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61.
Robert J. Meier 《Polymer》2002,43(2):517-522
The long standing question of how long a trans sequence in a polyethylene needs to be in order to contribute to the all-trans Raman bands at 1060 and 1130 cm−1 is addressed. Various hexadecane, C16H34, conformers were studied using ab initio type calculations revealing vibrational frequencies and intensities. We found that only trans sequences longer than 10 trans bonds reveal Raman intensity primarily selectively at the same frequencies as the C-C stretching modes arising from crystalline polyethylene. Since it is statistically highly unlikely that such long trans sequences occur in the amorphous phase, intensity arising from all-trans sequences not belonging to crystalline structure may only be expected as a consequence of strong non-equilibrium conditions (e.g. shear), or the presence of tie-molecules. 相似文献
62.
本文在综述近年来有关光孤子研究成果的基础上,对单模光纤中受激喇曼散射的喇曼孤子产生进行了详细地描述。从理论上分析了喇曼互作用及喇曼孤子的形成过程,讨论了喇曼孤子产生的实验方法及有关应用。 相似文献
63.
A review is proposed of different techniques available today for the characterization of the atomic structure of carbon nanotubes. This review covers the electron microscopies, various diffraction techniques, scanning probe microscopies, and optical spectroscopies, including Raman scattering. The advantages and limitations of the characterization techniques are discussed. 相似文献
64.
H. Launay S. Loridant D.L. Nguyen A.M. Volodin J.L. Dubois J.M.M. Millet 《Catalysis Today》2007,128(3-4):176-182
New vanadium oxide supported on mesoporous silica catalysts for the oxidation of methane to formaldehyde were investigated by infrared and Raman spectroscopies to identify and characterize the molecular structure of the most active and selective catalytic sites. In situ and operando experiments have been conducted in order to understand the redox and hydroxylation/dehydroxylation processes of the vanadium species. (SiO)2VO(OH) species were identified in these catalysts in reaction conditions and shown to undergo a deprotonation at 580 °C under vacuum, leading to a site giving a photoluminescence band at 550 nm attributed to reverse radiative decay from the excited triplet state:
(V4+–O−)* (V5+O2−). An activation mechanism of vanadium monomeric species with electrophilic oxygen species is proposed. 相似文献
65.
66.
解析扩展X射线吸收精细结构谱(TheExtendedX-rayAbsorptionFineStructureEXAFS)的一种方法是曲线拟合,在曲线拟合中,能量阈值E0的确定有着很重要的意义,同时也有相当的难度,本文应用AKIMA平滑数据点方法达到了对E0在数学意义上的精确求解,数据分析结果表明,这种方处理结果是令人满意的。 相似文献
67.
研究了InP样品和In1-xGaxAsyP1-y液相外延片在300~800nm范围内的电调制反射光谱。利用Apsnes三点法计算了临界点能量、增宽因子和自旋轨道分裂值。通过实验曲线与理论公式的拟合,确定了临界点能维数及相位因子。并且间接提供了被测In1-xGaxAsyP1-y四元合金的组份值及其它临界点能量值E0和E2。 相似文献
69.
Miguel Eduardo L. Felismino Paul A. Helm Chelsea M. Rochman 《Journal of Great Lakes research》2021,47(1):180-189
Microplastics (plastic particles <5 mm in size) have been reported in ecosystems worldwide and have been shown to cause adverse negative impacts on organisms. This study provides the first report of microplastics and other anthropogenic microparticles in the surface waters and sediments of Lake Simcoe in Ontario, Canada, a popular recreational and fishing lake. Surface waters (low volume grabs and manta trawls) and sediments were sampled from eight sites to determine microparticle abundances and character (size, morphology, material identity). Concentrations ranged from 0 to 0.7 particles/L in surface water grab samples, 0.4–1.3 particles/m3 in manta trawl samples, and 8.3–1070 particles/kg in sediment samples. Spectroscopic analysis confirmed that 72% of particles were anthropogenic, with 64% unambiguously identified as microplastics. However, confirmed microplastic concentrations were approximately 6–7 times lower than unadjusted counts in sediments, demonstrating the importance of verifying and adjusting reported values. Fibers were only quantified and characterized in surface water grab samples and sediments, and were the most common morphology, accounting for 82% and 89% of anthropogenic particles, respectively. Fragments were most common in manta trawl samples (75%, excluding fibers) and consisted predominantly of polyethylene (41%) and polypropylene (22%). The influence of proximity to urban centers and prevailing winds on the distribution of microplastics was apparent in surface water manta trawls. Microplastics and other anthropogenic microparticles are present in Lake Simcoe but at lower abundances than at locations impacted by larger population centers in other large freshwater lakes such as Lakes Ontario and Erie of the Great Lakes. 相似文献
70.
The surface structure of the oxidized and ammonia dissolved MoO3/-Al2O3 samples and the adsorption characteristics of the sulfided samples were investigated by Laser Raman Spectroscopy (LRS) and Low Temperature Infrared Spectroscopy (LTIR) techniques.It was verified that there were two kinds of coordinated unsaturated Mo sites (denoted as MoA(CUS) and MoB(CUS)) on the surface and the precursors of MoA(CUS) and MoB(CUS) were Mo(O) and Mo(T), respectively. It was also concluded that MoA(CUS) sites could adsorb NO and CO, while MoB(CUS) could adsorb CO only. The surface concentration of MoA(CUS) might be far smaller than that of MoB(CUS). 相似文献