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21.
燃料变化对气体燃烧器燃烧性能影响的数值模拟研究 总被引:1,自引:0,他引:1
该文以John Zink公司一种瓦斯燃烧器为几何原型,对燃烧器和稳焰旋流器附近三维复杂形状未作任何简化,生成了包括燃烧器和炉膛的结构化网格,换用甲烷、乙烷、丙烷和丁烷四种不同的气体燃料,用标准的k-ε湍流模型、k-ε-g湍流扩散燃烧模型和蒙特卡洛辐射换热模型对燃烧器内的流动及燃烧状况进行了全尺寸数值模拟,预报了燃烧器内流场和温度场,考察燃料变化对炉内温度场的影响规律及燃气射流特性参数(Re·D1)对火焰长度的影响,对进一步优化设计燃烧器、提高加热炉热效率有很好的指导意义。 相似文献
22.
23.
材料合成新技术──自蔓延高温合成 总被引:3,自引:0,他引:3
自蔓延高温合成(SHS)是目前被广泛开发用于工业陶瓷和其它先进材料制备的一种独特的先进工艺技术。本文对生产高科技材料的自蔓延高温合成技术方法进行了介绍,并分析了该工艺的特点及其理论基础,同时还讨论了影响材料合成的因素。 相似文献
24.
高压氮气中自蔓延燃烧合成氮化钛 总被引:1,自引:0,他引:1
利用钛粉在高压氮气中的自蔓延燃烧合成(SHS),制备了含氮量较高的TiN,研究了反应物的松装密度、氮气压的改变与稀释剂的加入对燃烧波蔓延速率和产物转化率的影响,还观察到燃烧方式的改变。 相似文献
25.
This paper deals with the gasless combustion problem in an infinite one-dimensional medium. The possibility of the existence of steadily propagating reaction waves is stated for system models with nonzero reaction rates everywhere but at the boundaries. Two forms for the chemical reaction rate dependence on the temperature are considered: the classical Arrhenius, and a modified Arrhenius incorporating and ignition temperature. The equations for the steadily propagating waves are studied in the phase-plane of the temperature and its derivative. The analysis first addresses the question of whether steadily propagating waves are admissible. Then bounds for the propagation velocity are sought and found. The results of the closed-form analysis are successfully tested against numerical experiments. Non-steady propagation regimes are also found, and regions in the parameter space associated with different asymptotic dynamical behaviour are identified. 相似文献
26.
Improved sooting tendency measurements for aromatic hydrocarbons and their implications for naphthalene formation pathways 总被引:1,自引:0,他引:1
Sooting tendencies have been determined for aromatic hydrocarbons using a new definition: the maximum soot volume fraction fv,max measured in a coflow methane/air nonpremixed flame whose fuel is doped with 400 ppm of the test hydrocarbon. These fv,max were converted into apparatus-independent yield sooting indices (YSIs) by the equation YSI=C×fv,max+D, where C and D are apparatus-specific parameters chosen so that YSI-benzene = 30 and YSI-1,2-dihydronaphthalene = 100. The dopants were added to the fuel mixture with a syringe pump and fv,max was measured with laser-induced incandescence. YSI was determined for 6 cycloaliphatics and for 62 aromatics, which included 28 alkylbenzenes, 10 alkenylbenzenes, 10 alkynylbenzenes, 25 multiply substituted benzenes, 6 two-ring aromatics, and 6 substituted benzenes with heteroatoms in the side chains. The YSIs correlate well with literature values of threshold sooting index (TSI), which is a more traditional sooting tendency based on the height of pure-fuelled flames at the smoke point. This agreement indicates that fv,max and smoke height are equivalent measures of sooting tendency and that YSI is largely apparatus-independent. However, the YSIs have a total uncertainty of ±3%, which is substantially better than the TSIs, and the number of aromatic YSIs reported here is more than double the number of aromatic TSIs in the literature. The YSIs depend strongly on molecular structure; thus they provide information about the chemical kinetic reaction mechanisms responsible for fuel decomposition and hydrocarbon growth from a broad cross section of one-ring aromatics. Important naphthalene formation pathways appear to include acetylene addition to ethynylphenyl, propargyl addition to benzyl, and methyl addition to indenyl. This last pathway is particularly significant because it converts indene quantitatively to naphthalene and because the side chains in many alkenylbenzenes and alkynylbenzenes cyclize to form five-membered rings. 相似文献
27.
Fang Ziien 《Petroleum Science and Technology》1994,12(5):705-714
A model of pyrolysis gasifier, which is mainly composed of a pyrolysis, a cracking and a combustion chamber, it developed to predict its performance parameters and to simulate its operation. Toe model consists of a pyrolysis-cracking sub-model, a secondary gasification sub-model and a combustion sub- model, of which the pyrolysis-cracking sub-model is modified to predict components of tbe pyrolysis gas. Then, It with the other two sub-models can predict components, heating value and flow rate of the produced gas, thermal efficiency and total energy efficiency of the gasifier as ell. Crank-Nicolson Scheme (half implicit difference formulation) in which the time step is not confined by stability and the cutting error is small, is applied to solving the model whose differential equations are nonlinear and have no analytic solution. Theo, the nonlinear difference algebraic equations are solved by interalions, which requires less storage of computer. Underrelaxation is applied to avoiding divergence of Causs-Seidel interations. Finally, the simulated results are input to Software Lotus 1-2-3, by which the results are printed and graphed so as to compare with the experimental ooes, and it shots acceptable agreement, thus validate the model. 相似文献
28.
摘要将燃烧合成技术与传统焊接技术相结合,以Ti-Ni体系为连接材料研究了08钢/1Cr18Ni9不锈钢焊接焊缝的形成过程,探索了Ti-Ni加压燃烧合成的过程及产物的形成机制,焊缝与基体的结合行为。目的在于开发出一种新型层状金属复合材料的制备工艺。 相似文献
29.
Fine powder of TiC was prepared by self-propagating high-temperature synthesis(SHS)method with re-duction stage.The influence of diluent and relative density of the sample on both combustion rate and combus-tion temperature has been studied.The combustion reaction in the system of TiO_2-Mg-C begins at the meltingof Mg.The propagation of combustion wave is related to the gasifying of Mg.The activation energy of theprocess has an approximate linear dependence on the porosity of the sample. 相似文献
30.