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1.
《Ceramics International》2022,48(13):18151-18156
The electrical properties and domain reversal in BiFeO3 ferroelectric films were studied using sandwiched heterostructures and piezoresponse force microscopy. A robust polarization state was observed, combined with a switchable domain pattern and a remanent polarization of approximately 100 μC cm?2. In addition, domain reversal was explored using scanning probe microscopy. The results show that dipoles could be reversed along the direction of the electric field under a negative tip bias, leading to carrier gathering near the domain walls. The enhanced conductivity near the domain walls was owing to the discontinuous polarization boundary conditions. In addition, typical diode-like current transport properties are sensitive to various temperature conditions, which is attributed to the Schottky barriers at the contact interface. These findings extend the current understanding of domain texture reversal in ferroelectric films and shed light on their potential applications for future ferroelectric random-access memory operations over a wide temperature range.  相似文献   
2.
In this study the effects of high temperature and moisture on the impact damage resistance and mechanical strength of Nextel 610/alumina silicate ceramic matrix composites were experimentally evaluated. Composite laminates were exposed to either a 1050°C isothermal furnace-based environment for 30 consecutive days at 6 h a day, or 95% relative humidity environment for 13 consecutive days at 67°C. Low velocity impact, tensile and short beam strength tests were performed on both ambient and environmentally conditioned laminates and damage was characterized using a combination of non-destructive and destructive techniques. High temperature and humidity environmental exposure adversely affected the impact resistance of the composite laminates. For all the environments, planar internal damage area was greater than the back side dent area, which in turn was greater than the impactor side dent area. Evidence of environmental embrittlement through a stiffer tensile response was noted for the high temperature exposed laminates while the short beam strength tests showed greater propensity for interlaminar shear failure in the moisture exposed laminates. Destructive evaluations exposed larger, more pronounced delaminations in the environmentally conditioned laminates in comparison to the ambient ones. External damage metrics of the impactor side dent depth and area directly influenced the post-impact tensile strength of the laminates while no such trend between internal damage area and residual strength could be ascertained.  相似文献   
3.
ZnO rice like nonarchitects are grafted on the graphene carbon core via a rapid microwave synthesis route. The prepared grafted systems are characterized via XRD, SEM, RAMAN, and XPS to examined the structural and morphological parameters. Zinc oxide grafted graphene sheets (ZnO-G) are further doped in β-phase of polyvinylidene fluoride (PVDF) to prepare the polymer nanocomposites (PNCs) via mixed solvent approach (THF/DMF). β-phase confirmation of PVDF PNCs is done by FTIR studies. It is observed that ZnO-G filler enhances the β-phase content in the PNCs. Non-doped PVDF and PNCs are further studied for rheological behavior under the shear rate of 1–100 s−1. Doping of ZnO-G dopant to the PVDF matrix changes its discontinuous shear thickening (DST) behavior to continues shear thickening behavior (CST). Hydrocluster formation and their interaction with the dopant could be the reason for this striking DST to CST behavioral change. Strain amplitude sweep (10−3% -10%) oscillatory test reveals that the PNCs shows extended linear viscoelastic region with high elastic modulus and lower viscous modulus. Effective shear thickening behavior and strong elastic strength of these PNCs present their candidature for various fields including mechanical and soft body armor applications.  相似文献   
4.
杨立宁  郑东昊  王立新  杨光 《化工进展》2022,41(11):5961-5967
以具有轻质高强优异性能的蜻蜓翅脉结构为设计灵感,在分析翅脉网格结构抗冲击原理的基础上,设计了传统和仿生两类对比结构。采用熔融挤出3D打印机成功制备了具有不同结构的连续碳纤维增强聚乳酸复合材料试样,并对不同结构复合材料试样的拉伸性能和抗冲击性能进行了测试和对比分析。研究分析结果表明:由于拉伸力方向上的连续碳纤维含量相对较少,限制了仿生结构复合材料抗拉强度的提高,但仿生结构的平均抗拉强度为传统结构的1.18倍;当仿生结构复合材料试样受到冲击力时,其内部六边形结构的连接角度会发生变化,从而极大消耗冲击能量,同时具有六边形网格结构的连续碳纤维可以有效阻碍裂纹的扩展,因此仿生结构的平均冲击韧性可以达到传统结构的2.46倍;仿生蜻蜓翅脉结构可以显著提高增材制造复合材料的综合力学性能,且对于抗冲击性能的提高具体突出效果。连续碳纤维增强树脂基复合材料的有效可行的仿生蜻蜓翅脉结构设计和增材制造,可极大扩展其在高冲击载荷领域中的相应应用。  相似文献   
5.
为研究钢管套筒灌浆连接轴向受拉破坏过程及破坏机理,试验中设计了16组48个钢管套筒灌浆连接试件,试件采用钢板代替圆钢管,并进行静载试验。分析了灌浆料裂缝扩展过程、荷载-相对位移曲线,并对抗剪键高距比、灌浆料厚度、侧向力等因素对破坏过程及承载力的影响进行分析。结果表明:对于不设置抗剪键的套筒灌浆连接试件,斜裂缝随机产生,裂缝分布不均匀;对于设置抗剪键的套筒灌浆连接试件,裂缝首先出现在底部抗剪键位置处,与水平方向夹角约为30°,随后在中部和上部抗剪键位置处分别出现斜裂缝。由于每个抗剪键上荷载分担并不均匀,与抗剪键接触的灌浆料逐渐达到极限压应力,达到极限状态时,承载力全部由抗剪键间的机械咬合力承担,在连接承载力中,可忽略摩擦力和胶结力作用。随着抗剪键高距比h/s增大,各试件初始剪切刚度相差不大,承载力增大,但增幅逐渐减小,建议抗剪键高距比0.06g/s>0.3,同时需要满足灌浆料灌注的施工要求。  相似文献   
6.
This paper presents the fresh, mechanical, and durability performance, of a structural concrete mix classified as C-1, by the Canadian Standards Association (CSA) made with controlled quality Recycled Concrete Aggregate (RCA). Five mixes with water-to-cementing material (w/cm) ratio of 0.40 were produced with various RCA contents and tested against two 0% RCA control mixes made with General Use (GU) cement, and General Use Limestone cement (GUL). The RCA contents in the mixes were 10%, 20%, and 30% by coarse aggregate volume replacement, as well as 10% and 20% fine and coarse (granular) aggregate volume replacement. All evaluated mixes met the specifications from the CSA for fresh, mechanical, and durability properties. The coarse RCA mixes performed better than the granular RCA mixes in terms of flexural and splitting tensile strengths, linear drying shrinkage, water sorptivity, and rapid chloride-ion permeability, where the test results were significantly affected by the ultra fines present in the granular RCA.  相似文献   
7.
ABSTRACT

This study investigates the effects of strain, strain rates, and forming directions (RD-rolling direction, TD-transverse direction, and ND-normal direction) on adiabatic shear, via dynamic impact compression tests using the Split Hopkinson Pressure Bar (SHPB) apparatus. A modified Johnson-Cook (J-C) constitutive model is proposed, which used to analyse the influence of the constitutive parameters on the sensitivity of adiabatic shear, employing a finite element software. The different sensitivities of adiabatic shear under different directions are explained by combining microscopic analysis and results from mechanical responses. The results show that the sensitivity of adiabatic shear can be related to the time of stress collapse in the following trend: ND?>?TD?>?RD; the sensitivities of these constitutive parameters on adiabatic shear are calculated and compared.  相似文献   
8.
This paper presents an analytical solution to the non-uniform pressure on thick-walled cylinder. The formulation is based on the linear elasticity theory (plain strain) and stress function method. As an example, the proposed solution is used to model the stress distribution due to non-uniform steel reinforcement corrosion in concrete. The model is formulated considering different scenarios of corrosion pressure distribution. It is validated against the finite element model for different cases of non-uniform pressure distributions. The results show that the corrosion-induced cracks are likely to start just beyond the anodic zone. This is confirmed by the experimental tests on concrete cylinder exposed to non-uniform accelerated corrosion of steel reinforcement. The model can be effectively used to calculate the distribution of corrosion-induced stresses in concrete.  相似文献   
9.
《Ceramics International》2022,48(18):26233-26247
A new type of 3D-printable ‘one-part’ geopolymer was synthesized with fly ash (FA), granulated blast furnace slag (GBFS), steel slag (SS) and flue gas desulfurization gypsum (FGD). The effects of SS content (0–40%) on the rheological properties, 3D-printability, mechanical anisotropy and reaction kinetics of geopolymer were investigated. The yield stress and plastic viscosity monotonically decreased with the increasing SS content. Contrarily, the geopolymer with 10% of SS presented better extrudability, buildability and mechanical strength than those with 0, 20%, 30% and 40% of SS. This was mainly attributed to the conflicting influence of SS on geopolymerization, of which the OH? produced by hydration of SS raised the alkalinity of the reaction system and accelerated the dissolution of SiO44? and AlO45?, while the low reactivity prohibited the following polymerization process. Furthermore, the 3D-printed geopolymer presented more compact microstructure and less mechanical anisotropy thanks to the crosslinking of morphologically complementary products, including N(C)-A-S-H, C–S–H, AFt and CH, formed via synergistic reaction of FA-GBFS-SS-FGD system.  相似文献   
10.
本文介绍了混凝土结构的压电体波和表面波检测的主要进展,对两种压电声波检测的优缺点进行了总结。体波检测设备一般埋入混凝土内部,需要选择合理的检测部位,检测结果较为精确;声表面波检测无需选择特定的部位,但是检测深度有限。在实际检测工作过程中,可以联合两种方法相互验证。  相似文献   
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