Improvement of Pt/ZrO2 by CeO2 for high pressure CH4/CO2 reforming

CH₄/CO₂ reforming over Pt/ZrO₂, Pt/CeO₂ and Pt/ZrO₂ with CeO₂ was investigated at 2 MPa. Pt/ZrO₂, which shows stable activity under 0.1 MPa, and Pt/CeO₂ showed gradual deactivation with time at the high pressure. The deactivation was suppressed drastically on Pt/ZrO₂ with CeO₂ prepared by different impregnation order (co-impregnation of Pt and CeO₂ on ZrO₂, and consecutive impregnation of Pt and CeO₂ on ZrO₂). The amount of coke deposition was found insignificant and similar among all the catalysts (including Pt/ZrO₂ and Pt/CeO₂). Catalytic activity after the reaction for 24 h was in agreement with Pt particle size after the reaction for same period, indicating that the difference of the catalytic stability is mainly dependent on the extent of Pt aggregation through catalyst preparation, H₂ reduction, and the CH₄/CO₂ reforming. Pt aggregation and the amount of coke deposition were least pronounced on (Pt–Ce)/ZrO₂ prepared by impregnation of CeO₂ on Pt/ZrO₂ and the catalyst showed highest stability.     

Performance evaluation of hexane-extracted oils from genetically modified soybeans

Soybeans produced by induced mutation breeding and hybridization were cracked, flaked and hexane-extracted, and the recovered crude oils were processed to finished edible oils by laboratory simulations of commercial oil-processing procedures. Three lines yielded oils containing 1.7, 1.9 and 2.5% linolenic acid. These low-linolenic acid oils were evaluated along with oil extracted from the cultivar Hardin, grown at the same time and location, and they were processed at the same time. The oil from Hardin contained 6.5% linolenic acid. Low-linolenic acid oils showed improved flavor stability in accelerated storage tests after 8 d in the dark at 60°C and after 8h at 7500 lux at 30°C, conditions generally considered in stress testing. Room odor testing indicated that the low-linolenic oils showed significantly lower fishy odor after 1 h at 190°C and lower acrid/pungent odor after 5 h. Potatoes were fried in the oils at 190°C after 5, 10 and 15 h of use. Overall flavor quality of the potatoes fried in the low-linolenic oils was good and significantly better after all time periods than that of potatoes fried in the standard oil. No fishy flavors were perceived with potatoes fried in the low-linolenic oils. Total volatile and polar compound content of all heated oils increased with frying hours, with no significant differences observed. After 15 h of frying, the free fatty acid content in all oils remained below 0.3%. Lowering the linolenic acid content of soybean oil by breeding was particularly beneficial for improved oil quality during cooking and frying. Flavor quality of fried foods was enhanced with these low-linolenic acid oils.     

Studies on the synthesis and properties of poly(amide-azomethine)

Homopolymer and copolymer of poly(amide-azomethine) were synthesized from the corresponding diamines and dialdehydes. The polymerization was proceeded in the mixed solvent of o-chlorophenol and m-cresol (1: I by volume) at 0 °C for I S h. The inherent viscosities of the new aromatic poly(amide-azomethine)s are in the range of 0.51 to 2.31 dl/g. These polymers were soluble in sulfuric and formic acid. The TGA results show that no weight loss up to 400 °C under nitrogen atmosphere, which suggests the relatively good thermal stabilities.     

蜂窝式构件长细比的计算方法

为了进一步研究蜂窝构件稳定承载性能,以现有长细比计算理论为基础,结合蜂窝构件的受力机理和界面特性,提出了蜂窝构件长细比计算中相关参数的计算方法．同时,结合理论推导和数值分析结果,提出了蜂窝构件换算长细比建议计算公式．     

基于相关分析的交流电力有功功率测试研究

基于相关性分析,提出了一种适合于交流电力智能传感器的有功功率测试方法,并将其与传统参数定义法进行了分析、比较,指出在不增加任何额外硬件开销和计算量的情况下相关性分析法能有效抑制采集信号中干扰的影响,从而简化系统、降低成本、提高实时性等测试性能。实验表明,相对于参数定义法,相关性分析法可减少约70%用于分析的采样点数,干扰幅值的要求从信号幅值的3%可放宽到信号幅值的12%左右。     

细观损伤力学在气体钻井井壁稳定性研究中的应用

用RFPA2D软件建立气体钻井井眼稳定的损伤力学模型,通过跟踪声发射信号研究井壁围岩在应力下的损伤演化,从细观损伤力学的角度探讨气体钻井时井壁围岩的损伤演化,以及转换介质后井壁失稳的原因。研究发现,气体钻井时井眼周围一定范围内出现损伤区,损伤区内形成微裂纹和裂缝,转换介质后由于泥浆渗入、压力波动而导致损伤区坍塌。     

靖边气田盒8段钻井液封堵性能提高方法研究

高桥地区靖边气田石盒子组盒8段砂岩储层井径扩大严重,引起测井信息失真、地质储量评价不准确等一系列问题.通过优化CaCO3酸溶性封堵剂的复配比例和添加成膜剂及润湿反转剂降低砂岩自吸两种途径提高钻井液的封堵性能,从而实现井壁稳定.改进后钻井液对盒8段的封堵率提高至95.6%,砂岩自吸量降低85%.     

非硅型氧漂稳定剂SHT稳定性能的研究

文章对作者自制的非硅型氧漂稳定剂SHT进行了双氧水的稳定性试验,结果表明:稳定剂SHT能耐强碱和高温,适用于常规的双氧水漂白工艺,可单独使用;可在硬水中使用,尤其是在Ca2+、Mg2+浓度较高的情况下,对Ca2+、Mg2+等离子仍然具有螯合作用;能克服产品在织物前处理过程中出现的各种质量问题,高效地保证设备的正常运转;并且采用稳定剂SHT能够缩短工艺流程,各项应用性能优异,综合成本低,是目前市场上不可多得的非硅型双氧水稳定剂。     

一类Bayes公式的推导及在小子样评估中的应用

工程中昂贵复杂系统的整机试验通常是小子样的,因此需要结合大量的先验信息进行系统评估,但这可能造成小子样的整机试验数据的信息被淹没。与通常考虑加权的融合方法不同,基于精度评估的正态逆伽玛分布推导了一类Bayes公式,将所有先验信息等价为单个整机试验数据,设计了相应的分布参数,结合等价先验样本量得到推导的后验结果,并给出案例分析了这类Bayes公式的应用范围和合理性。     

一类非线性组合系统新的稳定性条件

研究组合大系统存在非线性扰动和不确定性时的稳定性问题。通过对微分方程解的结构研究,应用矩阵相似变换和矩阵指数的特性,将原非线性组合系统的稳定性问题转化为线性系统的稳定性问题。根据线性系统渐近稳定的充分条件,导出了原系统渐近稳定新的判定准则。最后运用数值实例说明了该方法的有效性和可行性。