广东省伴生放射性矿资源利用过程辐射水平调查

为加强伴生放射性矿物资源开发利过程中放射性环境管理 ,防治放射性污染 ,对广东省几个大型伴生矿(包括稀土矿、钽铌矿和铅锌矿 )资源利用 (开采、冶炼、加工 )过程中天然放射性核素的污染现状进行了调查。调查结果表明 :稀土矿中独居石 ,天然放射性核素含量最高 ,2 3 8U、2 3 2 Th、2 2 6Ra的含量分别为 3.5 1× 1 0 4、1 .74× 1 0 5、4 .8×1 0 4Bq/kg,其冶炼废渣中核素的含量分别为 5 .1 0× 1 0 5、6 .38× 1 0 6、1 .5 2× 1 0 6Bq/kg。稀土选冶厂周围陆地环境 γ射线的空气吸收剂量率比一般地区的高。     

Evaluation of Handheld Radionuclide Identifiers

Characterization of commercially available instruments for measurement and identification of unknown radionuclides was carried out in support of the development and testing of the American National Standards Institute (ANSI) standard, N42.34, “Performance Criteria for Hand-held Instruments for the Detection and Identification of Radionuclides.” Measurements were based on the performance of the devices, i.e., the capability of the detectors to ensure a correct radionuclide identification in a given time interval for various radioactive sources.     

用αβ谱仪测量人工αβ放射性气溶胶体积活度的试验研究

本文介绍了用αβ谱仪系统同时测量αβ谱、实现Ｒｎ／Ｔｈ子体补偿、确定超铀α核素气溶胶体积活度及人工放射性气溶胶总β体积活度的技术途径。利用ＲａＡ、ＲａＣ′ａ峰的二段时间计数可确定空气中ＲａＡ、ＲａＢ、ＲａＣ的气溶胶体积活度，相应的，也能给出ＲａＢ、ＲａＣ对总β计数的贡献。根据一般环境条件下的平衡比，用ＴｈＣ′的。计数修正Ｔｈ子体对αβ测量的影响。￣［２３９］ｐｕ或／和￣［２４１］Ａｍ人工核素的α计数，可通过两段时间分别扣除ＲａＡ、ＲａＣ′拖尾的方法确定；β计数分别扣除Ｒｎ／Ｔｈ子体β贡献即可确定。在本文规定的测量条件下，对室内天然Ｒｎ子体水平在１５Ｂｑ／ｍ￣３以下，超铀α核素气溶胶体积活度的测量下限可达到０．１Ｂｑ／ｍ￣３；即使在７５Ｂｑ／ｍ￣３环境下，人工核素总β的测量下限也可达ｌＢｑ／ｍ￣３以下。     

Soil-to-Plant Transfer Factors of Stable Elements and Naturally Occurring Radionuclides (1) Upland Field Crops Collected in Japan

In long-term dose assessment models for radioactive waste disposal, an important exposure pathway to humans is via ingestion of contaminated foods. In order to obtain soil-to-plant transfer factors (TFs) of radionuclides under equilibrium conditions, naturally existing elements were measured as analogues of radionuclides. Crops grown in upland fields and associated soil samples were collected from 62 sampling sites throughout Japan. The total concentrations of 52 elements in the crops and 54 elements in the soil samples were measured. The TFs of 40 elements (Li, Na, Mg, Al, Si, P, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Rb, Sr, Y, Mo, Cd, Sn, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Pb, Th and U) were calculated on a dry weight basis.

Among all the TF data, K showed the highest TF with a geometric mean (GM) of 2.1, followed by P. The GMs of TFs for rare earth elements, Th and U were on the order of 10^?4. Most of the TF-GMs for green vegetables were higher than GMs of all crops for the elements. The obtained TFs of some elements for green vegetables and potatoes were compared with those in the technical report series-364 (TRS-364) compiled by IAEA in 1994. The TF-GMs were usually lower than the best estimates (expected values) listed in TRS-364; however, the GMs of TF for La and TF for Th observed for potatoes were slightly higher than the expected values.     

Uptake of Radionuclides onto Suspended Particulate Matter in Coastal Water

Distribution coefficients K _ds of several radionuclides on suspended particulate matter (SPM) have been determined with laboratory batch experiments using samples collected in the Kinki district, Japan. Most SPM in coastal water was retained on the initial filter of four sequential filtering stages (20, 5, 1 and 0.45 μm pore size), maximum K _d also being found for the SPM retained in this first stage. When the filtrations were not performed in series, however, but were conducted from the same tracer solution in parallel, the K _d values were identical for the smaller filter sizes (5, 1 and 0.45 μm) and were greater, by ca. 150% than those derived from the 20 μm filter. The degree of association of the radionuclides with SPM was ⁸⁵Sr<¹³⁷Cs<⁶⁵Zn<⁵⁴Mn<⁶⁰Co. The particulate radioactivity fraction of the SPM in coastal water was estimated at most 0.1 for radionuclides with K _d of ca. 5 X 10⁴ ml/g, i.e. which are highly associated with the SPM (2 mg/l). The scavenging effect by SPM seemed to be, however, considerable, the settling velocity being estimated at ca. 25 cm/day for particles of the Stoke's diameter of 30 μm.     

Analytical Models for Migration of Radionuclides in Geologic Sorbing Media

In safety evaluation of nuclear waste repository systems, the analysis on migration of radionuclides in geologic media is important. In previous analytical models called Band- Release, Step-Release and Impulse-Release for decay chains, nuclide-specific release rate and time-dependence of release rate can not be taken into consideration. In this paper, two new release models are proposed. In Preferential-Release model, both of nuclide-specific release rate and time-dependence of leach are taken into account. Exponential-Release model is a special case of Preferential-Release model, in which no preferentiality in leach is assumed. The obtained analytical solutions for these new models are applicable even to four or more member decay chains and are as simple as those for the previous models.

As an example of the application of the new models, the discharge rates of the four nuclides in the decay chain of ²³⁸Pu→²³⁴U→ ²³⁰Th→²³⁶Ra→ into a surface water body are calculated as a function of time after the start of leach and path length from the repository. By using the result, heavy hazard due to ²³⁸Pu at short distance and ²²⁶Ra at long distance are also discussed briefly.     

花岗岩单裂隙中核素迁移的研究

研制了花岗岩单裂隙扩散实验装置,用＾１２５Ｉ、＾１３４Ｃｓ进行了核素扩散实验,求得扩散系数并测定了裂隙表面的放射性活度分布。     

37Ar用于视察地下核试验的尝试

对地下核爆漏气体中放射性核素＾３７Ａｒ进行取样,提纯及测量并研究了泄漏速率随时间位置的变化规律。结果表明：监测土壤中＾３７Ａｒ的含量可有效地核查地下核试验。     

靶向CD93分子探针制备及其生物学实验研究

CD93分子作为一种新型新生血管生成激活剂,有可能成为肿瘤监测的重要分子靶点,因此制备125I标记抗CD93单抗(125I-anti-CD93 mAb),研究其在荷瘤鼠体内生物学分布及磷屏显像特点,探讨其对A549肺癌靶向性及CD93阳性肿瘤监测的可行性。本文制备125I-anti-CD93 mAb及125I-IgG并进行鉴定;建立A549肺癌荷瘤小鼠模型,经尾静脉注射125I标记抗CD93单抗,并设125I-IgG为对照组,注药后不同时间进行生物学分布及磷屏放射自显影;肿瘤组织行HE染色及CD93免疫组织化学染色;采用统计软件对定量数据(x+s)进行统计学处理,组间数据用t检验,P<0.05为差异有统计学意义。结果表明,125I-anti-CD93 mAb及125I-IgG标记率、放射性比活度、放化纯度分别为91.37%和90.24%,1096.44 MBq/mg和1082.88 MBq/mg,96.49%和94.82%,放置72 h后两标记物的稳定性仍>90%,两者间无统计学差异(生理盐水组P=0.93,t=0.09,血清组P=0.13,t=1.90)。荷瘤鼠生物学分布结果显示125I-anti-CD93 mAb主要经肝肾代谢,注射后48 h时肿瘤组织放射性摄取率为(6.42±0.71)%ID/g,T/NT(瘤/对侧肌肉)摄取比值为4.45±0.86,显著高于对照组125I-IgG组(2.45±0.33/1.71±0.24),P<0.05,t=3.07和P<0.01,t=5.10。动态全身磷屏自显影结果可见,24 h两组小鼠轮廓清楚,48 h时实验组肿瘤显像最清晰,肿瘤放射性摄取比(肿瘤/对侧肌肉)为3.34±0.18,明显高于对照组(1.62±0.19),P<0.01,t=6.52。免疫组化染色结果证实肿瘤高表达CD93。125I-anti-CD93 mAb制备简便,对A549肺癌组织靶向性好,有望成为CD93阳性肿瘤监测的新型分子探针。     

纳米零价铁材料对放射性核素的 去除及机理研究进展

随着人类社会的发展,放射性铀矿的开采和使用越来越多,环境面临着越来越严重的放射性污染问题。从生物和环境的角度来看,有效地清除环境中的放射性核素是核能利用过程中最重要的问题之一。纳米零价铁（nanoscale zero valent iron, nZVI）具有较大的比表面积和较高的活性位点,能显著提高放射性污染物的修复效率。本综述的目的是展示nZVI基材料对放射性核素的高效去除能力和环境修复作用。简介了常用的nZVI基材料（表面改性或多孔材料支撑的nZVI材料）及其对放射性核素的去除效果和相互作用机制（如吸附和氧化还原）。最后,对nZVI材料的应用和挑战给出个人见解。本综述有助于为高效去除放射性核素的nZVI材料的设计指明方向,为放射性核素的高效处理处置提供新材料。