不同浊度下的泥沙对水体镉、铅、砷去除的影响分析

针对流域突发性重金属污染,不同浊度下的泥沙对重金属有一定的去除效果。以浊度为指示指标,通过试验研究了常温(25 ℃)和低温(5 ℃)条件下浊度50～650 NTU(Nephelometric Turbidity Unit)范围内泥沙对重金属镉、铅、砷吸附去除的影响。试验结果表明:泥沙对重金属镉、铅、砷的去除效果为铅＞镉＞砷,其中铅的去除率达到99%。浊度与能处理达标的最高重金属浓度呈线性关系,常温下浊度与能处理达标的最高镉、铅、砷浓度关系曲线的相关系数分别为0.996、0.998、0.999,低温下其相关系数分别为0.999、0.996、0.998。常温较低温更利于泥沙对重金属镉、铅、砷的去除,能去除更高浓度的重金属,达到生活饮用水卫生标准。     

Determination of tetrachloroethylene—Results of a collaborative study and the standardized method

The development, by collaborative study, of a standardized method for the determination of tetrachloroethylene in olive oils is described. The results of the study, which was carried out in 1989 under the direction of the International Olive Oil Council (IOOC), are presented and show that tetrachloroethylene can be readily determined, to an acceptable degree of precision, by gas-liquid chromatography with electron capture detection. A limited number of results obtained for the determination of trichloroethylene and chloroform by the same method indicate that a similar precision could be obtained with the method when determining these solvents also.     

萘降解菌的筛选及降解性能的初步研究

微生物降解是多环芳烃从土壤和水环境中消失的主要途径。本文从加油站废油排放口附近被污染土壤中筛选到两种降解萘的混合菌H1、H2并从中分离出一株纯菌C_1。研究发现,利用纯无机盐培养基加萘作为唯一碳源要比加入其它营养物质的培养基对于筛选萘降解菌更为有利。H_1、H_2和C_1均能以萘为唯一碳源生长,在萘初始浓度为1000mg/L的纯无机盐培养基中培养40h后,培养液中微生物数量分别增长10倍以上,利用气相色谱测得萘的降解率都达到99．6％以上。     

修复土壤,腐植酸能做些什么

我国土壤污染形势严峻,已成为农产品安全和农业可持续发展的一大障碍."十一五"期间已将防治土壤污染列入重要议事日程,"全国土壤污染状况调查和防治项目"业已启动,2006年11月<农产品质量安全法>也开始实施.腐植酸学术界及行业又面临新的机遇和挑战.介绍了我国土壤污染的现状及其治理技术,阐述了腐植酸类物质(HS)修复污染土壤的研究进展、存在问题及应用的可行性,并对今后的研究开发及应用方向提出若干建议.     

Catalytic conversion of MTBE to biodegradable chemicals in contaminated water

The behavior of different acid zeolites in the hydrolysis at room temperature of methyl tert-butyl ether (MTBE) was studied with reference to the possibility of its conversion to more biodegradable products in underground water contaminated by MTBE. The effect of the structure of the zeolite and SiO₂/Al₂O₃ ratio was analyzed. The results indicate that acid H-MFI and H-BEA zeolites are effective in both adsorption and hydrolysis of MTBE and may be applied for both in situ underground water remediation and as protection barrier for wells or leaking tanks. However, other zeolites (mordenite and faujasite) result completely inactive. Furthermore, contrary to what was expected, the increase of the Si/Al ratio promotes the reactivity which is determined by the resistance to diffusion of MTBE in the pores of zeolites and the resistance of back-diffusion of the reaction products.     

陈家冲垃圾填埋场地下水环境健康风险评价

垃圾填埋是目前国内处理城市生活垃圾的主要方式,由垃圾渗滤液引发地下水环境污染已成为当前主要的水环境问题之一。选择武汉市陈家冲垃圾填埋场为研究对象,通过对该区周边地下水布孔取样和监测,分析了垃圾填埋场对其周围地下水环境的影响。结果表明:研究区地下水的主要污染因子为Pb、Cd和Fe,且各污染物的浓度与采样深度、井距呈负相关关系。垃圾填埋场产生污染的影响范围主要在距离800m以内、深度小于5.5m的地下水。为进一步了解该区地下水对人体健康危害的风险程度,对研究区地下水进行了水环境健康风险评价,结果显示:研究区各采样井地下水的总风险值在2.71×10~(-4)/a~7.12×10~(-3)/a,均超过国际辐射防护委员会(ICRP)推荐的最大可接受值5.0×10~(-5)/a,主要风险因子为基因毒物质Cd和Cr(VI)以及躯体毒物质硝态氮;其中,Cd和硝态氮所致的健康风险值超标率100%,而Cr(VI)的健康风险值超标率为50%,对暴露人群存在健康危害风险。此外,对男性和女性健康风险值的研究显示,研究区地下水环境中污染物的男性健康危害风险值普遍高于女性。     

Adhesive Bonding of Oil-Contaminated Steel Substrates

Durability of adhesive bonds formed by curing epoxies against oil-contaminated steel substrates using amidoamine curing agents was determined during exposure to boiling water. The most durable bonds were obtained using amidoamine curing agents with relatively low amine numbers and by blending silane coupling agents such as γ-glycidoxypropyltrimethoxysilane (γ-GPS) and N-(2-aminoethyl)-3-aminopropyltrimethoxy silane (AAMS) into the adhesives. When X-ray photoelectron spectroscopy (XPS) was used to characterize the failure surfaces of the adhesive joints after exposure to boiling water, it was determined that adhesives prepared using amidoamine curing agents with low amine numbers were able to displace the oil from the steel surface but adhesives prepared with amidoamine curing agents with high amine numbers were not. Results obtained from XPS also showed that the amino groups on the substrate fracture surfaces of joints prepared using curing agents with low amine numbers were protonated whereas the amino groups in the bulk adhesive were not, indicating that there was a chemical interaction between the curing agent and the hydrated surface of the substrate. It was also shown using infrared spectroscopy that the amidoamine curing agents formed salts with calcium compounds in the oil.     

在工程设计中采用循环流化床锅炉必须做好调查研究工作

本文概述了循环流化床锅的现状及发展,针对普遍存在的问题,指出在工程设计采用这类锅炉时,必须做好调查研究工作,向用户提供优质服务。     

水基(乳液)胶粘剂微生物污染及其罐内防腐效果测试

对广东省部分水基(乳液)胶粘剂生产企业微生物污染的来源和种群进行了调查,建立以微生物攻击挑战性试验来快速判定水基(乳液)胶粘剂罐内防腐效果的评价方法,探索该类胶粘剂微生物污染的有效防治技术。     

浅论食品化学污染及其防治策略

分析了食品化学污染的主要途径,以及这些污染物对人体健康的危害性,对食品化学污染的防治策略进行了探讨。