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Yi Xi Chenguo Hu Bin Feng Xue Wang Chunhua Zheng Xiaoshan He 《Journal of Superconductivity and Novel Magnetism》2010,23(6):901-903
Zinc sulfide nanoflowers are synthesized by the composite-hydroxide-mediated (CHM) method, using molten composite hydroxides as a reaction solvent, sodium sulfide and zinc nitrate hexahydrate as reactants at temperature of 200?°C in the absence of organic dispersant or capping agents. The XRD spectrum of the as-synthesized sample indicates a cubic ZnS with lattice group \(F\bar{4}3m[216]\) and lattice constant a=5.318 Å. The scan electron microscopy and transmission electron microscopy display its good crystallization and flower shape with diameter of 800–1000 nm. The photoluminescence results reveal that the ZnS nanocrystal has a band gap of 3.4 eV. The strong blue emission centered at 440 nm demonstrates the existence of defect states. This CHM approach provides a useful route for the synthesis of ZnS crystals, which may be extended to synthesize other II–VI semiconductors. 相似文献
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Yi Xi Chenguo Hu Puxian Gao Rusen Yang Xiaoshan He Xue Wang Buyong Wan 《Materials Science and Engineering: B》2010,166(1):113-117
CuxO (x = 1, 2) nanocrystals have been synthesized by the composite-hydroxide-mediated approach. The obtained nanocrystals were characterized by X-ray diffraction, energy dispersive X-ray spectroscopy, scanning electron microscopy, transmission electron microscopy, and UV–vis spectrum. The morphology of the nanocrystals changed from sphere-shaped nanostructures to flower-shaped nanostructures, and finally to nanowires associated with phase transformation from CuO to Cu2O by increasing the temperature. The possible phase transformation mechanism was discussed. The catalytic degradation activity of the CuxO (x = 1, 2) nanocrystals to methyl orange was also investigated. The photocatalytic ability of the sphere-shaped nanostructures is much higher than that of the nanowires, owing to its absorption of wider range of light energy. This work provides a new facile synthesis route of CuxO (x = 1, 2) nanocrystals and suggests their possible application in organic pollutants removal. 相似文献
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利用电磁场理论计算出单根纳米管场发射时其尖端附近的电势和电场分布。结果表明 ,纳米管尖端表面电场非常强 ,随着距离尖端表面的距离的增加 ,电场迅速下降 ;尖端附近的场强与纳米管场发射有低的阈值电压相符合。计算还给出在保持极板间距离和电压不变的情况下 ,纳米管长径比越大 ,尖端电场越强 ,因此 ,具有更低的阈值电压 相似文献
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Jian Wang Gui Li Shuyan Xu Huiyuan Wu Shaoke Fu Chuncai Shan Wencong He Qionghua Zhao Kaixian Li Chenguo Hu 《Advanced functional materials》2023,33(43):2304221
Currently, the research on improving charge density of charge-excitation triboelectric nanogenerators (CE-TENG) mainly focuses on surface modification and thinning of organic polymer materials. However, to increase durability and output, the exploration of high permittivity and high-thickness inorganic materials is important for extensive applications. Meanwhile, the physical mechanism of air ionization caused by air breakdown during secondary self-charge excitation (SSCE) needs to be explored. Herein, this study proposes a new strategy for CE-TENG based on inorganic materials by de-trapping reverse charge and increasing the contact barrier difference to obtain high charge density and achieve secondary self-charge excitation. SSCE of three types of films with different leakage currents are evaluated according to their trapping and de-trapping reverse charges. It is found that the trap distribution of dielectric films with larger leakage currents are mostly shallow-level traps, whose de-trapping ability becomes stronger after reverse charge injection. By regulating the contact barrier difference with thin organic polymer on thick inorganic high permittivity material, this study has achieved a high charge density of 1310 µC m−2 with a fast start-up time of SSCE, which is a new record for the charge density of inorganic materials. This study promotes TENG of inorganic materials toward high-energy output applications. 相似文献
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Gui Li Jian Wang Shaoke Fu Chuncai Shan Huiyuan Wu Shanshan An Yan Du Wencong He Zhao Wang Wenlin Liu Yongjie Nie Siyang Liu Ping Wang Chenguo Hu 《Advanced functional materials》2023,33(14):2213893
Triboelectric–electromagnetic hybridized nanogenerator (TEHG) is confirmed as an effective energy harvesting for Internet of Things. However, it is still a great challenge to gain a high-output triboelectric-nanogenerator (TENG) and to perfectly combine TENG with electromagnetic generator (EMG). Herein, a TEHG composed of space confined multi-layer-stack TENG (SM-TENG) and stack compression promoted flux change EMG is proposed. The interaction of magnets on the rotor with the magnets on the stator makes contact–separation of the SM-TENG and changes the magnetic flux of EMG in rotation process, reducing wear and deformation of TENG. A voltage multiplier circuit (VMC) with a Zener diode is employed to enhance SM-TENG performance and maintain stable output. The output charge and current of four SM-TENG units reach 3.2 µC and 385 µA at rotatory speed 60 rpm, and the voltage of four EMG reaches 8.09 V. The perfect combination and synergetic utilization of triboelectrification, charge excitation, and electromagnetic induction in a single device are realized. The integrated TEHG can power 12 bulbs (2 W) and 16 thermo-hygrometers, and a Bluetooth thermo-hygrometer to transmit wireless signals to a mobile phone. This work provides a new strategy for high efficient integration and utilization various mechanisms in one energy-harvesting device. 相似文献
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为实现ps脉冲电场(ps PEF)经冲激脉冲辐射天线(IRA)发射后在近似实际乳房组织(电导率为0.5 S/m)模型中的有效聚焦,采用计算机仿真技术(CST)Microwave studio软件构建了天线及乳房组织模型并计算了ps PEF在其中的聚焦特性。结果表明:引入优化参数的损耗介质材料(厚度为1 cm,电导率为10 S/m)衰减小路径角电场,最终能够实现ps PEF在焦点F2处的聚焦(电场强度E=0.08 V/m);损耗材料的引入使得焦点F2处的电场强度大大减小,引入损耗介质透镜,不仅实现了ps PEF在乳房组织模型中的良好聚焦,而且焦点F2处的电场强度(E=0.45 V/m)大大增强。因此,优化设计的损耗介质透镜能够实现ps PEF在生物组织中的有效聚焦。 相似文献