Study on purification and application of novel precipitant for ceria-based polishing powder

Novel precipitant prepared through carbonation with MgCl2 wastewater generated from rare earth extraction separation process and low-price dolomite as raw materials was studied in this paper. The purification methods of novel precipitant by adding appropriate oxidizing agent were studied. It was found that optimal purification result could be achieved with sodium hypochlorite as iron removal reagent and the iron removal rate could reach up to 90% when the adding amount was 0.1 vol.%. During the preparation, the particle size and distribution of ceria-based polishing powder were affected obviously by the parameters such as concentration, reaction temperature and feeding rate. The results showed that ceria-based polishing powder with D50 =2.5-3.5 μm and the particle size distribution of 0.65-0.75 μm could be prepared when the concentration of CeCl3 was 0.6 mol/L, the reaction temperature was maintained at 50 °C and the feeding speed was controlled at 25 ml/min. Compared with commercial powder, the self-made polishing powder had roughly the same cutting amount, but the surface finish of polished glass was better than that of commercial polishing powder.     

水蒸气对钙基吸收剂循环煅烧/碳酸化CO2捕集过程中孔结构的影响

利用自制等温测量热重实验台,对钙基吸收剂循环煅烧/碳酸化工艺中水蒸气对吸收剂孔结构影响进行了研究。仅煅烧阶段含有水蒸气时,转化率最低,而仅碳酸化阶段存在水蒸气时,取得最高的碳酸化转化率。煅烧阶段和碳酸化阶段均含有水蒸气与仅碳酸化阶段存在水蒸气转化率类似。采用氮吸附测试了典型工况下的Ca O孔结构。随着循环次数增加,碳酸化转化率降低,比表面积、孔容积逐渐减小。推测煅烧阶段水蒸气通过烧结降低了碳酸化转化率。碳酸化阶段水蒸气通过催化作用提高了转化率,此时孔结构作用并不占主动地位。煅烧和碳酸化均存在水蒸气时,碳酸化阶段水蒸气催化作用更加明显。     

6FA型燃气—蒸汽联合循环机组节能增效措施的应用

通过对6FA型燃气轮机联合循环机组启停操作优化、辅机操作优化、运行方式优化、节能改造等方面节能增效措施的应用,减少企业外购电量、节约天然气、减少启动厂用电,达到了预期的效果。     

126kV GIS盘式绝缘子金属法兰开孔的电场仿真分析

GIS中盘式绝缘子的电气性能是设计者关注的重点,盘式绝缘子在制造的过程中,由于浇注工艺的原因会在金属法兰处留有一椭圆切面的浇注孔,内部填充环氧树脂,在环氧树脂和金属法兰交界处会产生一定的电场畸变。主要研究金属法兰开孔尺寸大小和结构对盆式绝缘子表面和浇注孔表面电场强度的影响。研究表明:大尺寸浇注孔表面的场强最大值为0.85 k V/mm,要高于小尺寸浇注孔表面电场强度最大值0.38 kV/mm。说明开孔越小,浇注孔表面电场强度最大值越小,在满足测量要求情况下,开孔越小越好。     

Hydrophobic and nanoporous chitosan–silica composite aerogels for oil absorption

Hydrophobic and nanoporous chitosan–silica composite aerogels with low density, high porosity, and superior oil absorbency were successfully prepared by a typical sol–gel method and a two‐step hydrophobic treatment. The morphologies, porosity characteristics, mechanical properties, thermal stability, hydrophobicity, and oil absorbencies of the composite aerogels were systematically investigated. The nitrogen physisorption analysis showed that composite aerogels had large specific surface areas and uniform nanoporous structures. In addition, the composite aerogels could support 7000 times its own weight; this indicated the role of the supporting skeleton played by chitosan. The hydrophobicity and lipophilicity was demonstrated with a water contact angle of 137° and an oil contact angle of 0°. Importantly, the composite aerogel with 20 wt % chitosan had a relatively high oil absorbency of 30 g/g and could be reused up to 10 times. Therefore, the chitosan–silica composite aerogels in this study had a broad prospect to be used as efficient and recyclable oil absorbents. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41770.     

李楼铁矿一次爆破成井试验研究

为解决井下大结构采场切割天井成井速度慢、成本高、安全性差的问题,设计采用一次爆破成井的方式来形成切割天井。确定了合理可行的掏槽方式及孔网参数、装药量及装药结构、起爆顺序及微差时间。据现场统计,一次爆破成井总成本为6.84万元,较普通法节省了成井费用6.46万元,节省工期7~8d,表明一次爆破成井效果良好,可在全矿推广应用。     

塔里木盆地志留系柯坪塔格组沉积相特征

为了明确塔里木盆地志留系柯坪塔格组的沉积特征,通过对岩芯、钻井、测井和地震资料的分析,结合粒度分析手段,对柯坪塔格组上、中、下三段进行了沉积相识别与划分,在该层段识别出扇三角洲、有障壁滨海以及浅海3种沉积相,划分出三角洲平原、三角洲前缘、潮坪、陆棚4种沉积亚相及9种沉积微相。利用地震属性信息并结合砂地比,分析了柯坪塔格组各段沉积相平面展布特征,对今后的勘探开发提供一定的参考依据。     

考虑各向异性对软土隧道沉降的影响

采用不同本构模型对盾构开挖第4阶段的沉降进行了模拟,模型分别为考虑各向异性的本构模型（EVP-SCLAY1模型）和各向同性模型（MC模型和MCC模型）,将这3个模型的计算结果与实测数据之间进行了对比,结果显示,在模拟盾构开挖引起的沉降范围以及地表沉降时,各向异性模型模拟结果与实测结果更加吻合,而MC模型预测结果最差。     

矿用自动风门的设计

基于风压平衡原理,对矿用自动压力平衡风门的控风设施进行机械设计.以模块化设计为设计思路,对实现异向同步开启的传动装置、机械闭锁装置等分别进行改进,使得其安装方便,后期维护简单.此种新型压力平衡风门门扇采用岩棉填充.常开风门关闭后可实现对火灾烟流的有效阻挡.     

《房屋建筑学》教材编写的探究

基于贵州师范大学主持编写的《房屋建筑学》土建类规划教材,阐述了教材编写的四点创新理念,介绍了教材体例编排与内容特点。文章从原理篇与构造篇序列,滞后于行业发展的教材内容,建筑构造图形表达的地域局限性,学生工程素质和创新能力培养四方面进行了探究,对数字化校园课程纸质教材建设提出了建议。