较粗石英微粉制备超轻硬硅钙石隔热材料

用中位粒径20μm的粗石英和石灰石为原料，配制成Cao／SiO2摩尔比1．0，水固比20的料浆，倒入3000L的反应釜内进行水热反应，反应温度197℃，时间3h，合成的晶体料浆经XRD、SEM和TEM检测确认为由针状硬硅钙石缠绕组成的中空二次粒子球。球直径为30～100μm，球壁厚2～4μm。在料浆中加入纤维等辅助材料压制成型干燥后．即为容重小于130kg·m－3的超轻硬硅钙石隔热材料。     

2-乙氧基丙烯的合成

介绍了2-乙氧基丙烯(EPP)的用途及合成方法，采用自制催化剂由2，2-二乙氧基丙烷(DEP)合成2-乙氧基丙烯．总收率达到84．5％。     

三石─堇青石匣钵的研制

引入“三石”改善堇青石质匣钵性能,提高匣钵使用寿命。     

氧化石墨烯/石蜡复合相变乳液的制备及对流传热特性

为提高石蜡相变乳液的传热性能，通过添加氧化石墨烯(GO)，制备了GO/石蜡复合相变乳液并对其相关性能进行了表征。搭建了流动阻力、对流换热试验台，对比研究了石蜡相变乳液及GO/石蜡复合相变乳液的流动阻力特性和对流换热特性，试验结果表明，由于GO的亲水性，复合相变乳液都表现出较好的稳定性。当GO的质量分数为0.01％、0.02％、0.03％时，复合相变乳液的热导率分别增加了20.01％、30.50％、35.18％。添加GO使乳液的流动阻力略有增加，直管段最大增加了6.70%，90°弯管处最大增加了13.20%；对流传热系数随着GO浓度的增加而增大，当GO浓度为0.03％时，对流传热系数最大提高了43.90％。     

Thermodynamic Calculation of the Zirconia–Calcia System

An optimal thermodynamic data set for the zirconia–calcia system is evaluated by the CALPHAD (CALculation of PHAse Diagrams) method applied to experimental phase diagram and thermodynamic data. The liquid and C _ss (cubic ZrO₂ solid solution) are described by a subregular solution model. Three compounds, CaZr₄O₉, Ca₆Zr₁₉O₄₄, and CaZrO₃, are modeled as stoichiometric compounds. A regular solution model is applied to the other phases. Comparisons between calculated and measured phase diagrams and thermodynamic quantities show that most of experimental information is satisfactorily accounted for by thermodynamic calculations. The calculations also reasonably predict the measured electromotive force concerning the metastable C _ss.     

有机碱对莰烯直接乙酰化的影响

研究了在含氮有机碱存在下的莰烯直接乙酰化反应，结果表明，在反应中加入与莰烯等摩尔的六氢吡啶，有利于莰烯乙酰化反应，在反应液中的酰化产物ω－乙酰基莰烯含量最高达到56％，大大超过异构化产物乙酸异冰片酯。     

矿物质催化合成SP及SP-C

探索出一种以矿物质（橡胶填充剂）为催化剂合成ＳＰ及ＳＰ－Ｃ的新工艺。选择了最佳的工艺条件。此法制成的ＳＰ及ＳＰ－Ｃ产品性能优良、质量稳定。     

新型AGR管材的性能及应用前景

新型供水管材-AGR管(亚克力共聚PVC管)，采用超微粒子丙烯酸树脂弹性体与PVC接枝共聚而成，在保持原有PVC刚性性能基础上，提高了低温冲击性能及卫生性能，可用于供水管、抗震管及其他饮料和化工流体的输送。     

利用镁渣作混合材生产复合硅酸盐水泥试验研究

我国现在不仅有传统混合材生产的复合水泥，也有新开辟混合材的复合水泥。传统的混合材为高炉水渣、火山灰、粉煤灰、石灰石、炉渣等；新开辟的混合材有磷渣、增钙液态渣、玄武岩、页岩、铬铁渣等，镁渣是金属镁厂提炼金属镁之后排放出的工业废渣，我国在镁渣复合水泥方面的研究与开发资料报导很少。制备优良性能的复合水泥，关键在于所使用的不同种类的混合材能够优势互补，本实验拟采用镁渣与矿渣进行复合生产镁渣复合硅酸盐水泥。     

A kinetic investigation of coal liquefaction at short reaction times

Coal liquefaction kinetics have been studied at very short reaction times (less than 250 seconds) in order to emphasize the initial underlying physical and chemical processes involved. These studies were made possible by the use of a continuous flow stirred tank reactor (CSTR) which avoids the problems of slow heat up and cool down associated with the massive equipment required for running high-temperature and high-pressure liquefaction reactions. Preliminary physical (NMR and ESR) and chemical analytical results are presented on the coal liquids and reaction residues from Illinois No. 6 hv bituminous and Wyodak Black Thunder subbituminous coals.

ESR results showed that radical concentration in the solid residue changed during coal liquefaction. These changes were accompanied by changes in the NMR-derived aromaticity. The rate of decrease of organic-based radicals was different for Wyodak Black Thunder and Illinois No. 6 coals, perhaps indicating a different mechanism for the quenching of radicals in these bituminous and subbituminous coals. NMR spectra of the liquid products indicated that the initially produced material was relatively aromatic, and that subsequent products had lower aromatic content. This is consistent with secondary hydrogenation of the primary liquefaction products. Finally, the total oxygen contents of the coal residues decreased gradually during the first three minutes of coal liquefaction at 390°C. A corresponding decrease in the hydroxyl content of these residues was also noted.