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采用溶胶-凝胶技术制备TiO2/ZnO及掺银水溶胶,通过浸轧、烘干、焙烘等工序整理到织物上,测试了TiO2与ZnO溶胶的复合比例、浓度及掺银量对织物紫外屏蔽性能的影响。试验结果表明,分别采用TiO2:ZnO为3:7、5:5、7:3的水溶胶整理织物后,在297nm处的紫外线透过率分别为1.99%、0.83%、0.90%;最适宜的溶胶浓度为0.2~0.4mol/L,Ag^+的掺入对UVB波段的紫外屏蔽性能基本无影响,但可以明显降低UVA波段的紫外线透过率,掺Ag^+量为0.7%时较经济。 相似文献
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PBA/TiO2接枝复合整理剂及其整理棉织物的抗紫外线性能 总被引:2,自引:1,他引:1
通过原位乳液聚合制备了TiO2粒子表面接枝率为13.5%的PBA/TiO2接枝复合胶乳,以其为整理剂,通过浸轧对棉织物进行抗紫外线整理。研究表明:经PBA/TiO2接枝复合整理剂整理的棉织物具有优异的抗紫外性能和耐洗性能。扫描电镜观察发现,经PBA/TiO2整理的棉纤维表面TiO2粒子附着量大,分散更均匀。认为是纳米TiO2粒子表面存在的PBA接枝聚合物抑制了TiO2在棉纤维表面的团聚倾向,提高了TiO2与纤维聚合物的相容性和结合牢度,因而经接枝整理剂整理的棉织物具有良好的抗紫外性能。 相似文献
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抗紫外线纤维及纺织品 总被引:13,自引:3,他引:10
抗紫外线纺织品的加工技术一是在纺丝过程中加入屏蔽剂,二是采用织物表面涂层法。介绍了常用的抗紫外线屏蔽剂和吸收剂,对国产抗紫外线涤纶长丝的物理指标及其织品的抗紫外效果进行了测试分析。结果表明抗紫外线纤维制成的纺织品具有较好的抗紫外线功能。 相似文献
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纳米二氧化钛水溶胶的制备及表征 总被引:1,自引:0,他引:1
纳米二氧化钛可用于织物的后整理,使织物具有抗茵、抗静电、抗紫外线的功能.综合溶胶--凝胶法乙酰丙酮和硝酸的抑制水解作用和微乳法表面活性剂的分散效果制备纳米二氧化钛水溶胶.并用ZETAR激光粒度分析仪进行粒度分析,从而得知本实验制得了粒子大小在37~100 nm之间的TiO2水溶胶. 相似文献
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本研究利用碱木质素作为生物模板诱导剂,通过水热法成功合成了一种具有良好紫外屏蔽性能的木质素/TiO_2复合纳米颗粒。结果表明,木质素/TiO_2复合纳米颗粒具有锐钛矿晶型、良好的纳米粒径和热稳定性。同时,证实了木质素的含氧官能团和TiO_2表面羟基发生类酯化反应,从而使木质素与TiO_2形成包覆嵌顿式结构的复合材料。在此基础上,研究了木质素/TiO_2复合纳米颗粒与纳米纤维素水凝胶制备薄膜材料的抗紫外性能。结果表明,添加质量分数10%的木质素/TiO_2复合纳米颗粒的纳米纤维素薄膜在全紫外线波段(200~400 nm)吸收了约90%的紫外线,表明木质素/TiO_2复合纳米颗粒具有良好的紫外屏蔽能力。 相似文献
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通过对比试验选用聚丙烯酸类阴离子表面活性剂和钛酸酯偶联剂作为联合分散剂对纳米ZnO进行分散处理,使纳米ZnO分散体系稳定性良好,并采用TEM法对分散体系中纳米ZnO微观结构进行了表征。另外,对复合整理前后织物的白度、折皱回复角等性能也进行了测试和比较。研究表明,棉织物经聚丙烯酸钠和钛酸酯偶联剂分散的纳米ZnO溶液整理后,抗紫外线性能显著提高。采用壳聚糖和氨基硅酮作为交联剂,通过复合整理法可使纳米粒子与棉织物牢固结合,抗紫外线性能持久。 相似文献
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Since the suspended TiO2 powder enjoys free contact with UV irradiation in a photoreactor system, it can generally achieve better efficiency than the immobilized TiO2 catalysts. However, the separation and reuse of this catalyst powder from treated water often limit its application in practice. In this study, a new type of TiO2 catalyst called TiO2 microsphere was prepared by a sol-spraying-calcination method, which can easily settle in its aqueous suspensions under gravity. The SEM image of the TiO2 microsphere samples demonstrated that they had an almost spherical shape with a particle size of 30-160 microm, while the XRD analysis indicated that these TiO2 microspheres still had a crystal size of 8.1 nm. Since these TiO2 microspheres had a porous structure with higher specific surface area and pore volume than normal TiO2 powders, they appeared to have strong adsorption ability in its aqueous suspensions. The photocatalytic activity of the TiO2 microspheres was evaluated in the photodegradations of salicylic acid (SA) and sulfosalicylic acid (SSA). The experimental results showed that the reaction rate using the TiO2 microspheres was similar to that using the TiO2 powders in the SA suspensions and even higher than that in the SSA suspensions. Chemical and physical properties of the TiO2 microspheres and powders that are attributed to photoactivity were discussed based on the Langmuir-Hinshelwood kinetic model. The prepared TiO2 microsphere samples were reused in the photooxidation reaction more than 50 times. It was found that there was no significant weakening in their photoactivity and no change in their particle shape. This TiO2 microsphere catalyst can be simply used to conduct an effective photooxidation in its suspension for water and wastewater treatment with ease of recovery from treated water. 相似文献
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采用高分辨透射电镜(HRTEM)、X射线衍射分析(XRD)、粒度分析(DLS)等表征手段对溶胶-凝胶法所制钛溶胶和典型商品粉体TiO2的粒径、晶型和分散状态进行比较和分析,采用紫光-可见分光光度计评估上述TiO2对紫外-可见光的吸收特性,以及对酸性品红6B染料的光催化降解作用。发现,溶胶-凝胶法所制钛溶胶颗粒具有典型的锐钛晶型,且相对于粉体TiO2,其在水分散液中的表观粒径更小、分散程度更高、分散稳定性更好。因而对紫外-可见光具有高的选择性吸引特性(紫外屏蔽/可见光透过),对染料分子具有更强的光催化降解作用。 相似文献
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以钛酸四丁酯为原料,采用溶胶-凝胶法(Sol-Gel)制备纳米级锐钛矿二氧化钛粉末;利用激光粒度仪、AFM、XRD等方法分别对自制纳米TiO2、市售纳米TiO2和工业钛白粉等3种粉体进行表征。以典型的偶氮染料甲基红为目标污染物,测试以上3种粉体对甲基红无水乙醇溶液的降解情况。结果表明,自制产物为锐钛矿型TiO2纳米粉末,其平均粒径约为20nm;当甲基红的质量浓度为20mg/L,3种不同催化剂粉体粉末投加量为0.7g/L时,它们均具有光催化脱色性能。其中加入自制纳米TiO2粉末的甲基红溶液经紫外光照30min后.甲基红脱色率达到98%。 相似文献
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为更好地解决废水污染的问题,针对活性炭纤维(ACF)改性进行了研究。以活性炭纤维为基体,采用溶胶凝胶法制备氧化石墨烯(GO)掺杂二氧化钛(TiO2)的溶液,通过浸渍提拉法实现负载,制备了GO掺杂TiO2的活性炭纤维。借助红外光谱、拉曼光谱、扫描电子显微镜、X射线衍射对其微观结构和表面形态进行表征和分析,并探讨了改性ACF的吸附动力学,以及GO对其可见光光催化降解性能的影响。结果表明:制备的GO-TiO2/ACFs中TiO2主要由锐钛矿相组成,GO的掺杂可抑制TiO2晶体的生长和团聚,TiO2的晶粒尺寸从15.7 nm降为8.1 nm。与TiO2/ACFs相比,少量添加GO的GO-TiO2/ACFs具有更优异的可见光吸附性能,对亚甲基蓝的去除率从65%增至85%,其吸附相比准一级动力学模型更符合准二级动力学模型,属单分子吸附。 相似文献
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纳米TiO2的分散及其在织物上整理工艺的研究 总被引:3,自引:1,他引:3
研究了几种常用分散剂及其复配分散剂对TiO2水悬浮液中纳米粉体的分散稳定性能,得出了高聚物大分子与小分子电解质复配的分散剂对纳米TiO2有较好的分散效果,并对复配分散剂的用量、悬浮液pH值、超声波振荡分散时间对悬浮液稳定性的影响作了研究.确定了试验的分散工艺,分散后的悬浮液静置1h后,分散体系的透过率为4.8%,比不加分散剂体系的透过率下降了51.5%.讨论了3种整理工艺整理织物上纳米TiO2粒子分布的均匀性和抗紫外性能,认为二浸二轧法具有较好的综合效果,既能达到均匀的整理效果,对织物损伤也较小. 相似文献
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比较不同制备方法制得的复合催化剂,由超临界干燥法制备的光催化剂具有粒径小,分散性好,光催化活性高等特点.以TiCl4为原料,采用溶胶凝胶法结合超临界流体干燥法(SCFD)制备了纳米级SnO2TiO2/MMT(蒙脱土)复合光催化剂.采用XRD和TEM对样品进行了表征.结果表明:TiO2以锐钛矿型形式存在,催化剂粒径在13~20 nm.以活性红X-3B溶液、活性橙K-NG和活性紫X-2R为反应模型,对所得催化剂的催化活性进行了评价,降解率分别达到99.9%、99.6%和99.5%,化剂循环利用时仍具有较高的催化活性. 相似文献
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Photocatalytic decomposition of bisphenol A in water using composite TiO2-zeolite sheets prepared by a papermaking technique 总被引:1,自引:0,他引:1
Titanium dioxide (TiO2) photocatalyst and zeolite adsorbent were made into a paper-like composite by a papermaking technique using pulp and ceramic fibers as sheet matrix. The photocatalytic performance for the degradation of bisphenol A (BPA) dissolved in water was investigated under UV irradiation. The TiO2 sheet prepared was easier to handle than the original TiO2 powders in aqueous media. The TiO2 sheet could decompose the BPA under UV irradiation, although at a lower degradation efficiency than the TiO2 suspension. The TiO2-free zeolite sheet could not remove the BPA from water completely because of its adsorption equilibrium. Furthermore, the composite TiO2-zeolite sheets exhibited a higher efficiency for BPA removal than the zeolite-free TiO2 sheets, the efficiency of the former being equivalent to that of the TiO2 suspension. The enhancement in removal efficiency was not attributed to the simple adsorption of BPA on zeolite but rather to the synergistic effect obtained through the combined use of TiO2 photocatalyst and zeolite adsorbent in the paper-like composite sheet, which is believed to accelerate the BPA photodegradation in water. 相似文献