KINETICS OF HYDROCARBON GAS GENERATION FROM MARINE KEROGEN AND OIL: IMPLICATIONS FOR THE ORIGIN OF NATURAL GASES IN THE HETIANHE GASFIELD, TARIM BASIN, NW CHINA

In this paper we derive kinetic parameters for the generation of gaseous hydrocarbons (C_1‐5) and methane (C₁) from closed‐system laboratory pyrolysis of selected samples of marine kerogen and oil from the SW Tarim Basin. The activation energy distributions for the generation of both C_1‐5 (Ea = 59‐72kcal, A = 1.0×10¹⁴ s^?1) and C₁ (Ea = 61‐78kcal, A = 6.06×10¹⁴ s^?1) hydrocarbons from the marine oil are narrower than those for the generation of these hydrocarbons from marine kerogen (Ea = 50‐74kcal, A = 1.0×10¹⁴ s^?1 for C_1‐5; and Ea = 48‐72kcal, A=3.9×10¹³ s^?1 for C₁, respectively). Using these kinetic parameters, both the yields and timings of C_1‐5 and C₁ hydrocarbons generated from Cambrian source rocks and from in‐reservoir cracking of oil in Ordovician strata were predicted for selected wells along a north‐south profile in the SW of the basin. Thermodynamic conditions for the cracking of oil and kerogen were modelled within the context of the geological framework. It is suggested that marine kerogen began to crack at temperatures of around 120°C (or 0.8 %Ro) and entered the gas window at 138°C (or 1.05 %Ro); whereas the marine oil began to crack at about 140 °C (or 1.1 %Ro) and entered the gas window at 158 °C (or 1.6%Ro). The main geological controls identified for gas accumulations in the Bachu Arch (Southwest Depression, SW Tarim Basin) include the remaining gas potential following Caledonian uplift; oil trapping and preservation in basal Ordovician strata; the extent of breaching of Ordovician reservoirs; and whether reservoir burial depths are sufficiently deep for oil cracking to have occurred. In the Maigaiti Slope and Southwest Depression, the timing of gas generation was later than that in the Bachu Arch, with much higher yields and generation rates, and hence better prospects for gas exploration. It appears from the gas generation kinetics that the primary source for the gases in the Hetianhe gasfield was the Southwest Depression.     

贮煤塔开闭器驱动装置的改造

针对炼铁厂炼焦车间贮煤塔和开闲器驱动装置存在故障频繁，堵煤、开闭器易损坏和吹风管堵塞等问题，通过分析并结合实际情况，将煤塔漏嘴由27只减为9只双曲线形状漏嘴，开闭器驱动装置由车载驱动改为固定驱动。改造后，解决了使用中堵煤及开闭器驱动装置损坏等问题，降低了设备故障率，减少了生产成本，增加了装煤量，满足了生产需要。     

小江活动断裂带建坝地质问题及对策措施

某市清水海引水工程拟在天然湖泊清水海的湖口(出溢口)建坝,扩大湖泊容量,以形成调蓄枢纽,可行性研究论证的坝高规模为12.5 m,湖水位高程2 180 m,最大蓄水深度约40 m,湖水容量14 878×104m3.     

New concept of surface modification to LiCoO2

As the continuance of our series study on LiCoO₂ surface modification, the complicated traditional surface coating method is replaced with simple addition of amorphous YPO₄ and Al₂O₃ in commercial LiCoO₂ or in commercial electrolyte based on our understanding to the improvement mechanism of surface modification. Comprehensive studies by X-ray photoelectron spectroscopy (XPS), gas chromatography and mass spectroscopy (GC–MS), inductively coupled plasma (ICP) and Fourier transformed infrared (FTIR) indicate that the products of spontaneous reaction between the additive and the LiPF₆ based electrolyte are responsible for the performance improvements.     

人睫状神经营养因子基因克隆、表达、纯化及其生物活性

［摘 要］目的 克隆人睫状神经营养因子（hCNTF）基因，在大肠杆菌宿主系统中高效表达并纯化，获得具有生物活性的hCNTF蛋白。方法 以人染色体DNA为模板，经PCR扩增到编码CNTF成熟蛋白的cDNA序列，并克隆进原核表达载体 pBV220，在大肠杆菌 BL21（Gold）中进行表达，产物经 CM-Sepharose FF柱纯化后，以体外培养的鸡胚背根神经节（DRG）测定生物活性。结果 重组表达质粒pBV22Z- CNTF在大肠杆菌BL21（Gold）中获得了非融合的稳定、高效表达，目的蛋白占细胞总蛋白的45％左右，以可溶性和包涵体两种形式存在，表达上清及包涵体复性后经CM柱一步纯化纯度达90％以上；表达的重组hCNTF能促进培养的鸡胚背根神经节神经突起的生长。结论 基因工程rhCNTF的获得为进一步研究其结构功能关系和临床应用奠定基础。     

采用轴径向技术有效解决固定床反应器阻力降的快速升高

讨论了固定床反应器阻力降快速升高的原因，介绍了用轴径向技术解决这一问题的原理及优点，及其在铁铬系变换催化剂和钴钼系耐硫变换催化剂反应器中的实际应用。     

高空间频率向列相液晶二进制光栅

研究了向列相液晶在空间变化电场作用下的电光特性。模拟了向列相液晶相位光栅的旨向矢分布。随着光栅空间频率的增加条纹电场变得很重要，而且衍射方式也发生了变化。分析了光栅的光学性能并进行了实际测量。     

微机继电保护在西沟水电站的应用

随着科学技术的迅猛发展，计算机技术已在工业领域得到了广泛的应用。近年来，继电保护也由传统的继电器控制转向微机控制。结合西沟水电厂微机线路继电保护改造说明微机继电保护比传统继电器控制有更多优势，比如高可靠性、开放性、透明化、免调试、人性化设计等。图1幅。     

膜萃取器设计及应用研究进展

简要阐述了膜萃取的特点和基本类型;重点介绍了轴对称、纤维、片状等３种膜器的设计原理、特征以及膜过程设计．总结了膜萃取技术在金属离子分离、旋光化合物的分离、发酵萃取、医药萃取等方面的应用现状和最新进展;展望了膜萃取技术的发展趋势。     

非织造保暖材料在军用服装中的应用

介绍非织造保暖材料军用棉服、军用内衣的制作 ,对不同材料和结构的成品服装的各项性能作了分析和比较。