共查询到19条相似文献,搜索用时 359 毫秒
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采用碳纤维负载钴酞菁和苯磺酸钠制备出对活性染料具有高效降解的新型催化功能纤维(CoPc-CF),讨论了温度、pH对CoPc-CF/H2O2体系催化氧化染料性能的影响,并研究了在无机盐(NaCl、Na2SO4)和异丙醇存在下对染料催化降解速率的影响,以及不同活性染料对其催化降解性能的影响。结果表明:提高温度,能明显促进染料的氧化降解;CoPc-CF/H2O2体系在中性和弱碱性中都具有较好的催化降解性能;NaCl和Na2SO4的存在对CoPc-CF/H2O2体系的催化氧化没有影响,而异丙醇的加入有明显地抑制作用;CoPc-CF/H2O2体系对不同活性染料催化氧化速率有很大的影响。 相似文献
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通过将四氨基钴酞菁(CoTAPc)以共价键方式负载到碳纳米纤维(CNF)上,制备得到了碳纳米纤维负载钴酞菁催化剂(CoTAPc-CNF)。研究了CoTAPc-CNF对H2O2的催化分解性能,考察了不同底物浓度、pH和温度对CoTAPc-CNF催化分解H2O2的影响。结果表明:随着底物浓度的增加,CoTAPc-CNF催化分解H2O2的速率加快;在碱性条件下,CoTAPc-CNF具有较好的催化分解H2O2性能;温度越高,CoTAPc-CNF催化分解H2O2越快,并求得该催化反应的活化能为17.917kJ/mol。 相似文献
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将可反应的水溶性钴酞菁(Co-TDTAPc)负载到锦纶纤维上制备了催化功能纤维(F-CoTDTAPc)。利用紫外/可见分光光度法对F-CoTDTAPc/H2O2体系催化氧化酸性红G进行研究,考察了氧化剂质量浓度、pH值、反应温度等对F-CoTDTAPc/H2O2体系氧化降解酸性红G的影响。结果表明,F-CoTDTAPc在H2O2存在下能快速催化氧化酸性红G,并具有较好的原位再生能力。气质联用分析结果表明,酸性红G分子已被氧化降解为可生物降解的脂肪酸类化合物,酸性红G在反应过程中发生了深度氧化降解。 相似文献
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研究染色棉织物CoTSPc/H2O2/TAED催化氧化剥色剂。将四磺酸基钴酞菁(CoTSPc)吸附到活性艳红M-3BE染色后的棉织物上,与氧化剂过氧化氢(H2O2)以及过氧化氢活化剂四乙酰乙二胺(TAED)构成CoTSPc/H2O2/TAED催化氧化剥色体系,对染色棉织物进行剥色实验。研究pH值、CoTSPc浓度、H2O2浓度、TAED浓度、活化时间、剥色温度、剥色时间等因素对剥色效果的影响。通过测试染色棉织物剥色前后的K/S值下降率和断裂强力保留率对剥色效果进行综合评价。同时在最佳剥色条件下对另外4种活性染料染色后的棉织物进行剥色实验。结果表明:CoTSPc/H2O2/TAED催化氧化剥色体系对部分活性染料染色后的棉织物的剥色效果较好,且保留了较为理想的断裂强力。 相似文献
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为解决染料废水污染日益严重的问题,将钴酞菁负载到纤维素纤维上制备非均相催化剂钴酞菁/纤维素纤维(Co-TDTAPc-F),采用紫外可见光谱仪研究该非均相催化剂对6种不同结构活性染料的氧化脱色性能。结果表明:Co-TDTAPc-F对6种染料有一定的富集作用,而Co-TDTAPc-F/H2O2体系能有效地对这6种染料进行氧化脱色,而且反应60 min后染料的脱色率均超过85%,同时发现染料分子结构中含有的磺酸基数量、染料对纤维的直接性均会影响染料的脱色效果。 相似文献
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净化排放废气中的H_2S,实际上是采用苯二酚和酞菁钴为催化剂的氧化催化过程(用碱性苯二酚和碱性酞菁)。这些氧化催化过程,对用相同构造形式的设备和用碳酸钠与碳酸氢钠液作缓冲液吸收H_2S都是一样的。所不同的是在相同的pH值吸收液中,被吸收的H_2S氧化到元素硫的选择性和催化剂的活性。酞菁钴具有较高的催化活性,即使在溶液中含量较少,也能实现 相似文献
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在pH8 的NaH2PO4-Na2HPO4 缓冲溶液中,Co2+ 催化KBrO3 氧化苯甲酸产生强荧光,建立催化氧化荧光法间接测定苯甲酸的新方法。在最优化条件下,苯甲酸质量浓度在5 × 10-7~3 × 10-5g/mL 范围内与荧光强度呈良好的线性关系,方法的检出限为2 × 10-8g/mL。对质量浓度为1 × 10-6g/mL 的苯甲酸标准溶液进行11 次平行测定,得相对标准偏差(RSD)为1.9%。该法应用于食醋及酱油中苯甲酸的测定,回收率为95.7%~101.6%,结果令人满意。 相似文献
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为了解核桃抗氧化功效成分黄酮、总酚、维生素E的贮藏稳定性及其与核桃氧化劣变的相关性,采用Schaal烘箱法对云南核桃进行氧化加速试验,对核桃油的氧化卫生指标和核桃仁功效成分(总酚、黄酮、维生素E)进行了测定和分析研究.结果表明:在前29 d核桃氧化速度较慢,总酚、黄酮、维生素E含量迅速下降,稳定性差;29 d后核桃氧化速度加快,总酚、黄酮、维生素E含量变化较小.核桃仁总酚和黄酮稳定性与核桃油过氧化值呈显著负相关,VE稳定性与过氧化值呈极显著负相关.总酚、黄酮、维生素E对核桃的氧化具有很好的抗氧化保护作用,其中维生素E的抗氧化保护作用最大. 相似文献
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A novel metallophthalocyanine derivative, cobalt tetra (2,4-dichloro-1,3,5-triazine) aminophthalocyanine (Co-TDTAPc), was prepared and immobilized on cellulosic fiber by covalent bond to obtain a supported oxidation catalyst (Co-TDTAPc-F). Co-TDTAPc-F/H202 system based on phase-transfer catalytic oxidation for decomposing dyes, including acid, reactive, and direct dyes, has been investigated thoroughly. Compared to traditional adsorption technologies and advanced oxidation processes (AOPs) for dye treatment, Co-TDTAPc-F/H202 combines the advantages of both and is more efficient and more effective. Azo dyes such as C. I. Acid Red 1 (AR1) can be quickly adsorbed onto/into the fiber from aqueous solution and decomposed in situ simultaneously in the presence of Co-TDTAPc-F and H2O2. It has been found that the reaction process is not affected by the visible light. Furthermore, it turns the negative effect of NaCl normally observed in homogeneous catalysis into positive one. The catalytic reaction can proceed at a wide pH range from acidic to alkaline. In 60 min, more than 98% of AR1 was eliminated at initial pH 2. In 90 min, about 40% of the carbon was found mineralized as determined by the analysis of the residual total organic carbon. The high-performance liquid chromatography result indicated that a substantial amount of the starting AR1 was converted to other organic products, while gas chromatography/mass spectrometry analysis showed the rest of the carbon existed mainly as small molecular biodegradable aliphatic carboxylic compounds such as oxalic acid, malonic acid, and maleic acid, etc. Co-TDTAPc-F is stable, causes no secondary pollution, and remains efficient in repetitive test cycles with no obvious degradation of catalytic activity. 相似文献
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Autoxidation of Methyl Linoleate in Freeze-Dried Model Systems. 4. Effects of Metals and of Histidine in the Absence of Water 总被引:1,自引:0,他引:1
SUMMARY: Autoxidation of methyl linoleate dispersed on filter paper was studied in the dry state in the presence and absence of additives. Oxidation was followed volumetrically and by measuring the increase in conjugated dienes. Evaluation of the rate data indicates that added histidine is antioxidant in the very early stages of the oxidation and becomes prooxidant in the later stages. Increasing the concentration of histidine promoted an earlier appearance of its prooxidant effect. Cobalt chloride and manganese sulfate had a pronounced catalytic effect on the oxidation reaction in the model systems buffered to a high (8.0 and 9.0) but not to a low (4.0) pH. Histidine increased the catalytic activity of manganese but eliminated that of cobalt. Thin-layer chromatography showed that conditions under which histidine increased the prooxidant effect of manganese also resulted in the appearance of some decomposition products of histidine. These decomposition products may have catalytic activity. 相似文献
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Application of spinel-type cobalt chromite as a novel catalyst for combustion of chlorinated organic pollutants 总被引:1,自引:0,他引:1
Various chromium-containing catalysts were tested for the total oxidation of trichloroethylene (TCE) as a model reaction for the catalytic combustion of chlorinated organic pollutants. A spinel-type cobalt chromite (CoCr2O4) among others was proven to be a very promising catalyst showing higher activity and higher CO2 selectivity than traditional alumina supported chromia. Even if both Cr3+ and Cr6+ species were observed on the surface of CoCr2O4, the Cr6+ species was stable under reducing environment. The presence of Cr3+-Cr6+ pair sites and the effect of redox treatments on the activity were investigated to explain the nature of possible active sites for TCE decomposition. Higher selectivity to CO2 of CoCr2O4 was ascribed to the abundance of its Cr3+ species, together with its activity for water gas shift reaction. 相似文献
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Electrochemical reduction of carbon dioxide (CO(2)) to useful chemical materials is of great significance to the virtuous cycle of CO(2). However, some problems such as high overpotential, high applied voltage, and high energy consumption exist in the course of the conventional electrochemical reduction process. This study presents a new CO(2) reduction technique for targeted production of formic acid in a microbial electrolysis cell (MEC) driven by a microbial fuel cell (MFC). The multiwalled carbon nanotubes (MWCNT) and cobalt tetra-amino phthalocyanine (CoTAPc) composite modified electrode was fabricated by the layer-by-layer (LBL) self-assembly technique. The new electrodes significantly decreased the overpotential of CO(2) reduction, and as cathode successfully reduced CO(2) to formic acid (production rate of up to 21.0 ± 0.2 mg·L(-1)·h(-1)) in an MEC driven by a single MFC. Compared with the electrode modified by CoTAPc alone, the MWCNT/CoTAPc composite modified electrode could increase the current and formic acid production rate by approximately 20% and 100%, respectively. The Faraday efficiency for formic acid production depended on the cathode potential. The MWCNT/CoTAPc composite electrode reached the maximum Faraday efficiency at the cathode potential of ca. -0.5 V vs Ag/AgCl. Increasing the number of electrode modification layers favored the current and formic acid production rate. The production of formic acid was stable in the MFC-MEC system after multiple batches of CO(2) electrolysis, and no significant change was observed on the performances of the modified electrode. The coupling of the catalytic electrode and the bioelectrochemical system realized the targeted reduction of CO(2) in the absence of external energy input, providing a new way for CO(2) capture and conversion. 相似文献