全文获取类型
收费全文 | 2128篇 |
免费 | 251篇 |
国内免费 | 17篇 |
专业分类
电工技术 | 17篇 |
综合类 | 70篇 |
化学工业 | 1805篇 |
金属工艺 | 29篇 |
机械仪表 | 27篇 |
建筑科学 | 22篇 |
矿业工程 | 6篇 |
能源动力 | 5篇 |
轻工业 | 149篇 |
石油天然气 | 53篇 |
武器工业 | 1篇 |
无线电 | 13篇 |
一般工业技术 | 143篇 |
冶金工业 | 35篇 |
原子能技术 | 19篇 |
自动化技术 | 2篇 |
出版年
2024年 | 9篇 |
2023年 | 15篇 |
2022年 | 8篇 |
2021年 | 88篇 |
2020年 | 64篇 |
2019年 | 52篇 |
2018年 | 61篇 |
2017年 | 53篇 |
2016年 | 78篇 |
2015年 | 79篇 |
2014年 | 93篇 |
2013年 | 165篇 |
2012年 | 128篇 |
2011年 | 100篇 |
2010年 | 90篇 |
2009年 | 92篇 |
2008年 | 106篇 |
2007年 | 120篇 |
2006年 | 134篇 |
2005年 | 116篇 |
2004年 | 121篇 |
2003年 | 129篇 |
2002年 | 86篇 |
2001年 | 54篇 |
2000年 | 47篇 |
1999年 | 48篇 |
1998年 | 60篇 |
1997年 | 29篇 |
1996年 | 15篇 |
1995年 | 12篇 |
1994年 | 16篇 |
1993年 | 18篇 |
1992年 | 12篇 |
1991年 | 6篇 |
1990年 | 10篇 |
1989年 | 12篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 16篇 |
1984年 | 7篇 |
1983年 | 6篇 |
1982年 | 23篇 |
1973年 | 1篇 |
排序方式: 共有2396条查询结果,搜索用时 15 毫秒
91.
The splicing of reinforcement bars in tension using epoxy-sleeve joints is described. The optimum length of the splicing sleeve required and the optimum bonding layer of epoxy resin in the joint were determined in direct tension tests. The performance of the epoxy-sleeve joint made to these optimum dimensions is then compared to that of a lap splice made according to the provisions of CP 110 in a beam flexure test. A sleeve length of 12 bar diameters and an optimum average thickness of 2 mm of the bonding layer of epoxy are shown to develop the full strength of the splices bar. Tensile reinforcement bars spliced using epoxy-sleeve joints are shown to perform satisfactorily as flexural reinforcement in beams and compare favourably with the standard CP 110 lap splice. Epoxy-sleeve joints are shown to produce stiffer beams and reduced crack width at the joints. 相似文献
92.
93.
94.
以五氯化钽和四苯基锡为催化剂,通过二炔烃的环三聚反应一步法合成了一系列高支化的聚芳烃树脂;为改善均聚物的可溶性,引入了二炔单体与苯乙炔。IR和1H NMR谱图分析证实通过[2+2+2]环三聚机理形成了目标产物。同时研究了单体种类、单体催化剂比例、催化剂陈化时间、反应温度和反应时间对树脂结构和热性能的影响。 相似文献
95.
In order to lower the volume shrinkage of the DLP 3D printing photosensitive resins during printing, a thiol-terminated hyperbranched polymer (T-HBP) was synthesized and introduced into the bisphenol A epoxy acrylate (EA) based photosensitive resin system. The obtained T-HBP was characterized by FTIR and 1H NMR spectra, and the grafting rate of sulfhydryl was determined. The mechanical properties of the photosensitive resins were measured by tensile and impact strength measurement. The glass transition temperature of the photosensitive resins was analyzed by DSC and the impact fracture surface was observed by SEM. T-HBP exhibited a much lower viscosity than its linear counterparts, and the addition of thiol improved the curing speed of the photosensitive resins. When the amount of T-HBP added was 20 wt%, the shrinkage of the photosensitive resins was reduced by about 45.5% and the impact strength increased by 33.9% compared with the control. The macromolecular spherical structure of T-HBP effectively reduced the functional group density of the photosensitive resins. In addition, the thiol-acrylate photopolymerization introduced by T-HBP further reduced the volume shrinkage of the photosensitive resins. 相似文献
96.
In the presented study, the structural, thermal, and mechanical properties of the nanocomposites were investigated by doping silanized hexagonal boron carbide (h-B4C) nanoparticles in varying proportions (0.5%, 1%, 2%, 3%, 4%, and 5%) into the epoxy resin by weight. For this purpose, the surfaces of h-B4C nanoparticles were silanized by using 3-(glycidyloxypropyl) trimethoxysilane (GPS) to improve adhesion between h-B4C nanoparticles and epoxy matrix. Then, the silanized nanoparticles were added to the resin by ultrasonication and mechanical stirring techniques to produce nanocomposites. The bond structure differences of silanized B4C nanoparticles (s-B4C) and nanoparticle doped composites were investigated by using Fourier transform infrared spectroscopy. Scanning electron microscopy and energy dispersion X-ray spectroscopy (SEM-EDS) technique was used to examine the distribution of nanoparticles in the modified nanocomposites. Differential scanning calorimetry and thermogravimetric analysis techniques were used to determine the thermal properties of the neat and s-B4C doped nanocomposites. The tensile test and dynamic mechanical analysis were performed to determine the mechanical properties. When the experimental results were examined, changes in the bonding structure of the s-B4C nanoparticles doped nanocomposites and significant improvements in the mechanical and thermal properties were observed. The optimum doping ratio was determined as 2% by weight. At this doping ratio, the Tg, tensile strength and storage modulus increased approximately 18%, 35%, and 44% compared to the neat composite, respectively. 相似文献
97.
Firstly, cerium dioxide(CeO2) was modified by 3-(Methylacryloxyl)propyltrimethoxy silane (KH-570), and modified CeO2 (mCeO2) was prepared. Then poly (urethane-acrylate) was modified by mCeO2, and poly (urethane-acrylate)/modified CeO2 (PUA/mCeO2) composites with ultraviolet absorption property were prepared. The morphology, thermal hydrophobicity, mechanical properties, optical properties, and UV-absorption properties of PUA/mCeO2 composites were studied. XRD and SEM analysis showed that the modified CeO2 had better dispersion in the matrix than that of pure CeO2. Ultraviolet–visible spectrum and thermogravimetric analysis were used to characterize the optical properties and thermal stability of PUA/mCeO2 composites. The results showed that with the increasing of the mCeO2 content, the UV-absorption property of PUA/mCeO2 composites was improved gradually. When the content of mCeO2 is 3%, the absorption of ultraviolet of PUA/mCeO2 composites is about 5 times of pure PUA film, and the absorption band is mainly in the UVA section. The thermal stability of PUA/mCeO2 composites was improved with the adding of mCeO2. With the increasing of mCeO2 content, the contact angle of PUA/mCeO2 composites increased significantly. And the UV-absorption mechanism of PUA/mCeO2 Composites was studied. UV-curable PUA/mCeO2 composites have good UV absorption property and water resistance. They will be used in the sun screen and protect people's skin. 相似文献
98.
N503萃淋树脂分离富集金 总被引:7,自引:0,他引:7
研究了N_(503)萃淋树脂的合成方法及其分离富集金的条件.N_(503)萃淋树脂是萃取色层分离富集金的新固定相.2%硫脲、1%亚硫酸钠水溶液均可以定量解脱柱床上的金.经矿样验证,金的测定结果与717离子交换树脂吸附法一致.红外光谱表明该萃取色层与N_(503)液液萃取金有相同的机理. 相似文献
99.
100.
采用一种新合成的03#固化剂,可以使呋喃树脂在常温下缩短固化时间,并且在低温下可以固化.测试结果表明:在低温下呋喃树脂的固化性能、粘结强度和体积安定性均符合技术要求. 相似文献