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Afaf Kamal-Eldin Lars Åke Appelqvist 《Journal of the American Oil Chemists' Society》1994,71(2):149-156
Seeds from different collections of cultivatedSesamum indicum Linn and three related wild species [specifically,S. alatum Thonn.,S. radiatum Schum & Thonn. andS. angustifolium (Oliv.) Engl.] were studied for their oil contents and fatty acid composition of the total lipids. The oils from wild seeds
were characterized by higher percentages of unsaponifiables (4.9, 2.6 and 3.7%, respectively) compared toS. indicum (1.4–1.8%), mainly due to their high contents of lignans. Total sterols accounted forca. 40, 22, 20 and 16% of the unsaponifiables of the four species, respectively. The four species were different in the relative
percentages of the three sterol fractions (the desmethyl, monomethyl and dimethyl sterols) and in the percentage composition
of each fraction. Campesterol, stigmasterol, sitosterol and Δ5-avenasterol were the major desmethyl sterols, whereas obtusifoliol, gramisterol, cycloeucalenol and citrostandienol were
the major monomethyl sterols, and α-amyrin, β-amyrin, cycloartenol and 24-methylene cycloartanol were the main dimethyl sterols
in all species. Differences were also observed among the four species in sterol patterns of the free sterols compared to the
sterol esters.Sesamum alatum contained less tocopherols (210–320 mg/kg oil), andS. radiatum andS. angustifolium contained more tocopherols (ca. 750 and 800 mg/kg oil, respectively) than didS. indicum (490–680 mg/kg oil). The four species were comparable in tocopherol composition, with γ-tocopherol representing 96–99% of
the total tocopherols. The four species varied widely in the identity and levels of the different lignans. The percentages
of these lignans in the oils ofS. indicum were sesamin (0.55%) and sesamolin (0.50%).Sesamum alatum showed 1.37% of 2-episesalatin and minor amounts of sesamin and sesamolin (0.01% each).Sesamum radiatum was rich in sesamin (2.40%) and contained minor amounts of sesamolin (0.02%), whereS. angustifolium was rich in sesangolin (3.15%) and also contained considerable amounts of sesamin (0.32%) and sesamolin (0.16%). 相似文献
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The presence of avocado seed oil in various avocado oils was detected by thin-layer chromatography (TLC). An unsaponifiable
compound, called Component-C, was identified in the avocado seed oil. This compound is unique to avocado seed and has a blue
color when developed on the TLC plate. At least 9.2 μg of avocado seed unsaponifiables were needed at a single TLC spot to
detect the unique blue color definitely. Admixtures of as little as 0.16% avocado seed oil in various avocado oils can be
detected by the proposed procedure. 相似文献
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葡萄籽油中脂肪酸和非皂化物的GC/MS分析研究 总被引:2,自引:0,他引:2
本文采用GC/MS联用仪结合快速层析技术和化学衍生法对葡萄籽油中脂肪酸和非皂化物成分进行分析研究,鉴定了8种脂肪酸甲酯,4种甾醇乙酰化物和11种烃类化合物。 相似文献
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Paresh Chandra Dutta Lars-ke Appelqvist 《Journal of the science of food and agriculture》1996,71(3):383-391
The content of saturated sterols (stanols) was investigated in a small number of samples of hydrogenated fats and oils, and in the ‘free’ and ‘bound’ lipids of various samples of cereals. The sterols, after saponification of the total lipids, were analysed as trimethylsilyl derivatives by GC and identified by GC–MS. Among the hydrogenated fats and oils, coconut oil contained the largest amounts of sitostanol followed by soybean oil (c 80 and 20 g kg−1 of total unsaponifiables, respectively). No sitostanol could be detected in hydrogenated palm oil under the present analytical conditions. Both ‘free’ and ‘bound’ lipids in various samples of wheat, except for wheat germ, contained c 70–120 g kg−1 campestanol and 100–150 g kg−1 sitostanol in total unsaponifiables. In lipids of oats and barley, no campestanol or sitostanol could be detected. Rye total lipids contained 60–90 g kg−1 of campestanol and 100–150 g kg−1 of sitostanol of total unsaponifiables in ‘free’ and ‘bound’ lipids, respectively. 相似文献
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Gennady Rosenblat Herbert M. Kagan Manzoor A. Shah Gerchard Spiteller Itshak Neeman 《Journal of the American Oil Chemists' Society》1995,72(2):225-229
The active factor of lysyl oxidase inhibition was separated from unsaponifiables of avocado seed oil and characterized by
gas chromatography-mass spectrometry. Results indicated the presence of furan-containing lipids in the active factor mixture
and also showed a structural difference compared to previously reported furan-containing lipids of avocado which relates to
the length of the hydrocarbon chain substituent. Another structural difference evinced was the availability of the hydroxyl
group in the aliphatic moiety of the investigated substances. A purified mixture of furan-containing compounds was testedin vitro for inhibitory activity on pure bovine aorta lysyl oxidase. It was shown that mixing furan-containing lipids in Tween 80
reversibly inhibited pure bovine aorta lysyl oxidase activity against tritiated recombinant tropoelastin with the I50 value of inhibition of 105 μM. Thesein vitro studies suggested that the mixture of avocado seed oil furan-containing lipids was not a substrate-specific inhibitor of
lysyl oxidase, and it might prove to be useful as a potential antifibrotic drug. Moreover, the unique chemistry of the studied
compound for lysyl oxidase inhibition should enable the designing of new probes of the active site of this important enzyme. 相似文献
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采用GC-MS分析茶叶籽油中不皂化物的成分,并采用高效液相色谱法对茶叶籽油中的角鲨烯进行定量分析。结果表明:茶叶籽油不皂化物的主要成分为角鲨烯、α-生育酚,另外还有合金欢醇、香叶里拉醇、羊毛甾醇、茉莉酮、D12齐墩果烯、2,4-二叔丁基苯酚及2,5-二叔丁基-1,4-苯醌等物质。通过C18柱分离样品中的角鲨烯,当流动相为甲醇/乙腈(60+40,V/V)、检测波长210 nm、流速2 m L/min、柱温30℃时,能有效分离茶叶籽油样品中的各组分,再经HPLC测得茶叶籽油中角鲨烯含量为4.1 mg/kg。当角鲨烯质量浓度在20~500 mg/L之间时,峰面积和质量浓度的线性关系较好,线性相关系数(R~2)为0.999 0;平均加标回收率为84.2%~90.1%,相对标准偏差(RSD)小于6.98%(n=4),此方法的测定低限(LOQ)为2.7 mg/kg。 相似文献
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A. Kamal-Eldin G. Yousif L. Å. Appelqvist 《Journal of the American Oil Chemists' Society》1991,68(11):844-847
A new, two-dimensional thin-layer chromatographic system was established to provide good separation of the unsaponifiable
fractions from the seed oils of three wildSesamum species, [S. alatum, Thonn.;S. radiatum, Schum and Thonn.; andS. angustifolium, (Oliv.) Engl.] and of the cultivatedS. indicum, L. The system utilizes silica gel plates and n-hexane/diethyl ether (7:3, v/v) and chloroform/diethyl ether (9:1, v/v) as
mobile phases in the first and second directions, respectively. The system could be used for qualitative studies and as a
preparative technique for subsequent quantitative gas chromatographic separations in chemotaxonomic and related studies onSesamum spp. 相似文献
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Camelina oil and its unusual cholesterol content 总被引:1,自引:1,他引:1
V. K. S. Shukla P. C. Dutta W. E. Artz 《Journal of the American Oil Chemists' Society》2002,79(10):965-969
The oil in Camelina sativa L. Crantz has a combined linolenic and linoleic acid content that is greater than 50% and a relatively low saturated FA content
(∼10%). Although the FA composition has been reported, no information is available on the sterol composition of camelina oil.
The derivatized plant sterols were separated and quantified with capillary GC and their identity confirmed with GC-MS. The
refined camelina oil sample contained approximately 0.54 wt% unsaponifiables, and over 80% of the unsaponifiables were desmethylsterols.
Perhaps the most unusual characteristic of camelina oil is its relatively high content of cholesterol, particularly for a
vegetable oil, since it contains several times the cholesterol found in other “high-cholesterol” vegetable oils. Camelina
oil also contains relatively large amounts of another unusual sterol, brassicasterol. The major sterols identified in the
camelina oil included cholesterol (188 ppm), brassicasterol (133 ppm), campesterol (893 ppm), stigmasterol (103 ppm), sitosterol
(1,884 ppm), and Δ5-avenasterol (393 ppm). 相似文献
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