Thiol-Functionalized Covalent Organic Frameworks as Thermal History Indictor for Temperature and Time History Monitoring

Various products, including foods and pharmaceuticals, are sensitive to temperature fluctuations. Thus, temperature monitoring during production, transportation, and storage is critical. Facile indicators are required to monitor temperature conditions via color changes in real time. This study aimed to prepare and apply thiol-functionalized covalent organic frameworks (COFs) as a novel indicator for monitoring thermal history and temperature abuse. The COFs underwent obvious color changes from bright yellow to purple after exposure to different temperatures for varying durations. The reaction kinetics are analyzed under isothermal conditions, which reveal that the order of reaction rates is k_−20°C < k_4°C < k_20°C < k_35°C < k_55°C. The activation energy (E_a) of the COFs is calculated using the Arrhenius equation as 50.71 kJ moL⁻¹. The COFs are capable of sensitive color changes and offer a broad temperature tracking range, thereby demonstrating their application potential for the monitoring of temperature and time exposure history during production, transportation, and storage. This excellent performance thermal history indicator also shows promise for expanding the application field of COFs.     

水泥窑余热发电系统用耐磨材料的研制与应用

本研究针对水泥窑余热发电系统的工作条件,根据耐磨材料的损毁机理,采用高铝矾土、煅烧氧化铝粉、黏土、硅微粉等为原料,以磷酸二氢铝为结合剂,以铝酸钙水泥为促硬剂,通过添加掩蔽剂和优化配料工艺,制备了水泥窑余热发电系统用耐磨材料,并对不同处理温度对耐磨材料的性能影响进行了分析。结果表明增强骨料与基质的结合能力有利于耐磨性的提高,磷酸及磷酸盐与氧化铝之间会随着温度的升高生成不同的磷酸铝相,都能够起到结合作用,比采用水泥结合更有利于提高材料在不同温度下的强度和耐磨性。使用结果表明,制备的耐磨材料施工性能优良,凝结硬化时间适当,强度高,抗冲刷性能好,在水泥窑余热发电系统中取得了良好的使用效果。     

Tracing of the 1st IEC Secretariat Assumed by China

Introduction The IEC central office informed in 7/543/AC that the secretariat of TC 7 would be taken over by the Chinese National Committee on January 10, 2003 and affirmed subsequently in 7/544/AC that the secretariat of TC 7 has been taken over by the Chinese National Committee which appointing secretary in Shanghai Electric Cable Research Institute as no objection has been raised by the Standardization Management Board members. It's the first IEC secretariat that assumed by China, with great significance, just as commented by the media that the commitment indicate undoubtedly China is to play a much more active and important role in the world especially after its entry into world trade organization as well as the trend of global economic integration.     

水蒸汽喷射泵系统实用设计软件的开发

本文在Turboc环境下开发了多级蒸汽喷射泵系统的设计软件，该软件包括了压缩比优化分配、单级喷射泵结构尺寸设计和冷凝器的结构尺寸设计等内容，使设计人员能够根据具体的工艺条件，快速地完成多级喷射泵系统的设计，对于提高多级喷射泵系统的工作稳定性、节省能源具有实际意义。     

一种铁氧体移相驱动器专用集成电路

介绍了ＳＡ０１８铁氧体移相驱动器专用集成电路的工作原理，电路设计和实验结果。该电路的内部电路设计有双路激励驱动器，放大器，积分器和双路高速比较器等功能单元。将铁氧体移相器的激励驱动器和相位控制器融于一体，大大减少了铁氧体移相器的外围设计。     

m,m′-二氨基二苯酮与均苯四酸二酐的微波辐射聚合

研究 m,m′-二氨基二苯酮 (m,m′- DABP)与均苯四酸二酐 (PMDA)的缩聚及亚酰化 ,并运用微波辐射和常规加热两种方式对反应进行了比较。考察了微波辐射时间 (功率 )、单体浓度、单体配比和温度等因素对缩聚物的特性粘数、转化率的影响。用红外光谱对亚酰化度进行了表征 ,并用简并四波混频技术首次测量了该缩聚物的三阶光学非线性极化率系数及其响应时间。实验结果表明 ,微波辐射对提高聚合物的特性粘数和转化率都有显著作用 ;合成的缩聚物具有较大的三阶光学非线性极化率系数 (聚酰亚胺的 χ(3) =1.642× 10 -13 esu)和较快的时间响应 (19ps     

The preparation and magnetic properties of Fe-Ag granular solid using a sol-gel method

The Fe-Ag granular metal solid samples with 10% and 30% weight iron have been successfully fabricated using a sol-gel method, which are characterized by X-ray diffraction and transmission electron micrography. The average diameters of iron particles are from about a few nanometres to a few tens of nanometres controlled by the reducing temperature. The evolution of magnetic properties and microstructure during heat treating are described in detail and explained by using the superparamagnetism, single domain and multi domain theories. The magnetic anisotropy of the Fe-Ag granular solid is studied by using the law of approach to saturation. It is found that the magnetic anisotropy constant is in the order of 10⁵ J m^–3 which is higher than the value of the bulk iron and increases with the increase of reducing temperature.     

PbO－Bi_2O_3－B_2O_3－SiO_2系重金属氧化物玻璃的结构与光学性

通过密度、可见光光谱、红外吸收光谱、Ｃｏ－６０辐照损伤试验及荧光光谱的测试，研究了ＰｂＯ－Ｂｉ２Ｏ３－Ｂ２Ｏ３－ＳｉＯ２玻璃系的光学性能与结构．密度最高可达８．４６４ｇ／ｃｍ３其紫外吸收达截止波长随Ｐｂ２＋及Ｂｉ３＋含量升高而红移．玻璃熔化温度低达８５０℃．在ＰｂＯ－Ｂｉ２Ｏ３－Ｂ２Ｏ３系玻璃中加人ＳｉＯ２可使玻璃结构更致密．室温下该系统玻璃在３６０ｎｍ有一个宽的激发峰，能产生４１８ｕｍ及４３８ｕｍ两个弱的发射峰．该系统玻璃的结构是由［ＳｉＯ４］４－、［ＢＯ３］３－、［ＢＯ４］５－、［ＰｂＯ４］６－及［ＢｉＯ６］９－构成．其中部分Ｐｂ２＋及Ｂｉ３＋以网络外体进入玻璃．     

人血清白蛋白对模拟宫腔液中铜的光电响应特性的影响

用动电位伏安法，动电位光电流测量，表面膜的阴极还原和XRD分析等手段研究了铜在含或不含人血清白蛋白的模拟宫腔液（pH=7)中的电化学和光电化学行为，在不含白蛋白的模拟宫腔液中，铜电极表面生成的Cu2O呈n型光响应；一定量白蛋白存在时使Cu2O的光响应从n型转为p型，Cu2O在模拟宫腔液中呈n型光响应可归因于氯离子对Cu2O的掺杂，白蛋白排斥氯离子对Cu2O的掺杂，使其光响应从n型转为p型。     

电感耦合等离子体原子发射光谱法测定云南某矿山锑矿选矿流程样品中锑

锑在现代工业体系中占有重要地位,快速准确测定锑矿中锑含量对锑矿的采选具有重要指导意义。云南某矿山锑矿以萤石为主要伴生矿,现有的盐酸、硝酸、氢氟酸和高氯酸混酸体系无法彻底分解样品,而采用碱熔处理流程长且引入大量基体,均无法满足准确快速测定的要求。选择硫酸-氢氟酸混酸体系分解样品,再用酒石酸-盐酸混合溶液加热浸取,锑完全溶解于溶液中,选择Sb 206.833{463}nm为分析谱线,使用电感耦合等离子体原子发射光谱法(ICP-AES)测定锑。结果表明,锑的质量浓度在5.0～80 μg/mL范围内与其发射强度呈良好的线性关系,校准曲线线性相关系数r=0.999 8;方法的检出限为0.012 μg/mL。按照实验方法对锑矿石成分分析标准物质和锑矿选矿流程样品中锑进行测定,结果的相对标准偏差(RSD,n=5)为0.71%～5.7%;标准物质的认定值和测定值相一致;锑矿选矿流程样品中锑的加标回收率为97%～102%,满足国家地质矿产行业标准DZ/T 0130—2006的要求。