Engineering with Computers - We studied a new implicit method of order three based on two off-step points for the numerical solution of second-order nonlinear initial-value problems... 相似文献
Phase transformation studies have been made of the Mn-Al alloys with compositions near the equiatomic range with or without small amounts of carbon, copper and nickel, using differential thermal analysis, X-ray diffraction and optical and electron microscopy. The high temperature hexagonal phase obtained by quenching, transforms to the ferromagnetic phase between 500 and 550° C and on further heating transforms back to the hexagonal phase between 750 and 950° C. Also, on controlled cooling of the phase from about 900° C, the ferromagnetic phase is formed between 800 and 670° C. TEM studies have shown the presence of the B19 ordered phase, ferromagnetic phase and Mn5Al8 precipitates even in quenched alloys. 相似文献
A new topotactic sintering method using Fe2O3 (obtained from FeO · OH) and BaCO3 is developed for preparing cheaper grain oriented barium hexaferrite. Fe2O3 and BaCO3 (precipitate grade) are wet mixed in a ball mill in stoichiometric proportion. The mixed slurry is then dried at 110° C for about 12h. The dried powder mixture containing moisture as a binder is uniaxially compacted at 5×106–10×106 kg m–2 pressure. The green compacts are air sintered in the temperature range 1100–1300° C for 1 H. The best results of the sintered ferrite show maximum energy product (BH) max in the range 7–10 kTAm–1. The bulk of commercial requirements for toy magnets etc. may be met by this method of production which eliminates steps like calcination and cost intensive wet magnetic compaction. 相似文献
A mathematical model for the transient heat flow analysis in arc-welding processes is proposed, based on a unique set of boundary conditions. The model attempts to make use of the relative advantages of analytical as well as numerical techniques in order to reduce the problem size for providing a quicker solution without sacrificing the accuracy of prediction. The variation of thermo-physical properties with temperature has been incorporated into the model to improve the thermal analysis in the weld and heat-affected zones. The model has been evaluated using a five-point explicit finite difference method for analysing the welding heat flow in thin plates of two different geometric configurations. The temperature distribution closer to the heat source, primarily in the weld zone and the heat-affected zones, are predicted by the numerical technique. The thermal characteristics beyond the heat-affected zone are amenable to standard analytical techniques. The behaviour of the boundary condition in the model has been investigated in detail.Nomenclature
q
Rate of heat per unit thickness (Wm–1)
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d
Plate thickness (m)
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v
Velocity of source (m s–1)
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t
Time (s)
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T
Temperature value at the desired point (K)
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T0
Initial temperature (K)
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K
Thermal conductivity (W m–1 K–1)
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Density (kg m–3)
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cp
Specific heat (J kg–1 K–1)
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Thermal diffusivity (m2 s–1)
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n
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Distance of point considered from the source (=x–vt) (m)
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K0
Modified Bessel function of second kind and zero order
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r
Radial distance from the source (r=(x2+y2)1/2) (m)
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Model width (m)
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a
Plate width (m)
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Distance from the source =(2+4 ×10–4)1/2 (m)
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Antimicrobial resistance has long been viewed as a lethal threat to global health. Despite the availability of a wide range of antibacterial medicines all around the world, organisms have evolved a resistance mechanism to these therapies. As a result, a scenario has emerged requiring the development of effective antibacterial drugs/agents. In this article, we exclusively highlight a significant finding reported by Zbořil and associates (Adv. Sci. 2021, 2003090). The authors construct a covalently bounded silver-cyanographene (GCN/Ag) with the antibacterial activity of 30 fold higher than that of free Ag ions or typical Ag nanoparticles (AgNPs). Ascribed to the strong covalent bond between nitrile and Ag, an immense cytocompatibility is shown by the GCN/Ag towards healthy human cells with a minute leaching of Ag ions. Firm interactions between the microbial membrane and the GCN/Ag are confirmed by molecular dynamics simulations, which rule out the dependence of antibacterial activity upon the Ag ions alone. Thus, this study furnishes ample scope to unfold next-generation hybrid antimicrobial drugs to confront infections arising from drug and Ag-resistant bacterial strains. 相似文献
A temperature sensor based on photonic crystal structures with two- and three-dimensional geometries is proposed, and its measurement performance is estimated using a machine learning technique. The temperature characteristics of the photonic crystal structures are studied by mathematical modeling. The physics of the structure is investigated based on the effective electrical permittivity of the substrate (silicon) and column (air) materials for a signal at 1200 nm, whereas the mathematical principle of its operation is studied using the plane-wave expansion method. Moreover, the intrinsic characteristics are investigated based on the absorption and reflection losses as frequently considered for such photonic structures. The output signal (transmitted energy) passing through the structures determines the magnitude of the corresponding temperature variation. Furthermore, the numerical interpretation indicates that the output signal varies nonlinearly with temperature for both the two- and three-dimensional photonic structures. The relation between the transmitted energy and the temperature is found through polynomial-regression-based machine learning techniques. Moreover, rigorous mathematical computations indicate that a second-order polynomial regression could be an appropriate candidate to establish this relation. Polynomial regression is implemented using the Numpy and Scikit-learn library on the Google Colab platform.
High nitrogen steels provide excellent mechanical properties and corrosion resistance but are prone to form precipitates which adversely affect the corrosion resistance and toughness. High nitrogen steel powders currently available in the market are not claimed to be precipitate free. It is critical to avoid these precipitates while retaining nitrogen in the dissolved form to realize the value of these powder alloys. However, retaining high level of dissolved nitrogen in steel powder during melt atomization process is very challenging. Instead, solid-state dissolution of nitrogen into the powder alloy followed by rapid cooling may provide a convenient approach to avoid precipitate formation compared to traditional melt processing. This study presents a solution treatment approach to achieve elevated dissolved nitrogen levels (~ 0.4 wt pct) in Fe–Mn–Cr powder alloy with negligible precipitation of nitrides. The influence of starting material, holding time, temperature and cooling rate on the resulting microstructure is presented. A fully austenite matrix with high dissolved nitrogen content resulted in powders with desired mechanical properties.
Different structured activated carbons were prepared from Terminalia arjuna nuts, an agricultural waste, by chemical activation with zinc chloride for the adsorption of Cr(VI) from dilute aqueous solutions. The most important parameter in chemical activation was found to be the chemical ratio (activating agent/precursor, g/g). Carbonization temperature and time are the other two important variables, which had significant effect on the pore structure of carbon. A high surface area of was obtained at a chemical ratio of 300%, carbonization time and temperature of 1 h and 500 °C, respectively. The activated carbon developed shows substantial capability to adsorb Cr(VI) from dilute aqueous solutions. The parameters studied include pH, adsorbent dosage, contact time, and initial concentrations. The kinetic data were best fitted to the Lagergren pseudo-first-order model. The isotherm equilibrium data were well fitted by the Langmuir and Freundlich models. The maximum removal of chromium was obtained at pH 1.0 (about 99% for adsorbent dose of 2 g/l and 10 mg/l initial concentration). 相似文献