Synergistic Effects of Polybenzimidazole and Aramide on Enhancing Flame-Retardancy and Solubility

Aromatic and functional polymers with processibility derived from biobased starting materials are prerequisite considering sustainable society. Poly(2,5-benzimidazole)s are rigid-rod polymers to show ultrahigh thermal stability such as flame retardance, while usually suffer from poor solubility. Here, poly(benzimidazole-co-amide)s are synthesized from two biobased monomers, 3,4-diaminobenzoic acid and a semirigid comonomer, 4-aminohydrocinnamic acid. The copolymers with an amide composition of 80 mol% and higher are soluble in widely used polar solvents to fabricate the films keeping high flame retardance, which is comparable with popular high-performance polymers such as aromatic polyimides, polyetheretherketone, polyphenylene sulfide, etc.     

Thermal transport and chemical conversion in single reacting sorbent particles

The effects of particle size and carbon dioxide concentration on chemical conversion in engineered spherical particles undergoing calcium oxide looping are investigated. Particles are thermochemically cycled in a furnace under different carbon dioxide concentrations. Changes in composition due to chemical reactions are measured using thermogravimetric analysis. Gas composition at the furnace exit is evaluated with mass spectroscopy. A numerical model of thermal transport phenomena developed previously is adapted to match the physical system investigated in the present study. The model is used to elucidate effects of reacting medium characteristics on particle temperature and reaction extent. Experimental and numerical results show that (1) an increase in particle size results in a decrease in carbonation extent, and (2) the carbonation step consists of fast and slow reaction regimes. The reaction rates in the fast and slow carbonation regimes increase with increasing carbon dioxide concentration. The effect of carbon dioxide concentration and the distinction between the fast and slow regimes become more pronounced with increasing particle size.     

外墙保温系统中粘结材料的检测技术分析

选择了几份典型的外墙外保温系统标准,通过对这几份标准中胶粘剂和抹面胶浆的成型和检测方法的比较,分析了现有检测技术的优劣,并结合工作实践提出了建议。     

Simultaneous improvement of thermal conductivity and mechanical properties for mechanically mixed ABS/h-BN composites by using small amounts of hyperbranched polymer additives

Recently, thermal interface materials (TIMs) are in great demands for modern electronics. For mechanically mixed polymer composite TIMs, the thermal conductivity and the mechanical properties are generally lower than expected values due to the sharply increased viscosity and poor filler dispersion. This work shows that addition of a small amount of polyester-based hyperbranched polymer (HBP) avoided the trade-off in mechanically mixed ABS/hexagonal boron nitride (h-BN) composites. After adding 0.5 wt% HBP, the maximum h-BN content in the composites increased from 50 to 60 wt%. The out-of-plane, in-plane thermal conductivity, and tensile strength of ABS/h-BN with 50 wt% h-BN were 0.408, 0.517 W/mK, and 18 MPa, respectively, and were increased to 0.729, 0.847 W/mK, and 32 MPa by adding 0.5 wt% HBP, while 0.972, 1.12 W/mK, and 29.5 MPa were achieved for ABS/h-BN/HBP with 60 wt% h-BN. The morphological and rheological results proved that these enhancements are due to the improved h-BN dispersion by decreasing viscosity of composites during mixing. Theoretical modeling based on the modified effective medium theory confirmed such results and showed that the interfacial thermal resistance also decreased slightly. Thus, this work demonstrates a facile and scalable method for simultaneously improving the thermal conductivity and mechanical properties of thermoplastic-based TIMs.     

改进Elman神经网络在短期热负荷预测中的应用

热电厂的短期热负荷预测在城市集中供暖中起着至关重要的作用,直接影响热电厂的经济效益和热能利用率。电厂的短期热负荷一般采用神经网络预测模型进行预测,而BP神经网络应用最为广泛。Elman神经网络算法在BP神经网络基础上加入了承接层,作为一步延时算子,实现记忆能力,使系统具备适应时变能力,增强系统全局稳定性。但Elman神经网络算法模型的构造依然需要大量样本的支撑,而且输入层的变量多,导致预测时间依然很长,收敛速度慢。该文在Elman神经网络预测前,进行了相关系数预处理和对样本中异常值的平均化预处理,通过数据归一化运算,使Elman神经网络输入层变量大幅减少。仿真实验表明,改进的Elman神经网络算法使预测模型快速寻优,减少预测时间的同时明显提高预测精度。     

红外热成像在乳腺疾病检测的应用研究

乳腺疾病已严重危害女性身心健康,其中乳腺癌更位居全球范围内女性癌症发病率和死亡率首位,因此乳腺癌的早期发现意义重大。传统结构影像学早期检测疾病具有一定局限性,而红外热成像作为功能成像技术可为乳腺癌的早期筛查提供有效线索。因此本文主要就红外热成像在乳腺疾病的早期检测及预后评估的应用价值进行综述。     

Fabrication of Cu/graphite film/Cu sandwich composites with ultrahigh thermal conductivity for thermal management applications

Effective thermal management of electronic integrated devices with high powder density has become a serious issue, which requires materials with high thermal conductivity (TC). In order to solve the problem of weak bonding between graphite and Cu, a novel Cu/graphite film/Cu sandwich composite (Cu/GF/Cu composite) with ultrahigh TC was fabricated by electro-deposition. The micro-riveting structure was introduced to enhance the bonding strength between graphite film and deposited Cu layers by preparing a rectangular array of micro-holes on the graphite film before electro-deposition. TC and mechanical properties of the composites with different graphite volume fractions and current densities were investigated. The results showed that the TC enhancement generated by the micro-riveting structure for Cu/GF/Cu composites at low graphite content was more effective than that at high graphite content, and the strong texture orientation of deposited Cu resulted in high TC. Under the optimizing preparing condition, the highest in-plane TC reached 824.3 W·m⁻¹·K⁻¹, while the ultimate tensile strength of this composite was about four times higher than that of the graphite film.     

Effect of lanthanum doping on water content and diffusion properties of corundum for producing transparent ceramics

The effect of doping corundum with lanthanum on the content of water and other gas impurities, on the diffusion characteristics, on the unit cell size and static strength of fine-crystalline corundum synthesized under thermovapours conditions in a supercritical water fluid was studied.Content, release and diffusion coefficients of water and other volatile impurities in corundum were measured by kinetic thermodesorption mass spectrometry. Water is the main volatile impurity in fine-crystalline corundum. It was found that the introduction of lanthanum into the structure of corundum reduces several times the content of water and other gas-liquid impurities. An increase in the diffusion coefficient of water during the doping of corundum with lanthanum leads to an increase in the degassing rate of fine-crystalline raw materials. When doping corundum, lanthanum, being localized in structural defects, not only displaces structural hydroxyl groups with the formation of strong aluminate-like bonds, but also decreases in the unit cell and increases in the average static strength of the crystals. La-doped corundum, due to the reduced content of water and other gas impurities, is a promising raw material for the production of transparent ceramics.