TiNiNb钎焊Cf/SiC与TC4接头组织结构

文中在钎焊温度980℃、钎焊时间15 min的条件下,采用Ti_54.8Ni_34.4Nb_10.8（原子分数,%）共晶合金粉末真空钎焊C_f/SiC复合材料与TC4钛合金.用SEM,EDS及差热分析法（DTA）观察测定了钎料组织、成分及熔点,分析了钎焊接头的微观组织结构.结果表明,Ti_54.8Ni_34.4Nb_10.8共晶钎料由Ti₂Ni及Ti（Nb,Ni）化合物组成,实际熔点为935℃.钎焊过程中,Ti和Nb元素与复合材料反应形成TiC和NbC混合反应层;钎料中的镍与TC4中的镍发生互扩散,在TC4钛合金侧形成扩散层;连接层由弥散分布的Ti（Nb,Ni）化合物和Ti₂Ni相组成.C_f/SiC与连接层界面为接头最薄弱环节,此处易形成裂纹.     

清洗工艺对GH4099蜂窝夹层结构钎焊性能的影响

目的 研究激光清洗和离子轰击对GH4099蜂窝夹层结构钎焊性能的影响,优化GH4099蜂窝夹层结构焊前清洗工艺。方法 分别用400#砂纸、不同激光功率(60~200 W)、不同离子轰击时间(1~2 h)对GH4099带材表面进行了砂纸打磨、激光清洗和离子轰击试验,分析了激光清洗和离子轰击对GH4099表面形貌、O元素含量、BNi2钎料润湿性的影响,测试了不同清洗工艺下蜂窝夹层结构钎焊接头的拉伸性能。结果 随激光功率从60 W增加到100 W,GH4099表面O含量逐渐降低,表面粗糙度逐渐增大,钎料润湿面积百分比增加到83.5%,润湿性增加。当激光功率大于100 W时,表面残留网状分布的氧化物,导致钎料润湿性降低。当激光功率进一步增加到200 W时,氧化物网状分布现象减轻,润湿性随之增加,粗糙度也有所降低;随离子轰击时间从1 h增加到2 h时,带材表面氧化皮逐渐去除干净,钎料润湿性随之增加,钎料对离子轰击2 h的表面的润湿面积百分比达到91.2%,与400#砂纸打磨的相当。经离子轰击2 h、1 020 ℃-15 min钎焊获得的夹层结构等效抗拉强度为11.9 MPa。结论 与激光清洗相比,离子轰击可以同时去除蜂窝型面及附近侧壁部分的氧化皮,能更有效地改善钎料对蜂窝基体的润湿性。     

搅拌针对FSSW-B接头界面组织与力学性能的影响

铝/镁异种金属复合结构在结构轻量化领域具有极大的应用价值。采用新型搅拌摩擦点焊-钎焊技术(friction stir spot welding-brazing,FSSW-B)对铝/镁异种金属进行搭接点焊,同时与搅拌摩擦钎焊(friction stir spot brazing,FSSB)工艺进行对比,研究焊接工具中搅拌针的存在对接头界面组织与力学性能的影响。FSSW-B接头界面中间层分为明显上下2个部分,上层界面主要为MgZn₂相,下层界面主要为Mg₇Zn₃相;FSSB接头主要为MgZn₂相。接头的断裂模式主要为界面剥离断裂,由于搅拌针的存在,出现了眉状断裂模式。搅拌针的存在提高了接头的抗拉剪性能与疲劳性能,FSSW-B接头的最大抗拉剪力为7600 N,疲劳极限为3366.6 N;搅拌针使抗拉剪性能提升了53.5%,使疲劳性能提升了11.4%;FSSW-B中搅拌针的存在增加了接头疲劳性能的分散性。     

Graphene-coated copper foam interlayer for brazing carbon/carbon composite and niobium

Problems such as poor structural integrity, inhomogeneous dispersion, and agglomeration of graphene in the brazing seam are typically encountered for graphene additives in a brazed joint interface. To resolve these problems, a plasma-enhanced chemical vapor deposition process was employed for in-situ preparation of a high-quality graphene-coated copper (Cu) foam composite interlayer prior to be applied for brazing carbon/carbon composite and niobium. The prepared graphene and the brazed joints were characterized via Raman spectroscopy, scanning electron microscopy, and high-resolution transmission electron microscopy. The results revealed that graphene was evenly distributed in the brazing seam with the help of the Cu foam, which was characterized by interconnected porosity. Simultaneously, the excellent chemical inertia of graphene inhibited the collapse of the Cu foam, based on which the thermal residual stress in the joint was effectively mitigated due to the synergistic reinforcement effect of the Cu foam (with good plastic deformation capacity) and graphene (with extremely low coefficient of linear expansion). This effect led to significant improvement in the average shear strength of the joint.     

A brief review of brazing diamond in cutting tools

Diamond has high hardness and good wear resistance. It is widely used in cutting tools and workpieces. Brazing is an effective method to realize high quality cemented carbide joints in various materials connection technologies. This paper analyzes the research status of diamond brazing in detail. The materials used as brazing filler in diamond brazing are reviewed. Copper base filler and nickel base filler are the most commonly used brazing filler in diamond brazing. The advantages and disadvantages of diamond grinding tools under different production methods are analyzed. In addition, a series of new brazing alloys such as amorphous Ni based brazing filler metals are analyzed. Finally, the development trend of diamond brazing is pointed out.     

K9玻璃与2507不锈钢的真空钎焊

采用不同Ti含量的Sn Ag Cu-x%Ti复合钎料对K9玻璃与2507不锈钢进行了真空钎焊,研究了Ti含量对接头界面组织和力学性能的影响。采用场发射扫描电子显微镜(SEM)、能谱仪(EDS)和光学数码显微镜(OM)对钎焊接头组织结构进行了分析,用万能材料试验机对接头进行了剪切试验测试得到其力学性能,并对断口界面进行了分析。结果表明,接头界面典型组织结构为2507不锈钢/FeSn_2/Fe Sn/Sn(s,s)/Ti-Sn/K9玻璃。随着复合钎料中Ti含量的增加,接头界面中Ti-Sn化合物增多,且剪切强度升高。在钎焊温度为675℃,保温时间为10 min时,接头室温剪切强度最高达7. 3 MPa。钎焊接头断裂于K9玻璃并延伸至钎料中。     

银钎焊剂水溶法改性处理工艺的优化

采用水溶法改性工艺制备银钎剂，正交试验表明，烘干时间对钎剂性能的影响最大，其次是成分配比及烘干温度．在配方为42％KF 23％KBF4 35％B2O3，烘干时间为45min，烘干温度为350℃时，制备的银钎剂质量稳定且焊接效果良好．     

高温热结构复合材料的连接技术

综述了高温热结构复合材料之间的连接技术.主要包括C/C复合材料之间采用热压炭素、反应生成SiC的连接;C/SiC复合材料的液相硅渗透连接;SiC基复合材料的钎焊连接;SiC/SiC复合材料与钨板的扩散连接等.并简介了高温热结构复合材料连接在航天及核工业上的应用.     

Microstructural and mechanical assessment of transient liquid phase bonded commercially pure titanium

Diffusion joining of commercially pure titanium was successfully prepared via transient liquid phase bonding in vacuum environment. The process was carried out using AMS 4772 silver-based filler alloy at 900–1000°C for various holding time under the vacuum of 6?×?10^?7?Torr. Optical and scanning electron microscopy equipped with an EDS analyzer was conducted for microstructural evaluations. Mechanical properties were also investigated by shear test, fractographic assessment and X-ray diffraction analyses. The tendency to achieve isothermally solidified joint increased by increasing bonding time. No sign of athermal solidification was detected of sample bonded at 1000°C for 90?min. Consequently, the bonding condition of a high quality joint was obtained. Elemental analyses revealed that filler alloy’s elements (Ag, Cu) distributed more uniformly in fully isothermal solidified bond, whereas the aggregation of these elements is considerable in athermally solidified bond. Shear test results represented that the highest shear strength attributed to the sample bonded in isothermal solidified condition (bonded at 1000°C for 90?min).     

Computer methods of structural analysis

Amorphous metallic brazing alloys are used widely for brazing dissimilar materials, including corrosion-resisting steels. The results of detailed tests carried out in accordance with the GOST standard in tensile, impact, and bend loading are presented, and the results of non-standard torsion tests of brazed joints are also outlined.