变,在酸性条件下表现比较稳定的红色调;染液在70℃以下热稳定性良好;金属离子媒染工艺可以较大程度提升苋菜红染丝绸织物的染色深度和牢度。     

pH值敏感型食品新鲜度指示标签及其应用的研究进展

近年来,智能包装的研究受到巨大关注,pH值指示标签是新鲜度指示器中的一种,可以简单、高效、实时、直观地通过标签颜色变化反映食品的新鲜度,在食品供应链中有巨大的发展潜力。为了改善pH值指示标签的效果,研究者们开发了多种类型的pH值敏感色素和基体材料,以强化指示标签的显色强度,优化阻隔性、机械强度、稳定性及生物活性。本文从pH值敏感色素来源和基膜类型两方面分析pH值新鲜度指示膜的研究进展,并对当前研究面对的困难、挑战与未来研究趋势进行讨论,以期为pH值敏感型指示标签的研究和应用提供参考。     

Development of sago (Metroxylon sagu)-based colorimetric indicator incorporated with butterfly pea (Clitoria ternatea) anthocyanin for intelligent food packaging

Innovation in colorimetric sensors to detect early signs of food spoilage is a growing interest in food safety and quality control. Currently available chemical dyes for sensor applications have concern because of their possible migration into food packaging and food in contact. In this study, a colorimetric indicator was developed using natural butterfly pea (Clitoria ternatea) anthocyanin with Sago (Metroxylon sagu) as polymeric film. The principle was based on pH shift due to chemical processes produced by microorganism causing anthocyanin color to change. The film was fabricated by solvent casting method and characterized by color change at different pH values, total water solubility, swelling rate, and morphological structure. Trials on chicken breast samples in various conditions exhibited that the film indicator responded well according to pH variation enabling a real-time monitoring due to spoilage. Thus, our natural pH indicator with visible color variation allows for simple, economic and safe monitoring of perishable foods.     

A review on colorimetric indicators for monitoring product freshness in intelligent food packaging: Indicator dyes,preparation methods,and applications

Intelligent food packaging system exhibits enhanced communication function by providing dynamic product information to various stakeholders (e.g., consumers, retailers, distributors) in the supply chain. One example of intelligent packaging involves the use of colorimetric indicators, which when subjected to external stimuli (e.g., moisture, gas/vapor, electromagnetic radiation, temperature), display discernable color changes that can be correlated with real-time changes in product quality. This type of interactive packaging system allows continuous monitoring of product freshness during transportation, distribution, storage, and marketing phases. This review summarizes the colorimetric indicator technologies for intelligent packaging systems, emphasizing on the types of indicator dyes, preparation methods, applications in different food products, and future considerations. Both food and nonfood indicator materials integrated into various carriers (e.g., paper-based substrates, polymer films, electrospun fibers, and nanoparticles) with material properties optimized for specific applications are discussed, targeting perishable products, such as fresh meat and fishery products. Colorimetric indicators can supplement the traditional “Best Before” date label by providing real-time product quality information to the consumers and retailers, thereby not only ensuring product safety, but also promising in reducing food waste. Successful scale-up of these intelligent packaging technologies to the industrial level must consider issues related to regulatory approval, consumer acceptance, cost-effectiveness, and product compatibility.     

Applications of natural polysaccharide-based pH-sensitive films in food packaging: Current research and future trends

With the increased awareness of food safety and growing environmental concern of plastic packaging disposal, the research and development of novel food packaging is extremely urgent and attracts much attention. Natural polysaccharides are ideal candidate materials to develop “green” food packaging due to their biodegradable properties and good film-forming properties. Especially, the natural polysaccharides-based intelligent films can provide consumers the real-time information about the quality and safety of the packaged food through the pH-sensitive indicators. Consequently, this paper summarized the current researches on the development of natural polysaccharides-based pH-sensitive films. Then, the applications of natural polysaccharides-based pH-sensitive films in food packaging, including the packaging for meat products, fruits and vegetables, etc., are emphasized. Finally, an overview of the trends/challenges of pH-sensitive films in food packaging is discussed. Taken together, the natural polysaccharide-based pH-sensitive food packaging films show more advantages as compared with the common food package films, which can not only protect the packaged food, but also monitor the quality of packaged food in real time. Nevertheless, the further studies should continue to focus on the commercially sustainable key points including consumer acceptance and trust, cost, regulatory considerations and multifunctional performance of the pH-sensitive food packaging films.     

食品新鲜度指示器的研究与发展趋势

食品新鲜度与消费者的饮食安全密切相关。新鲜度指示器可检测食品腐败所产生的释放物并产生直观的颜色变化指示食品的新鲜度,成为研究热点。这些释放物包括挥发性盐基氮、二氧化碳、硫化氢等。围绕这些释放物分别开发了盐基氮指示型、二氧化碳指示型以及硫化氢指示型指示器。本文综述了上述指示器的工作原理及研究进展,并指出加强指示新鲜度对象的特异性识别,发展天然色素显色剂型指示器,发展接触式非破坏型指示器,发展电子式智能化指示器是主要的发展趋势。随着新鲜度指示器技术不断成熟,其在新鲜食品包装领域将会得到越来越广泛的应用。     

负载天然色素的生物基智能包装指示器研究进展

智能包装指示器能够基于其检测、感知和记录产品环境变化的能力为消费者提供被包装食品新鲜度、安全性或食品环境条件(温度、pH值、气体氛围)等的有效信息,是传统包装传播信息能力的延伸,并且有助于改善危害分析与关键控制点(HACCP)和质量分析与关键控制点(QACCP)系统,有助于现场检测不安全食品,识别潜在的健康危害,并制定策略以减少或消除食品安全问题发生。生物基智能包装系统因采用可降解、可再生材料向消费者直观显示包装食品在供应链中的品质相关信息,契合循环经济和可持续发展的需求而备受关注。介绍了以天然色素(花青素、叶绿素、姜黄素和甜菜素等)为敏感元件,以生物基聚合物(多糖、蛋白质、脂质和改性纤维素等)为载体的环境友好型智能包装指示器(pH值感应、时间-温度感应、气体感应等)的类型、功能适应性及其在监控食品品质、储运环境等方面的新趋势、新进展。     

Electrospun nanofibers as food freshness and time-temperature indicators: A new approach in food intelligent packaging

Intelligent packaging with the ability to detect chemical, physical, and/or biological changes in the food is a breakthrough in the food industry. Food freshness indicators (FFI) and time-temperature indicators (TTI) are major groups of intelligent packaging. They can be fabricated as a label, providing a rapid response to food quality or storage temperature changes through color changes. Electrospinning, as an effective and versatile method of preparing continuous nanofibers, has been employed as a promising candidate to manufacture food packaging materials. More recently, electrospun nanofibers have been utilized as a novel platform for the development of FFI/TTI intelligent packaging due to their excellent properties including high molecular orientation, high porosity, high surface area with tailored morphology, and a high level of versatility. This article reviews the morphological/thermal properties, color response activity, and stability of electrospun nanofibers mats as intelligent food packaging (i.e., FFI and TTI-based electrospun nanofibers). The applications of FFI/TTI-based nanofibrous on different food commodities are discussed. Finally, the existing limits and perspectives for the development of electrospinning in the area of intelligent food packaging are discussed.     

基于天然色素的食品新鲜度指示包装研究进展

随着食品安全意识的不断增强,消费者希望通过更加快捷直观的方式了解他们所购买食品的质量。由此出现了能在食品运输和储藏过程中,向人们提供食品质量信息的食品新鲜度指示包装。考虑到食品的安全性,越来越多的研究者开始利用植物中提取的天然色素作为指示剂。本文综述了近年来以花青素、姜黄素、茜素和紫草素为染料的食品新鲜度指示膜的研究现状。分析了基于天然色素的食品新鲜度指示膜在生鲜肉、水产品、牛奶和水果中的应用原理及其研究进展,并对食品新鲜度指示包装的研究和应用前景进行了展望。