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21.
Shuangjian Li Xiaoqin Zhao Yulong An Duanduan Liu Huidi Zhou Jianmin Chen 《Ceramics International》2018,44(15):17864-17872
Thermal sprayed ceramic coatings have extensively been used in components to protect them against friction and wear. However, the poor lubricating ability severely limits their application. Herein, yttria-stabilized zirconia (YSZ)/MoS2 composite coatings were successfully fabricated on steel substrate with the combination of thermal spraying technology and hydrothermal reaction. Results show that the synthetic MoS2 powders are composed of numbers of ultra-thin sheets (about 7 ~ 8?nm), and the sheet has obvious lamellar structure. After vacuum impregnation and hydrothermal reaction, numbers of MoS2 powders, look like flowers, generate inside the plasma sprayed YSZ coating. Moreover, the growing point of the MoS2 flower is the intrinsic micro-pores of YSZ coating. The friction and wear tests under high vacuum environment indicate that the composite coating has an extremely long lifetime (>?100,000 cycles) and possesses a low friction coefficient less than 0.1, which is lower by about 0.15 times than that of YSZ coating. Meanwhile, the composite shows an extremely low wear rate (2.30?×?10?7 mm3 N?1 m?1) and causes slight wear damage to the counterpart. The excellent lubricant and wear-resistant ability are attributed to the formation of MoS2 transfer films and the ultra-smooth of the worn surfaces of hybrid coatings. 相似文献
22.
The effect of the acidic hairy layer length on the interdiffusion of polymer between particles and as a consequence on the mechanical properties of the films produced from waterborne coatings has been studied. In order to isolate this effect, latexes with the same particle diameter and molecular weight but stabilized with poly(acrylic acid)-block-poly(butyl acrylate) (PAA-b-PBA) block copolymers of controlled and different lengths were prepared. Tensile strength measurements showed at the macroscopic level that the presence of AA chains in the particle surface reduced the mechanical properties of the films dried at room temperature, being its effect worse the longer the AA chain length. Higher annealing temperatures erased the negative effect of the acidic hairy layer on mechanical properties. The neutralization with NaOH instead of with NH4OH also led to worse mechanical properties. These macroscopic results were supported by Fluorescence Resonance Energy Transfer (FRET) experiments that showed that at the microscopic level, the extent of interdiffusion occurred slower when the AA chains in the particles surface increased, the annealing temperature was lower and when NaOH was used as neutralizing agent instead of NH4OH. 相似文献
23.
水驱后的残余油膜将贴于孔隙壁面,为壁面边界层流体,处于三相界面的包围和共同作用下。目前的调研结果显示,油膜的组成及力学特性沿孔壁方向上是变化的。在化学驱过程中油膜不仅受到驱油剂的驱替作用。还受驱油剂/油界面张力、油/固体界面张力及驱油剂/固体界面张力的阻碍作用。由于油膜组成、力学特性及相间作用的复杂性.以往对油膜驱替机理的研究都是从微观实验的角度对现象作观察和定性解释。本文根据水驱后残余油膜在油藏孔隙中存在的特点,提出了油膜驱替的简化模型。基于油膜驱替的微观实验,采用数值方法从定量的角度分别计算了不同黏弹性驱油剂在不同的驱油剂/原油界面张力作用下对残余油膜的驱替效率。考察了驱油剂的流变性、驱油剂/油界面张力、驱替速度等因素对驱替不同厚度油膜的影响规律。进一步探讨了驱油剂/原油界面特性和流变性在驱替残余油中的综合作用。研究结果表明,驱油剂对油膜的驱替始于驱油剂/油界面,要同时克服驱油剂/油界面约束力和油膜的屈服应力。降低界面张力、增强驱油剂的黏弹性、增加驱替速度,有利于提高驱替残余油膜的驱替效率。适当增加驱油刑的黏弹性可以放宽驱替薄油膜时对超低界面张力的要求。图13参9。 相似文献
24.
基于调谐频率与分频处理的高分辨率反演技术 总被引:12,自引:2,他引:10
讨论了基于调谐频率与分频处理的高分辨率反演技术,给出了方法的基本原理,即利用地震数据的调谐频率和分频处理分析,半定量地确定储层厚度,并将其作为地震反演的约束条件。方法的实现过程是:通过层状地质模型的地震正演模拟,建立不同主频子波时地层厚度与调谐频率的关系;利用地震资料时-频分析技术,实现地震资料分频处理;利用合成地震记录标定地震子波主频;利用分频处理结果,借助于调谐频率分析与调谐振幅分析,给出地震反演约束条件;利用反演算法消除地震子波影响,提高和拓展地震资料的频带范围,实现储层的高分辨率成像。普光地区的应用实例表明,调谐频率与分频处理的高分辨率反演方法无需对储层空间变化规律进行假设,适用于强非均质碳酸盐岩储层的高分辨率成像。 相似文献
25.
Edible film from water-soluble fish proteins were developed by casting film solution on leveled trays and effects of pH (9.5, 10.0 and 10.5), heating temperature (60, 70 and 80 °C), and heating time (10, 20 and 30 min) of the film solution on various film properties were determined using Response Surface Methodology (RSM). The impact of pH and heating temperature of film solution was more significant, overall, on the film's properties than heating time. Contour plots of tensile strength and elongation at break was highest at pH of 10.0 at 70 °C (2.75-3.02 MPa) but low in elongation at break (6.35-9.16%), while water vapor permeability and oxygen permeability were at their lowest (58.55-65.96 g mm/m2 d kPa and 351.33-624.18 cm3 μm/m2 d kPa). There was a direct correlation between the films’ and proteins’ solubility on one hand, and heating temperature of film solution on the other, which reversed with change in pH of film solution. Film color was darker and more yellowish with increase in the pH of film solution. 相似文献
26.
碳纳米管膜的场致发射电流密度仅由它表面的宏观电场决定,无论其表面形状是平的还是半球状的。对于理想的平行板电极系统,其表面电场强度均匀(UId),发射电流密度、总电流与发射面积成正比:对于半球一平面电极系统半球形的阴极存在一个宏观场增强因子ks,一个与两极距离和球半径之比(d/r)相关的函数,其表面的平均场强为ks U/d。对于d/r=0,ks=1,d≥r的情况,ks接近于常数。对于10〈d/r〈100的情况,存在一个经验的表达式:ks=1+0.15d/s=0.005(d/r)^2。在引入ks后,不同作者给出的平面电极系统和半球一平面电极系统碳纳米管膜的场致发射电流I与宏观表面电场强度E的关系都可以近似用-经验公式描述:I=a(E-Eo)^b,a,b为常数。该经验公式可为稳定生产的CNT膜片应用产品设计提供方便。 相似文献
27.
1 Influence of PAMAon Boundary Fil mFormation and Friction1.1 Experi mental methodsUltra-thin optical interferometry has been used tostudy thinlubricating fil ms for more than a decade and theexperi mental details of this technique have been reportedpreviously[1].The principle of the test setup is shown inFigure1.A polished steel ball is loaded and rolled againstthe flat surface of a glass disc that is coated with a thinsemi-reflecting chromiumlayer and a silica spacer of about500nmthickne… 相似文献
28.
Hiroshi Takamatsu Hikaru Yamashiro Nobuo Takata Hiroshi Honda 《International Journal of Refrigeration》2003,26(6):79
Heat and mass transfer in a falling film vertical in-tube absorber was studied experimentally with LiBr aqueous solution. The presented results include the effect of solution flow rate, solution subcooling and cooling water temperature on the absorption in a smooth copper tube 16.05 mm I.D. and 400 mm long. The experimental data in the previous report for a 1200-mm-long tube was also re-examined and compared. It was demonstrated by the observation of the flow in the tube that the break down of the liquid film into rivulets leads to deterioration of heat and mass transfer at lower film Reynolds number or in longer tubes. An attempt to evaluate physically acceptable heat and mass transfer coefficients that are defined with estimated temperature and concentration at the vapor–liquid interface was also presented. 相似文献
29.
30.
金刚石膜在真空电子器件输出窗中的应用 总被引:3,自引:0,他引:3
综述了金刚石膜的性能和制备方法,着重介绍丁国内外常用的封接工艺,讨论了该材料在mm波器件中的应用前景。 相似文献