激光熔覆生物陶瓷涂层及界面的热力学计算

在医用金属材料表面形成一层生物陶瓷是制备高性能、高可靠性生物植入材料的有效途径．采用激光处理技术在钛合金表面同步合成及熔覆了以羟基磷灰石为主的生物陶瓷涂层复合材料，激光熔覆制备生物陶瓷涂层覆界面反应是非常复杂的过程，其中包括很多的化学反应，从物理化学角度对涂层覆界面反应进行热力学计算，计算结果表明：在该实验条件下，完全具备合成羟基磷灰石、磷酸钙等生物陶瓷涂层的热力学条件，而且也满足界面处发生化学反应生成钛酸钙等新相的条件。     

U表面Al及Ti/Al双重镀层的电化学腐蚀行为

采用动电位极化技术和扫描电镜(SEM)对U表面Al及Ti/Al双重镀层在含50μg/gCl^－的KCl溶液中的电化学腐蚀行为进行研究。研究结果表明：U表面Al镀层和Ti/Al双重镀层的腐蚀为局部腐蚀，其腐蚀速度明显低于裸体U，能够对U表面提供较好的保护。Al镀层相对U基体为阳极性镀层，能对U基体提供牺牲性保护；Ti镀层相对U基体为阴极性镀层，对U基体的保护是基于镀层对腐蚀介质的物理屏障作用。     

NdAlO3掺杂对Ba4.2Nd9.2Ti18O54陶瓷微波介电性能的影响

研究了NdAlO3掺杂对Ba4.2Nd9.2Ti18O54(简称BNT)陶瓷材料微观结构及其微波介电性能的影响.采用XRD和场发射扫描电子显微镜分析了掺NdAlO3后的BNT陶瓷材料的微观结构.结果表明,掺入的NdAlO3与Ba4.2Nd9.2Ti18O54形成了固溶体.随着NdAlO3掺入量的增加,材料的介电常数和谐振频率温度系数逐渐减小,Q×f值先增大后减小.当NdAlO3的掺入量为10wt%时,材料的Q×f值达到最大(11400GHz),谐振频率温度系数接近为零(-0.7ppm/℃),此时材料的相对介电常数为66.29(3.5GHz).     

致密烧结Ti/Al2O3复合材料

利用放电等离子烧结技术(SPS)制备出相对密度、断裂韧性、弯曲强度分别为99.74%、19.73±0.4MPa·m1/2、1002±12MPa的40vol%Ti/Al2O3复合材料。SEM对复合材料表面形貌观察发现,Ti、Al2O3两相分布均匀,表面无明显气孔存在;断口的SEM和EDS表明,复合材料已形成网络导电结构;复合材料的HREM微观结构分析表明,Al2O3三角晶界处无其它杂质的偏聚,小颗粒的金属Ti富集在Al2O3的三角晶界结合处,界面结合紧密。     

气体辅助法陶瓷薄膜的制备

Ceramics （alumina） coating on sevaral materials has been successfully achieved at room temperature by gas - assisted deposition （ GAD） technique. In the GAD process the alumina powder was accelerated by jet flow with velocity of - 1000 m/s and impaeted to a substrate, thereby a fiat and dense film was deposited up to 10 μm on the substrate without arty additional heating. The crystal structttre of the alumina in an obtained GAD films seemed as amorphous like. The crystalline phase was recovered by post nnnenling at 1 300 ℃ , however, the matrix resulted in a hollow structure.     

Investigations of ferritic/martensitic super heat resistant 11‐12 %Cr steels for 650 °C power plants

The investigations of advanced ferritic/martensitic 11–12 %Cr steels for 650 °C power plant components focus on the improvement of high‐temperature creep properties with respect to chemical composition. The claim of the DFG research work was the development of new heat‐resistant 12 %Cr ferritic‐martensitic steels with sufficient creep and oxidation resistance for a 650 °C application by using basic principles and concepts of physical metallurgy on the basis of the state of art and to overcome the usual trial and error industrial alloy development. Efforts are focussed on a 100,000h creep strength of 100MPa at 650 °C in combination with a sufficient corrosion resistance by a Cr content of 12 % with contents 4‐5 %W, 3.4‐5,5 %Co, V, B and 1 %Cu as well as the choice of Ta or Ti instead of Nb. The results demonstrate that the aim is not to realize with the used alloying concept. In the long term range all 12 %Cr melts have a lower creep rupture strength than the advanced 9 %Cr piping steel P92. A high creep strength could be reached with a 0.06 % Ta alloyed 11 %Cr melt, which is in addition alloyed with a higher C and B content and as well as with lower W and Co portions. The results indicate in accordance with the finding of other steel researcher that a lower Cr content allows more effectiveness for the alloying partners respectively for the generation of more stable precipitates.     

Ti(C,N)基金属陶瓷合金成分与性能研究进展

介绍了Ti(C,N)基金属陶瓷的基本组成和典型结构,概述了Ti(C,N)基金属陶瓷合金成分对组织结构和力学性能的影响,总结了Ti(C,N)基金属陶瓷的研究现状,并展望了其发展前景。     

球化处理对氢化脱氢钛粉特性及其注射成形喂料流变性能的影响

氢化脱氢(HDH)钛粉形状不规则、流动性较差,不利于注射成形和提高其制品性能。本文通过PCS系统对HDH钛粉末进行球化处理,考察了球化处理对HDH钛粉特性及其注射成形喂料流变性能的影响。结果表明:球化处理后的HDH钛粉末变为近球形,粉末的流动性显著提高,其注射成形喂料的流变性能得到明显改善;同时,球化处理后钛粉的烧结组织明显细化,致密度大幅度提高。     

EAF-LF-CSP流程Ti微合金化钢炼钢工艺研究

基于珠钢EAF-LF-CSP流程,研究深脱O、深脱S、低N钢等生产技术,使[O]＜25×10-6、[N]＜70×10-6、[S]＜50×10-6,解决了Ti微合金收得率低、性能不稳定和连铸过程堵水口的问题,Ti铁的回收率稳定控制在67%左右,并在此基础开发出屈服强度为450～700MPa的高强钢.     

热镀锌板温度测量数据辨识模型探索与应用

介绍了热镀锌机组带钢进入锌锅的温度控制原理,针对板温控制建立了温度测量数据辨识模型,即用等温辐射针对温度进行测量的辨识模型,介绍了基于辨识模型的生产实践和取得的效果。