催化反应精馏制备乙酸乙酯

利用反应精馏装置研究了乙酸和乙醇直接酯化法合成乙酸乙酯的转化条件:加热温度200 ℃,浓硫酸质量占混和物总质量0.6%,回流比为3∶1,乙酸与乙醇的摩尔比为1.15∶1.以反应精馏方式进行时,乙醇转化率、乙酸乙酯收率分别为94.09%和60.45%,明显高于普通蒸馏法,而乙醇转化为乙酸乙酯的选择性变化不大.     

Gas-phase selective oxidation of toluene on TiO2–sepiolite supported vanadium oxides: Influence of vanadium loading on conversion and product selectivities

Gas-phase selective oxidation of toluene has been carried out on vanadium oxide systems (5–20 wt.% of V₂O₅, equivalent to 0.4–1.7 theoretical monolayers) supported on TiO₂–sepiolite (with titania loading around the theoretical monolayer, 12 wt.%) and on sepiolite. A study has been made on both the influence of vanadia loading and of the support on the catalytic behaviour of the supported vanadium systems. The reducibility by H₂ TPR was also studied as well as the acid and basic/redox sites from the results of conversion of the 2-propanol test reaction of the solids. Benzaldehyde, benzoic acid and several coupling products were the main ones detected, attaining over 50% selectivity towards the benzaldehyde and benzoic acid products at a total conversion around 10%. The activity and selectivity to the selective products exhibited by vanadium systems supported on mixed support were superior to those exhibited by the systems supported on sepiolite and increased notably in both series with the increase in vanadium loading. The best catalytic behaviour exhibited by the vanadium systems supported on mixed support, which also exhibited the highest density of sites capable of being reduced (as well as their reducibility) and of those responsible for propanone formation, could be attributed not only to the different balance of the vanadia species existing in the two supports (monomeric + oligomeric/polymeric), but also to such other factors as the nature of the support and, concretely, its chemical composition.     

公伯峡水电站土石围堰防渗布置与施工

公伯峡水电站土石围堰布置5种防渗型式，分别是沥青防渗墙，现浇混凝土防渗，粘土心墙，土工膜防渗和高压旋（摆）喷混凝土防渗墙。通过对不同类型防渗墙的施工方法，施工程序和防渗效果的比较，可为其他类拟工程的防渗设计及其施工提供参考。     

塑料排水板的等效直径

首先，通过室内模型试验认为，一字形塑料排水板在换算成等效直径的砂井时换算系数宜为0.85-0.9。然后，对等效直径的各种研究方法进行了讨论，并给出了排水板等效直径的定义。     

在N-数字小数分频器中的作用

分析了∑－△对S／N的改善作用，将∑－△在A／D中的应用引入到N－数字小数分频器中，简述了∑－△对N－小数分频器输出相位抖动的改善，提出用单级∑－△累加器级代多级累加器级联复用概念。     

实体造型及其二维图形转换技术在包装机械设计中的应用

介绍运用AutoCAD进行实体造型，再将其转换为二维图形，从而获得零件图的方法，该方法可以显著提高包装机械的设计效率。     

WC对铜基和镍基喷焊覆层材料耐气蚀性能的影响

在CuNiSiB,NiCrSiB自熔合金粉末中添加WC陶瓷颗粒，利用氧乙炔焰粉末喷焊工艺制备覆层材料，用超声波振动气蚀仪对覆层材料进行耐气蚀性能研究，用扫描电子显微镜对覆层材料表面气蚀破坏形貌进行观察，结果表明：复合覆层材料的耐气蚀能力比基体强；提高CuNiSiB覆层材料耐气蚀能力的途径是强化晶界，还探讨了覆层材料的气蚀破坏机理。     

Spray forming technology for military applications

Over the past five years, the Annapolis Detachment, Carderock Division, Naval Surface Warfare Center (formerly David Taylor Research Center) has established a state- of- the- art spray forming facility for the study and exploitation of this near net shape manufacturing process. Spray forming is a single step gas atomization/deposition process which yields ferrous and nonferrous, near final shape, near fully dense preforms that has proven to be a viable and cost effective alternative to conventional metalworking technology for the production of material preforms with properties surpassing those of their cast and wrought counterparts. Current programs at Carderock Divison Naval Surface Warfare Center are aimed at optimization of the process, certification of the spray formed products and industrialization of the technology.     

钢铁表面黑色转化膜处理技术

黑色转化膜技术是目前较为先进的钢铁表面处理技术 ,本文试验研究了一种新工艺 ,提出了TB值的概念 ,通过控制TB值即可控制处理液的质量 ,获得性能优良的转化膜。此工艺性能可靠 ,可操作性强 ,并可应用于激光热处理前的预处理。