Characterization of barium titanate reinforced acrylonitrile butadiene rubber composites for flexible electronic applications: influences of barium titanate content

The aim of this study was to develop high dielectric constant flexible polymers with a highly efficient and cost‐effective approach using acrylonitrile butadiene rubber (NBR) as the polymer matrix and barium titanate (BT) as the high dielectric constant filler. The BT powder was synthesized with a solid‐state reaction and was characterized using a particle size analyzer, XRD, SEM and Fourier transform infrared spectroscopy. NBR/BT composites were fabricated using an internal mixer with various BT loadings up to 160 phr. The influence of BT loading on the cure characteristics and mechanical, dynamic mechanical, thermal, dielectric and morphological properties was determined. The incorporation of BT in the NBR matrix shortened scorch time and increased delta torque. The mechanical properties, thermal stability and dielectric constant were greatly improved and increased with BT loading. The results suggest that the reinforcement effect was achieved due to strong hydrogen bonding or polar–polar interactions between NBR matrix and BT filler. This is further corroborated by the good dispersion of BT filler in the NBR matrix observed with SEM imaging. These findings can be applied to produce high‐performance dielectric elastomers. © 2020 Society of Industrial Chemistry     

Theoretical study on a kind of cyclization mechanism of boron trichloride and hexamethyldisilazane to form the borazine ring for SiBCN ceramics precursor

Borazine rings act as a pivotal part in siliconboroncarbonitride ceramics (SiBCN) for high-temperature stability and great resistance to crystallization. A detailed investigation of the ring formation mechanism will guide the design and synthesis of SiBCN to meet application requirements under extreme conditions. Boron trichloride (BCl₃) and hexamethyldisilazane (HN(SiMe₃)₂) are common raw materials for the synthesis of precursors for SiBCN. In this paper, quantum chemical calculation was used to study the cyclization reaction mechanism between BCl₃ and HN(SiMe₃)₂ to form trichloroborazine (TCBZ) at the MP2/6-31G (d,p) level of theory. We discussed the structure properties, reaction pathways, energy barriers, reaction rates, and other aspects in detail. The results show that BCl₃ and HN(SiMe₃)₂ alternately participate in the reaction process, accompanied by the release of trimethylchlorosilane (TMCS), and that the entire reaction shows an absolute advantage in terms of energy. In the Step by step reaction, lower reaction barriers are formed due to the introduction of BCl₃ with more heat released compared to that for the introduction of HN(SiMe₃)₂. The final single-molecule cyclization and TMCS elimination steps are found to be faster compared to all previous bimolecular reactions.     

破损水文观测孔涌水封堵技术在高河矿的应用

针对高河矿奥灰水文观测孔空水管锈蚀断裂漏水严重的问题,分析了存在的问题,制定了钻孔涌水封堵技术方案及相应的注浆施工工艺,并进行了为期7天的井下试验。封堵注浆压力达到6 MPa,使用注浆水泥50 t,水泥浆液凝固良好,注浆阀门打开后无出水现象。     

脱硫胶粉在乳化改性沥青中的应用

考察了不同规格胶粉及不同脱硫程度的脱硫胶粉对橡胶改性乳化沥青性能的影响,结果表明,采用100目胶粉即可制备出橡胶改性乳化沥青,但乳化沥青的性能较差;采用活化度为50%左右的100目脱硫胶粉制备乳化沥青时,脱硫胶粉的用量相比于胶粉可大幅提高;在通过外掺100目50%左右活化度的脱硫胶粉(质量分数15%,以沥青计,下同)和质量分数2%的苯乙烯-丁二烯-苯乙烯嵌段共聚物改性的乳化沥青中添加质量分数1%的丁苯胶乳,所制备橡胶改性乳化沥青无筛上剩余物,5 d储存稳定性为2.9%,蒸发残留物的25℃针入度、软化点和5℃延度分别为55 (0.1 mm)、64.5℃和22.5 cm,能够满足乳化改性沥青的技术指标要求。     

增材制造技术在超高膨胀封隔器中的应用

石油和天然气行业不断关注增材制造技术在航空航天和汽车行业的应用发展。研发了利用增材制造技术的超高膨胀封隔器,该封隔器的支承环系统由增材制造。增材制造设计大幅减少了支承系统的构件数量,同时显著提高了膨胀能力和额定压力。密封元件系统与增材制造支承环安装在一起,提供了极端膨胀比、零挤压间隙和对不规则孔的良好适应性。分析和测试结果表明:直径膨胀比高达111%,与常规封隔器相比,提高50%以上; 至少涵盖5种线重的套管(外径相同); 在148.89 ℃的温度下,密封元件能够保持压力68.95 MPa。介绍了增材制造技术、增材制造支承环概念、增材制造材料力学性能、密封元件系统优化和测试情况,以期给我国的完井作业提供借鉴。     

自愈合橡胶材料研究进展

具有自感知、自诊断、自愈合功能的智能聚合物材料是高分子科学领域的前沿材料之一。介绍了自愈合橡胶材料的自愈合机理,综述了自愈合橡胶材料的分类、特性和发展概况,展望了其应用及发展前景。     

基于压缩机-支架系统的异常噪声研究

针对某乘用车发动机转速在1 573 r/min，压缩机开启时车内噪声异常的问题，对样车进行试验分析与诊断，对压缩机-支架系统进行仿真分析，提出改进方案并验证改进效果。利用LMS声振信号采集系统采集振动噪声数据，采用频谱分析、阶次追踪等方法，并结合压缩机-支架系统模态仿真结果，确定车内异常噪声是压缩机轴频21阶与压缩机-支架系统3阶模态频率接近发生共振造成的。通过优化支架结构来提高压缩机-支架系统3阶模态频率以此来避免共振，并换装橡胶驱动盘缓和压缩机输入扭矩波动。将改进结构进行整车试验，结果表明：匀速工况空调开启时问题转速下，车内噪声降低了2.5 dB(A)；匀加速工况空调开启时发动机转速1 500~1 650 r/min区间，车内噪声无峰值，其余转速空调开启时改进前/后车内噪声基本不变，噪声波动趋势平缓。     

不同硬度PTMG型CPUE与硫化橡胶的性能对比研究

通过改变硬段含量、扩链系数等制备了几种不同硬度的四氢呋喃均聚醚(PTMG)浇注型聚氨酯弹性体(CPUE),讨论了PTMG型CPUE与硫化橡胶(VR)的物理机械性能、拉伸应力应变行为以及动态力学性能的区别。结果表明,随CPUE硬度的提高,材料的刚性增强,力学性能是低硬度VR的数倍。通过对CPUE硬度的调节,可以使之兼具聚氨酯和橡胶的优良性能。在玻璃态温度下CPUE的储能模量随硬度的减小而降低,但都高于VR,而且CPUE的硬度越大,二者相差越大,温度越低,相差也越大;在室温以上温度范围内,CPUE具有比VR更小的力学损耗。