半芳香族耐高温尼龙PA6T/6I基LDS功能材料制备及性能

采用半芳香族耐高温尼龙聚对苯二甲酸/间苯二甲酸己二胺(PA6T/6I)为树脂基体,铜铬氧化物为激光镭射助剂,制备了PA6T/6I基的激光直接成型(LDS)功能材料。采用扫描电子显微镜对激光镭射助剂分散状态及LDS功能材料模塑器件的表面形貌能进行了表征,使用热失重分析仪、差示扫描量热仪对LDS功能材料的热失重行为、熔融结晶性能进行了表征,研究了激光镭射助剂添加量对LDS功能材料的力学性能、热稳定性、化学镀性能的影响,同时研究了PA6T/6I熔融结晶性能和注塑模具温度对于模塑器件表面、外观的影响。结果表明,偶联剂的添加有利于改善激光镭射助剂在PA6T/6I树脂基体中的分散,其中环氧类的偶联剂KBM–403处理后的LDS镭射助剂分散效果最佳。激光镭射助剂添加量的增加,会造成LDS功能材料拉伸强度、弯曲强度、冲击强度及初始分解温度降低。激光镭射助剂添加量在8%时,预镀铜上镀时间和镀层覆盖时间最短,化学镀效果最佳。当注塑模具温度为175℃时,玻纤增强PA6T/6I基LDS功能材料模塑器件的外观最佳。     

特征学习的单幅图像去雾算法

目的 雾霾天气使图像降质,严重影响军事、交通和安全监控等领域信息系统的正常运作,因此图像去雾具有重要研究意义。目前主流的单幅图像去雾算法主要利用各种与雾相关的颜色特征实现,但不同的颜色先验知识往往存在各自的场景局限性。为提高图像去雾的普适性,提出一种特征学习的单幅图像去雾方法。方法 首先通过稀疏自动编码机对有雾图像进行多尺度的纹理结构特征提取,同时抽取各种与雾相关的颜色特征。然后采用多层神经网络进行样本训练,得到雾天条件下纹理结构特征及颜色特征与场景深度间的映射关系,并估算出有雾图像的场景深度图。最后结合大气散射模型,根据场景深度图复原无雾图像。结果 与主流去雾算法的结果定性对比,复原后的图像细节更清晰,颜色更自然。采用均方误差和结构相似度定量评价各算法去雾结果与真实无雾图像的相似度,本文算法结果与真实无雾场景间的相似度最高,达到99.9%。结论 对实验结果的定性及定量分析表明,本文算法能有效获取有雾图像的场景深度,复原出视觉效果理想的无雾图像,且具有很好的场景普适性。     

高级氧化-IC-曝气工艺处理克林霉素生产废水实例

某药业股份有限公司克林霉素生产废水采用高级氧化-IC-曝气工艺处理,重点介绍了工程的调试启动。工程运行结果表明,出水水质稳定,COD为112mg/L,BOD5为23mg/L,SS为48mg/L,NH3-N为37.1mg/L,TN为49.6mg/L,硫化物为0.72mg/L,急性毒性(以HgCl2毒性当量计)为0.05mg/L,pH为8.22,处理后出水毒性和有机物浓度都大大降低,各项水质指标符合《化学合成类制药工业水污染物排放标准》(GB 21904-2008)的要求。     

Sinusoidal disturbance induced topology identification of Hindmarsh-Rose neural networks正弦扰动诱导复杂网络拓扑识别

Topology identification of complex networks is an important problem. Existing research shows that the synchronization of network nodes is an obstacle in the identification of network topology. Identification of the structure of the network presents an interesting challenge during the synchronization of complex networks. We developed a new method using the sinusoidal disturbance to identify the topology when the complex network achieves synchronization. Compared with the disturbance of all the nodes, the disturbance of the key nodes alone can achieve a very good effect. Finally, numerical simulation data are provided to validate our hypothesis.     

“Area Without Numbers”: Using Touchscreen Dynamic Geometry to Reason About Shape

Abstract

In this article, we report on two lessons aimed at introducing junior high school students to the idea of shearing in a touchscreen dynamic geometry environment. By using shearing, we hoped to shift students’ attention away from a formula-driven, computational conception of area toward a more geometric one. We found that the students were able to solve several problems involving the comparison of polygons based on verbal and diagrammatic explanations. We describe the features of the touchscreen dynamic geometry technology that supported their learning, as well as the specific role that the teacher played in modeling students’ reasoning about area.     

基于B/S结构的在线报障系统的设计与实现

随着办公自动化的推广、计算机应用及网络应用的深入,计算机故障及网络故障越来越多,故障管理工作变得越来越繁重和复杂,如何有效合理地解决这些计算机应用过中的故障和网络故障等问题是维护部门的一项重要工作.针对茂名职业技术学院计算机应用特点和技术现状,结合学院计算机故障应急处理方案,提出了建立计算机故障在线报障系统的解决方案.主要利用UML设计出基于B/S结构的故障处理系统的各模块类图、用例图、活动图等,在Linux系统的基础上,用PHP作为开发工具、MYSQL作为后台数据库,实现了在线报障系统各模块的功能.在线报障应用系统的主要功能是用户报障、管理员查询故障、管理员接单、提出解决办法、故障处理结果汇报等功能,系统的应用过程符合茂名职业技术学院的相关管理办法,具有一定的实际应用价值,克服了传统人工报障效率低、维护时间长、成本过高的弊端,从而降低了维护成本、提高了设备及网络利用率、规范了故障处理过程,较大地提高了学院计算机及网络故障处理的质量,使得管理人员的技术水平和故障的处理效率得到很大的提高,并为实训中心及设备管理部门等提供了有效的决策支持.     

Grain size effects on cyclic fatigue and crack-growth resistance behaviour of partially stabilized zirconia

Cyclic fatigue crack growth and crack-resistance behaviour was studied in partially stabilized zirconia (PSZ) with three different cubic-phase grain sizes following sub-eutectoid heat treatments. Raman spectroscopy was used to determine the extent of phase transformation around the cracks for both cyclic and monotonic loading conditions. All tests were on long, through thickness cracks using compact-tension specimens. Predictions of crack-tip shielding were made following determination of toughening parameters using crackresistance data. It was found that the dominant factors affecting cyclic fatigue-crack growth were the level of crack-tip shielding, as a result of phase transformation, and the intrinsic toughness of the material. Grain size did not appear to significantly affect fatigue crack-growth behaviour.     

基于SURF-HOG与显著性特征的红外可见光图像配准融合北大核心CSCD

针对现有红外与可见光图像配准不精确,边缘及细节纹理缺失,融合时间较长,不能突出重点目标等不足,提出一种基于SURF-HOG描述符与红外显著性特征的红外与可见光图像融合方法。首先,在红外与可见光图像配准阶段,在SURF(Speed-Up Robust Features,SURF)框架内构建基于HOG(Histogram of Oriented Gradient,HOG)的特征点描述符,并通过NNDR(Nearest Neighbor Distance Ratio,NNDR)进行红外与可见光图像的特征点匹配;其次,在显著特征提取阶段,先通过四叉树算法对源红外图像分解,然后通过贝塞尔插值法重建红外图像背景,接着分别对红外图像中的背景及目标进行自适应抑制以提取目标红外显著性特征;最后,结合已配准的可见光图像与重建后的红外图像以获取最终融合结果。实验结果表明,所提方法对不同场景下的红外与可见光图像具有较高的配准精度,不同场景下的融合结果不但主观视觉上具有显著的目标特征,同时背景纹理和边缘细节清晰,整体对比度适宜,运行时间最短,并且在客观评价指标上也取得了较好的效果。     

中国电力中长期市场分时段交易价格形成机制及模型

电力中长期市场分时段交易是中国电力市场改革的重要举措之一。针对当前电力中长期市场分时段交易价格形成机制不合理、不完善的问题,提出了中国电力中长期市场分时段交易价格形成机制及其模型。首先,分析影响中国电力中长期分时段交易价格形成的因素,提出电力中长期交易的4种典型场景;然后,综合考虑生产成本和用户效用,探索性地提出适用于中长期分时段交易的系统平均成本定价、用户失负荷价值定价、系统边际成本定价和发电企业失负荷价值定价4种成本定价机制,构建了基于成本定价的分时段交易定价模型;最后,以某省实际数据为例进行测算,验证了模型的有效性。     

Comprehensively Strengthened Metal-Oxygen Bonds for Reversible Anionic Redox Reaction

Introducing anionic redox in layered oxides is an effective approach to breaking the capacity limit of conventional cationic redox. However, the anionic redox reaction generally suffers from excessive oxidation of lattice oxygen to O₂ and O₂ release, resulting in local structural deterioration and rapid capacity/voltage decay. Here, a Na_0.71Li_0.22Al_0.05Mn_0.73O₂ (NLAM) cathode material is developed by introducing Al³⁺ into the transition metal (TM) sites. Thanks to the strong Al–O bonding strength and small Al³⁺ radius, the TMO₂ skeleton and the holistic TM–O bonds in NLAM are comprehensively strengthened, which inhibits the excessive lattice oxygen oxidation. The obtained NLAM exhibits a high reversible capacity of 194.4 mAh g^-1 at 20 mA g^-1 and decent cyclability with 98.6% capacity retention over 200 cycles at 200 mA g⁻¹. In situ characterizations reveal that the NLAM experiences phase transitions with an intermediate OP4 phase during the charge–discharge. Theoretical calculations further confirm that the Al substitution strategy is beneficial for improving the overlap between Mn 3d and O 2p orbitals. This finding sheds light on the design of layered oxide cathodes with highly reversible anionic redox for sodium storage.