镀锡板钝化污染控制技术

介绍了电镀锡机组钝化污染缺陷的宏观形貌;从挤干设备、助熔工艺、钝化工艺、钝化设备等方面分析了钝化污染产生的原因。通过产线实践,发现助熔挤干辊位置,钝化段槽液中重铬酸钠浓度和p H值与钝化污染缺陷的产生无关,钝化极板的清洁程度、钝化液的老化程度以及助熔液的清洁程度才是导致钝化污染的主要原因。通过调整助熔槽液浓度,保证钝化极板清洁性,钝化污染缺陷得到有效控制。     

Nanomaterials for radiotherapeutics-based multimodal synergistic cancer therapy

Over the past decade, numerous studies have attempted to enhance the effectiveness of radiotherapy (external beam radiotherapy and internal radioisotope therapy) for cancer treatment. However, the low radiation absorption coefficient and radiation resistance of tumors remain major critical challenges for radiotherapy in the clinic. With the development of nanomedicine, nanomaterials in combination with radiotherapy offer the possibility to improve the efficiency of radiotherapy in tumors. Nanomaterials act not only as radiosensitizers to enhance radiation energy, but also as nanocarriers to deliver therapeutic units in combating radiation resistance. In this review, we discuss opportunities for a synergistic cancer therapy by combining radiotherapy based on nanomaterials designed for chemotherapy, photodynamic therapy, photothermal therapy, gas therapy, genetic therapy, and immunotherapy. We highlight how nanomaterials can be utilized to amplify antitumor radiation responses and describe cooperative enhancement interactions among these synergistic therapies. Moreover, the potential challenges and future prospects of radio-based nanomedicine to maximize their synergistic efficiency for cancer treatment are identified.

     

基于密钥共享的分层混合认证模型

随着信息时代的迅速发展,云计算数据访问安全已经成为了用户最关心的问题。身份认证技术是确保参与者在开放的网络环境中实现安全通信的一种重要手段,如何利用身份认证技术为云环境安全保驾护航,成为学者研究的热点。文中通过公钥基础设施(Public Key Infrastructure,PKI)颁发CA证书以在不同云服务间建立信任,将多个采用身份密码体制(Identity-Based Encryption,IBE)的云联合起来；采用分层身份加密体系,引入共享密钥技术,通过选取成环结构,提出一种PKI-IBE混合认证模型方案,并对方案的安全性进行分析,从理论上证明了云环境下PKI-IBE(Public Key Infrastructure-Identity-Based Encryption)同层成环模型提供服务的可行性。同时文中设计了一种基于该模型的签密技术,通过公私密钥对实现云内认证以及跨云认证。安全性理论证明与性能分析表明,该方案在计算量稍增加的前提下,保证了足够的安全性,更加满足云环境下的用户分属不同云域的认证以及用户安全访问的需求,有效解决了云环境中数据访问的安全问题。     

车用复合材料板簧性能的有限元分析

为了初步验证所设计复合材料板簧的结构性能,利用有限元分析方法对复合材料板簧结构的静载力学和动态疲劳进行了研究。计算得到空载工况加载过程中的载荷—位移曲线,板簧刚度为373 N/mm。当两端施加载荷为64.7 kN时,板簧达到最大压缩应力。结合复合材料的S—N曲线对板簧寿命进行了估算,循环次数最低处位于板簧下表面靠近卷耳部分,循环次数为33万次。对比复合材料板簧的设计刚度和疲劳寿命,与有限元分析处理方法计算所得结果较为接近,该板簧结构基本符合使用要求。     

响应面法优化艾叶挥发油的提取工艺及其抗氧化性能研究

以艾叶挥发油提取率为考核指标,采用单因素实验考察浸泡时间、料液比、提取时间等对艾叶挥发油提取率的影响,在此基础上,采用响应面法优化艾叶挥发油的共水蒸馏提取工艺,并通过紫外分光光度法测定艾叶挥发油对DPPH自由基的清除率来评价其抗氧化性能。结果表明,艾叶挥发油的最佳提取工艺条件为:浸泡时间1.5 h、料液比1∶10(g∶mL)、提取时间4.5 h,在此条件下,艾叶挥发油提取率最高,为0.83%。当艾叶挥发油浓度为80 mg·mL~(-1)时,DPPH自由基清除率最高,为39.12%。表明艾叶挥发油具有一定的抗氧化活性。     

大宗粉煤灰的综合利用及提质方案

对于大宗粉煤灰原灰进行分选加球磨机粉磨，同时添加合适的激发剂进行提质，可以生产出不同细度和活性的粉煤灰产品，提升粉煤灰在水泥及商品砼中的用量。介绍了某发电公司的粉煤灰处置现状，在此基础上，对商品砼的粉煤灰性能要求进行了大量市场调研，针对性地给出了该公司粉煤灰的提质方案，最后进行了提质粉煤灰的应用市场和产品竞争力分析。     

管道清管器运行速度控制技术研究进展

随着对管道安全问题和降本增效理念的逐步重视，管道清管操作已成为全世界油气管道运行中必不可少的作业规程，清管器的运行速度是需要重点控制的参数之一，当其处于合理区间内时（原油管道1~5m/s，天然气管道2~7m/s），清管效果最佳。本文基于对管道清管数学模型的研究，首先论述了不同的被动控制方法，认为该方法较为灵活，应用广泛，对不同入口条件下清管器速度的准确计算是能否控制清管器速度处于合理区间的关键；然后对不同的主动控制方法进行了研究，研究表明：射流清管器速度控制的核心是旁通率的优选，其依赖于压降系数、皮碗与管壁间摩擦力的准确计算，建立简便可靠的摩擦力工程计算模型将有助于射流清管技术应用的进一步推广；最终本文对清管器智能调速技术进行综述和展望，指出发展稳定可靠的国产智能调速技术是未来重点研究方向。     

Combined effects of wheat gluten and carboxymethylcellulose on dough rheological behaviours and gluten network of potato–wheat flour-based bread

Incorporating high level of potato flour into wheat flour enhances nutritional values of bread but induces a series of problems that lead to the decline of the bread quality. To overcome the barrier, wheat gluten and carboxymethylcellulose (CMC) were added into potato–wheat composite flour to improve dough machinability and bread quality. The rheological properties, thermo-mechanical properties and microstructures of dough were investigated. The results showed that the interaction between gluten and CMC mitigated the discontinuity of gluten matrix and gluten protein aggregation caused by the addition of potato flour, which yielded a more branched and compact gluten network. The compact three-dimensional viscoelastic structure induced improvements of gas retention capacity and dough stability, making it mimic the machinability properties of wheat flour dough. Bread qualities were apparently improved with the combined use of 4% gluten and 6% CMC, of which specific volume increased by 42.86%, and simultaneously, hardness reduced by 75.93%.     

Preparation of Silver Nanowires via a Rapid,Scalable and Green Pathway

Rapid synthesis of silver nanowires(Ag NWs) with high quality and a broad processing window is challenging because of the low selectivity of the formation of multiply twinned particles at the nucleation stage for subsequent Ag NWs growth.Herein we report a systematic study of the water-involved heterogeneous nucleation of Ag NWs with high rate(less than 20 min) in a simple and scalable preparation method.Using glycerol as a reducing agent and a solvent with a high boiling point,the reaction is rapidly heated to 210 ℃ in air to synthesize Ag NWs with a very high yield in gram level.It is noted that the addition of a small dose of water plays a key role for obtaining highly pure Ag NWs in high yield,and the optimal water/glycerol ratio is0.25%.After investigating a series of forming factors including reaction temperature and dose of catalysts,the formation kinetics and mechanism of the Ag NWs are proposed.Compared to other preparation methods,our strategy is simple and reproducible.These Ag NWs show a strong Raman enhancement effect for organic molecules on their surface.     

In situ characterization of LiY(WO4)2 nanotubes for electrochemical energy storage

Here, LiY(WO₄)₂ nanotubes are prepared via a feasible electrospinning technique. This new anode material shows excellent electrochemical properties. The capacity loss of LiY(WO₄)₂ nanotubes is as low as 6.9% after 156 cycles, while bulk LiY(WO₄)₂ presents the capacity loss higher than 55.0%. Even after 600 long-life cycles, the capacity loss of the nanotubes is only 9%. It can be seen that the hollow structure with a rough surface and a porous morphology contributes to the improvement of electrochemical performance. Furthermore, online X-ray diffraction (XRD) method is firstly applied to understand the lithium ions insertion/extraction mechanism of LiY(WO₄)₂ nanotubes. It can be concluded that it is an asymmetrical two-phase reaction. A phase transformation from LiY(WO₄)₂ to Li₃Y(WO₄)₂ can be obviously seen from the in situ XRD during discharge process. While Li₂Y(WO₄)₂ appears as an intermediate phase with a reverse charge reaction. In addition, in situ XRD also demonstrates that LiY(WO₄)₂ nanotubes have surprised electrochemical reversibility. All the above results indicate that LiY(WO₄)₂ nanotubes can be expected to be anode candidate for rechargeable lithium ion batteries (LIBs).