VO2/GaAs异质结的制备及其光电特性研究

采用直流磁控溅射和后退火氧化工艺在p型GaAs单晶衬底上成功制备了n-VO_2/pGaAs异质结,研究了不同退火温度和退火时间对VO_2/GaAs异质结性能的影响,并分析其结晶取向、化学组分、膜层质量以及光电特性。结果表明,在退火时间2 h和退火温度693 K下能得到相变性能最佳的VO_2薄膜,相变前后电阻变化约2个数量级。VO_2/GaAs异质结在308 K、318 K和328 K温度下具有较好的整流特性,对应温度下的阈值跳变电压分别为6.9 V、6.6 V和6.2 V,该结果为基于VO_2相变特性的异质结光电器件的设计与应用提供了可行性。     

Transition from random packing to stable state in a continuously avalanching granular flow

We investigate the transition evolution from the initial state with the random packing of the particles to the stable state in which successive avalanches exhibit consistent characteristics under the slumping regime. It is found that there exist three distinct stages in the transition evolution, considering the change of the volume fraction. The coordination number is almost unchanged during the transition evolution, which indicates the particle contact form is consistent in the three stages. The pause phenomena are discovered in some avalanches, and the probability of pause occurrence increases continuously in the three consecutive stages. We also explore the distribution of particles in the passive layer at the stable state. The particles in the middle region of the passive layer have the closest packing status, and the deeper the region is located, the later it reaches the stable state.     

Fabrication of Cu/graphite film/Cu sandwich composites with ultrahigh thermal conductivity for thermal management applications

Effective thermal management of electronic integrated devices with high powder density has become a serious issue, which requires materials with high thermal conductivity (TC). In order to solve the problem of weak bonding between graphite and Cu, a novel Cu/graphite film/Cu sandwich composite (Cu/GF/Cu composite) with ultrahigh TC was fabricated by electro-deposition. The micro-riveting structure was introduced to enhance the bonding strength between graphite film and deposited Cu layers by preparing a rectangular array of micro-holes on the graphite film before electro-deposition. TC and mechanical properties of the composites with different graphite volume fractions and current densities were investigated. The results showed that the TC enhancement generated by the micro-riveting structure for Cu/GF/Cu composites at low graphite content was more effective than that at high graphite content, and the strong texture orientation of deposited Cu resulted in high TC. Under the optimizing preparing condition, the highest in-plane TC reached 824.3 W·m⁻¹·K⁻¹, while the ultimate tensile strength of this composite was about four times higher than that of the graphite film.     

Effects of short carbon fiber on the macro-properties,mechanical performance and microstructure of SiSiC composite fabricated by selective laser sintering

Selective laser sintering was combined with reactive melt infiltration to fabricate SiSiC part, and the effects of carbon fiber (C_f) on the properties of the SLS green body, the carbonized and final SiSiC sample were investigated. Results show that the addition of an appropriate amount of C_f (1.59 wt%~2.97 wt%) can increase the bulk density and geometric precision of the sample at all stages, and improve the mechanical properties of green and carbonized samples. The main phases composed of the SiSiC composite were free Si, a-SiC, β-SiC, plus a very small amount of Al–Si alloy. With 1.59 wt% C_f addition, a relatively comprehensive favorable macro-properties of both the green sample and carbonized sample was achieved, and the homogeneous microstructure of the latter favored the decreased free Si content and increased β-SiC content of the final composite. The evolution mechanism of C_f added to the raw material is inferred to be the mutual diffusion of [C] and [Si] that occurred at the C_f/Si melt boundary leading to the formation of the siliconized C_f with relatively large diameter size (24.3 μm) and high aspect ratio (>30). Amorphous C, which derived from the pyrolysis of epoxy resin E12, undergone a dissolution-precipitation mechanism with the formation of fine-grain β-SiC.     

Solvent-free synthesis of C9 and C10 branched alkanes with furfural and 3-pentanone from lignocellulose

Jet fuel range branched alkanes were first synthesized under solvent-free conditions by the aldol condensation of furfural and 3-pentanone from lignocellulose followed by the one-step hydrodeoxygenation (HDO). Among the investigated solid base catalysts, CaO and KF/Al₂O₃ demonstrated the highest activity for the aldol condensation reaction of furfural and 3-pentanone. The aldol condensation product of furfural and 3-pentanone (liquid at room temperature) was directly hydrodeoxygenated to 4-methyl-nonane and 4-methyl-octane. These alkanes have low freezing points (174.1 K and 159.8 K) and can be blended into jet fuel without hydroisomerization. Among the investigated HDO catalysts, the Ni-Cu/SiO₂ exhibited the best performance.     

二氧化碳跨临界系统参数间相互关系的热力学第二定律的分析与研究

本文利用热力学第二定律（Yong） 的(exergy)分析法，对二氧化碳跨临界制冷循环系统进行了仿真和分析，分析显示：炯效率随着放热压力的变化而变化，其最大值出现在最优放热压力处，同时，本文还就气体冷却器口温度、蒸发温度及蒸汽过热度对系统Yong效率的影响进行了仿真和分析。     

Windows平台下的汉字输入法机制及应用

作者在Windows平台下，通过对E码汉字输入法系统实现的软件研发过程，本质地认识了Windows平台下的汉字输入法系统的实现原理及其基本方法；本文对Windows IME系统的两个主要组成部分：转换引擎和界面模块以及二者之间的交互关系进行了深入的分析，并揭示了Windows平台下整个汉字输入法系统的底层运转机制。     

传感技术与RFID在血液管理分析中的运用

由于血液管理对于环境条件的特殊要求，针对血液管理分析提出了将传感技术与RFID技术结合后应用于其中的想法。简要介绍了RFID传感器标签的设计，分析了将其运用于血液管理分析后对加强流程监控、提高工作效率的好处，并主要从血液的出入库管理、跟踪管理、质控管理三个方面详细描述，阐明了方法的可行性。     

Theoretical investigations on the spin Hamiltonian parameters for Er3+ ion in LiYF4

The spin Hamiltonian parameters g_∥, g_⊥, A_∥ and A_⊥ for Er³⁺ ion in LiYF₄ are investigated by using the perturbation formulas of these parameters for a 4f¹¹ ion in tetragonal symmetry. In these formulas, the contributions to the spin Hamiltonian parameters from the second-order perturbation terms and the admixtures of different states are considered. The relevant crystal field parameters are calculated from the superposition model and the local structural parameters of the Y³⁺ site occupied by impurity Er³⁺. The theoretical optical spectra within ⁴I_15/2 and ⁴I_13/2 states and the spin Hamiltonian parameters obtained in this work are consistent with the observed values.     

太阳能热风发电技术研究进展

介绍了太阳能热风发电的产生背景、技术原理和特点。太阳能热风发电能够实现由太阳能到空气动能,最终到电能的转变,具有环保无污染、运行维护简单、缓解常规能源消耗等特点。简要介绍世界上第1座试验性质的太阳能热风发电站。对太阳能热风发电技术相关研究历程从试验研究和理论研究2个方面做了综述,重点介绍了澳大利亚电站的建设进展及最新相关学术研究进展,包括过渡段理论及试验研究、系统数值模拟和太阳能热风发电技术在高山地区的应用等。介绍我国太阳能资源情况,指出我国太阳能资源丰富,适合建造大型太阳能热风发电站。