FeOOH–CoS composite catalyst with high catalytic performances for oxygen evolution reaction at high current density

Water electrolysis is an efficient approach for high-purity hydrogen production. However, the anodic sluggish oxygen evolution reaction (OER) always needs high overpotential and thus brings about superfluous electricity cost of water electrolysis. Therefore, exploiting highly efficient OER electrocatalysts with small overpotential especially at high current density will undoubtedly boost the development of industrial water electrolysis. Herein, we used a simple hydrothermal method to prepare a novel FeOOH–CoS nanocomposite on nickel foam (NF). The as-prepared FeOOH–CoS/NF catalyst displays an excellent OER performance with extremely low overpotentials of 306 and 329 mV at 500 and 1000 mA cm⁻² in 1.0 M KOH, respectively. In addition, the FeOOH–CoS/NF catalyst can maintain excellent catalytic stability for more than 50 h, and the OER catalytic activity shows almost no attenuation no matter after 1000 repeated CV cycles or 50 h of stability test. The high catalytic activity and stability have exceeded most non-noble metal electrocatalysts reported in literature, which makes the FeOOH–CoS/NF composite catalyst have promising applications in the industrial water electrolysis.     

NaFeTiO4: A novel visible light active photocatalyst for water splitting and environmental remediation

Single phase, crystalline NaFeTiO₄ with tunnel structure is prepared by a solid state method and explored as a novel photocatalyst for the first time. Structural, optical and morphological properties of NaFeTiO₄ are investigated by various characterization techniques such as X-ray diffraction (XRD), scanning & transmission electron microscopy (SEM & TEM), Energy dispersive X-ray spectroscopy (EDS), N₂ adsorption-desorption study (BET), UV-vis, X-ray photoelectron, X-ray absorption (UV-vis DRS, XPS and XANES) and photoluminescence (PL) spectroscopy. The interfacial charge transfer ability of the prepared n-type NaFeTiO₄ was also investigated by transient photocurrent response and electrochemical impedence spectroscopy which proved to be an efficient tool for better understanding of electronic properties of NaFeTiO₄. The photocatalytic efficiency of NaFeTiO₄ is evaluated for decomposition of methylene blue (MB) and Rhodamine B (RhB) dyes as well as for H₂ evolution through water splitting reaction under visible light. NaFeTiO₄ exhibits efficient charge separation properties, excellent photocatalytic activities and reusability.     

太原精神病院污水处理系统改建为中水处理系统的工程设计

太原精神病医院将现有生活污水处理系统改建为中水回用系统,平均日处理水量100 m3.工程设计充分考虑了对原有设施的利用,生物处理单元采用生物接触氧化法.为减少污水提升次数,调节池设在生物处理单元之后.通过延长水力停留时间缓解水量、水质波动对沉淀、生物处理单元的不利影响,投入运行后效果良好.     

龙口水利枢纽工程规模论证

从目前电力系统的发展来看,不论是华北电网还是晋、蒙电网都存在着调峰能力不足的问题。为更好地利用黄河托龙段的水能资源,改善下游河道的水流条件,为地方经济建设提供清洁可靠的能源,建设龙口水利枢纽工程已经提到日程上来。龙口水利枢纽工程开发任务为发电、对万家寨电站进行反调节、兼有滞洪削峰等综合利用。根据电力系统的需求、泥沙淤积情况、动能经济指标和反调节等要求,综合考虑,选定正常蓄水位898m,装机容量420MW。龙口水利枢纽工程的建设符合国家关于调整能源结构,优先开发水电和加强基础设施建设,拉动经济增长的部署。     

输气管线中水合物的形成及预防

天然气管道输送过程中因地貌、气象及各种管道条件而使少量天然气形成水合物，导致堵塞管线，影响管线的安全运行。分析了输气管线中形成水合物的热力学和动力学条件，其中在热力学条件中着重介绍了管道中含水量对形成水合物的影响，结合两方面条件简要介绍了预防水合物的常用措施。     

烟气轮机叶片寿命的影响因素和评估方法

合理准确预测烟气轮机叶片寿命,是催化裂化装置安全运行的必要保障。文章研究了影响烟气轮机叶片疲劳寿命的因素;评述了叶片疲劳寿命评估方法;选取并介绍了适合烟气轮机叶片寿命的评估方法;阐明了目前存在有关叶片寿命的关键问题。     

小浪底水电站水轮机稳定运行技术措施

小浪底水电站位于黄河中游,多年平均含沙量高,水头变幅大。为减轻泥沙对水轮机的磨损,水轮机在水力设计、机械结构、抗磨蚀、密封等方面采取了一些非常规措施。经过几年的运行实践表明,小浪底水电站采取的这些技术措施效果良好,值得运行于多泥沙河流的水电站借鉴。     

黄河龙口水利枢纽坝基岩体钙质充填夹层地质分析与试验研究

龙口水利枢纽坝基岩体主要由奥陶系中统马家沟组(O2m2)灰岩组成,其中发育有多层软弱夹层。作为其中之一的钙质充填夹层,强度虽不很低,但由于处于坝基下的持力层内,间距不大,发育密集,产状平缓,是坝基浅层抗滑稳定的主要控制因素,因此,在大坝抗滑稳定分析时,应进行分析和研究。     

Vapor absorption by LiBr aqueous solution in vertical smooth tubes

Heat and mass transfer in a falling film vertical in-tube absorber was studied experimentally with LiBr aqueous solution. The presented results include the effect of solution flow rate, solution subcooling and cooling water temperature on the absorption in a smooth copper tube 16.05 mm I.D. and 400 mm long. The experimental data in the previous report for a 1200-mm-long tube was also re-examined and compared. It was demonstrated by the observation of the flow in the tube that the break down of the liquid film into rivulets leads to deterioration of heat and mass transfer at lower film Reynolds number or in longer tubes. An attempt to evaluate physically acceptable heat and mass transfer coefficients that are defined with estimated temperature and concentration at the vapor–liquid interface was also presented.     

西气东输对南水北调穿黄隧洞影响动力分析计算

西气东输管线距离南水北调工程穿黄河隧道的最近距离:河漫滩仅150 m,主河槽仅205 m.输气管线在运行过程中,存在着因误操作、管道腐蚀、自然灾害或人为破坏等因素引发事故发生爆炸的可能.对深泓区穿黄隧洞地下部分在天然气爆炸冲击波作用下的安全性进行动力分析计算,认为西气东输管道破裂引起的天然气爆炸,不会对南水北调输水隧洞产生破坏影响.