全文获取类型
收费全文 | 7827篇 |
免费 | 1040篇 |
国内免费 | 803篇 |
专业分类
电工技术 | 1656篇 |
综合类 | 743篇 |
化学工业 | 1201篇 |
金属工艺 | 435篇 |
机械仪表 | 248篇 |
建筑科学 | 386篇 |
矿业工程 | 129篇 |
能源动力 | 341篇 |
轻工业 | 660篇 |
水利工程 | 155篇 |
石油天然气 | 288篇 |
武器工业 | 39篇 |
无线电 | 1000篇 |
一般工业技术 | 715篇 |
冶金工业 | 262篇 |
原子能技术 | 65篇 |
自动化技术 | 1347篇 |
出版年
2024年 | 42篇 |
2023年 | 186篇 |
2022年 | 244篇 |
2021年 | 267篇 |
2020年 | 318篇 |
2019年 | 275篇 |
2018年 | 232篇 |
2017年 | 306篇 |
2016年 | 347篇 |
2015年 | 349篇 |
2014年 | 470篇 |
2013年 | 521篇 |
2012年 | 630篇 |
2011年 | 613篇 |
2010年 | 408篇 |
2009年 | 465篇 |
2008年 | 454篇 |
2007年 | 493篇 |
2006年 | 439篇 |
2005年 | 394篇 |
2004年 | 353篇 |
2003年 | 246篇 |
2002年 | 250篇 |
2001年 | 251篇 |
2000年 | 176篇 |
1999年 | 152篇 |
1998年 | 112篇 |
1997年 | 87篇 |
1996年 | 94篇 |
1995年 | 99篇 |
1994年 | 77篇 |
1993年 | 76篇 |
1992年 | 50篇 |
1991年 | 36篇 |
1990年 | 35篇 |
1989年 | 25篇 |
1988年 | 13篇 |
1987年 | 10篇 |
1986年 | 10篇 |
1985年 | 11篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 9篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1965年 | 2篇 |
1960年 | 2篇 |
排序方式: 共有9670条查询结果,搜索用时 15 毫秒
1.
Jiajia Suo Bowen Yang Edoardo Mosconi Hyeon-Seo Choi YeonJu Kim Shaik M. Zakeeruddin Filippo De Angelis Michael Grätzel Hui-Seon Kim Anders Hagfeldt 《Advanced functional materials》2021,31(34):2102902
Surface passivation treatment is a widely used strategy to resolve trap-mediated nonradiative recombination toward high-efficiency metal-halide perovskite photovoltaics. However, a lack of passivation with mixture treatment has been investigated, as well as an in-depth understanding of its passivation mechanism. Here, a systematic study on a mixed-salt passivation strategy of formamidinium bromide (FABr) coupled with different F-substituted alkyl lengths of ammonium iodide is demonstrated. It is obtained better device performance with decreasing chain length of the F-substituted alkyl ammonium iodide in the presence of FABr. Moreover, they unraveled a synergistic passivation mechanism of the mixed-salt treatment through surface reconstruction engineering, where FABr dominates the reformation of the perovskite surface via reacting with the excess PbI2. Meanwhile, ammonium iodide passivates the perovskite grain boundaries both on the surface and top perovskite bulk through penetration. This synergistic passivation engineer results in a high-quality perovskite surface with fewer defects and suppressed ion migration, leading to a champion efficiency of 23.5% with mixed-salt treatment. In addition, the introduction of the moisture resisted F-substituted groups presents a more hydrophobic perovskite surface, thus enabling the decorated devices with excellent long-term stability under a high humid atmosphere as well as operational conditions. 相似文献
2.
Dr. Ying Wang Prof. Dr. Andrew Ewing 《Chembiochem : a European journal of chemical biology》2021,22(5):807-813
Exocytosis plays an essential role in the communication between cells in the nervous system. Understanding the regulation of neurotransmitter release during exocytosis and the amount of neurotransmitter content that is stored in vesicles is of importance, as it provides fundamental insights to understand how the brain works and how neurons elicit a certain behavior. In this minireview, we summarize recent progress in amperometric measurements for monitoring exocytosis in single cells and electrochemical cytometry measurements of vesicular neurotransmitter content in individual vesicles. Important steps have increased our understanding of the different mechanisms of exocytosis. Increasing evidence is firmly establishing that partial release is the primary mechanism of release in multiple cell types. 相似文献
3.
4.
Eui Dae Jung Amit Kumar Harit Do Hui Kim Chung Hyeon Jang Jong Hyun Park Shinuk Cho Myoung Hoon Song Han Young Woo 《Advanced materials (Deerfield Beach, Fla.)》2020,32(30):2002333
A series of anionic conjugated polyelectrolytes (CPEs) is synthesized based on poly(fluorene-co-phenylene) by varying the side-chain ionic density from two to six per repeat units (MPS2-TMA, MPS4-TMA, and MPS6-TMA). The effect of MPS2, 4, 6-TMA as interlayers on top of a hole-extraction layer of poly(bis(4-phenyl)-2,4,6-trimethylphenylamine (PTAA) is investigated in inverted perovskite solar cells (PeSCs). Owing to the improved wettability of perovskites on hydrophobic PTAA with the CPEs, the PeSCs with CPE interlayers demonstrate a significantly enhanced device performance, with negligible device-to-device dependence relative to the reference PeSC without CPEs. By increasing the ionic density in the MPS-TMA interlayers, the wetting, interfacial defect passivation, and crystal growth of the perovskites are significantly improved without increasing the series resistance of the PeSCs. In particular, the open-circuit voltage increases from 1.06 V for the PeSC with MPS2-TMA to 1.11 V for the PeSC with MPS6-TMA. The trap densities of the PeSCs with MPS2,4,6-TMA are further analyzed using frequency-dependent capacitance measurements. Finally, a large-area (1 cm2) PeSC is successfully fabricated with MPS6-TMA, showing a power conversion efficiency of 18.38% with negligible hysteresis and a stable power output under light soaking for 60 s. 相似文献
5.
Polarity Effect and Electromagnetic Radiation of Partial Discharge Accompanying Growth of Electrical Tree
下载免费PDF全文
![点击此处可从《Electrical Engineering in Japan》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Tatsuya Mutakamihigashi Yoshito Kuroishi Hideki Ueno 《Electrical Engineering in Japan》2015,192(3):19-26
We have investigated the characteristics of radiated electromagnetic (EM) waves from positive and negative partial discharges (PD) in epoxy resin and cross‐linked polyethylene. We found that there is a correlation among the EM level from PD, the positive PD current, and electrical trees. Therefore, the growth of an electrical tree produces a lot of positive PD. We have also investigated the characteristics of the frequency region of EM waves from PD in air, insulating oil, and liquid epoxy in addition to the above insulators. EM waves were detected in the frequency region of 40 MHz to 300 MHz from positive and negative PD in epoxy resin and cross‐linked polyethylene. EM waves were also detected in the frequency region of 40 MHz to 150 MHz from positive and negative PD in air. In the case of insulating oil and liquid epoxy, EM waves were detected in the frequency regions of 40 MHz to 150 MHz from positive PD, and 40 MHz to 250 MHz from negative PD. The frequency region differed depending on the material and the discharge polarity. Our investigation indicates that the cause is differences in electric field strength at the time of PD occurrence. 相似文献
6.
Behavior of Magnesium‐Alloys for Automotive Applications under Mechanical and Environmental Loading: Influence of Passivating Films and Mechanisms of Local Breakdown To assure an efficient design of components under cyclic loading, all available data concerning fatigue have to be observed. Therefore the influences of manufacturing on the material condition, the mechanical loads and environmental effects have to be analysed. Magnesium‐alloys are of special interest for lightweight applications because of their excellent strength‐density ratio. The corrosion resistance of magnesium‐alloys depends on the same factors that are critical to other metals. The alloys have a good stability to atmospheric exposure and a good resistance to attack by alkali, chromic and hydrofluoric acids. However, because of the electrochemical activity of magnesium, the relative importance of some factors is greatly amplified. The nature and composition of passive films formed on magnesium‐alloys depend on the prevailing conditions, viz. alloy‐composition, passivation potential, pH, electrolyte composition and temperature. Passive films may be damaged by local breakdown. Because of this, magnesium‐alloys suffer a degradation of their properties when exposed to an aqueous environment. The main topic of the present investigations is the verification of mechanisms of the local breakdown of the protecting film. At least two mechanisms are possible for this localization: mechanical breakdown by slip steps and electrochemical breakdown (for e.g. by the effects of chloride ions). Corrosion and passivation of different high purity alloys have been studied in different solutions (neutral, alkaline with specific anions and cations) using electrochemical techniques. The diecasted alloys were tested as produced and machined. The results clarified that depending on alloy/material and surface condition/corrosion environment different mechanisms for electrochemical breakdown of the protecting films are possible. Hence fatigue life under environmental loading is influenced by surface and testing conditions. 相似文献
7.
针对车用柴油酸度等性质测定过程繁琐,采用衰减全反射样品池测定车用柴油的红外光谱,用偏最小二乘法(PLS)建立红外光谱测定车用柴油酸度、密度、闪点和凝点的4个校正模型,验证标准误差分别为0.46 mg/(100 mL),0.77kg/m3,2.60 ℃,2.77 ℃,该方法符合标准方法再现性要求。与标准方法相比,该方法具有无需预处理、操作简单、测量快速、重复性好等优点。 相似文献
8.
基于PC机群的大地电磁Occam反演并行计算研究 总被引:4,自引:0,他引:4
Occam反演以其稳定收敛和不依赖于初始模型的特性被广泛应用于大地电磁数据的处理,但偏导数矩阵的计算和拉格朗日乘子的求取导致大量的模型正演,使得反演速度较低。为此,研究了用基于PC机群的并行计算来解决这一问题的方法。首先对Occam反演方法进行了阐述;然后,分析了反演方法中各计算耗费的时间,提出对约占计算量90%的偏导数和拉格朗日乘子进行并行计算的思想,即偏导数计算采用频点计算一级的大粒度并行,拉格朗日乘子扫描和一维搜索分别采用弘值计算一级的大粒度并行和频点计算一级的小粒度并行;给出了并行计算的实现方法,即在PC机群上,利用主一从编程模式实现Occam反演的整体并行计算。在计算中,采用任务组合方式,减少了通信量,较好地实现了负载均衡。在4节点PC机群上,对应于拉格朗日乘子的扫描和一维搜索方式,整体加速比分别达到3.36和2.83。 相似文献
9.
本文提出了属性相关表这样一种新的概念,定义了相应的运算并研究了它的有关性质及定理,在此基础上提出了用属性相关表求关系模式全部主属性的等级,并给出了用主属性来组合关系模式全部候选关键字的算法,上述算法的时间复杂度均为O(n^2)。 相似文献
10.